二甲磺酸阿米三嗪-β-环糊精包合物的鉴定

通过共沉淀法制备了二甲磺酸阿米三嗪 β 环糊精包合物,使用红外光谱、差示扫描量热法加以鉴定。证实了二甲磺酸阿米三嗪 β 环糊精包合物的生成,形成包合物后,二甲磺酸阿米三嗪得到了稳定。     

用光度法研究在3种溶剂中的硫氰酸钼(V)配合物

报道在3种溶剂中硫氨酸钠（V）配合物的生成情况，并以石油亚砜为萃取剂对其进行萃取研究，讨论了萃取剂的影响和有关萃取机理．     

Study on the charge transference and local magnetic moment of yttrium-cobalt compound

The electronic charge transference and local magnetic moment of the YCo₅ intermetallic compound were calculated using SCF-MO-DVXα method and multiple cluster model. The result shows that about one 4d-electron is transferred from anY atom to Co₁(2c), and the calculated local spin magnetic moments of Co_I(2c) and Co_II(3g) atoms in YCo₅ compound are 1.33 and 1.48μ _B , respectively, which are in very good agreement with experiments. Supported by the National Natural Science Foundation of China Qiao Haoxue: born in Apr. 1970, Master     

Synthesis of glucoside compounds of ferrocenyl phenols and their antianemic activity

Six glucoside compounds have been synthesized by means of phase-transfer catalytic method and deacetylation from the starting material ferrocene. Their structures have been confirmed by elementary analysis, IR,¹HNMR and MS. The antianemic activities of some compounds have also been tested. Results indicate that these glucoside compounds possess the antianemic activities and therefore, the further study is well worth making. Supported by the foundation of Wuhan Metropolis Commission of Science and Technology Liu Huiying: born in 1937, Professor     

聚丙烯腈水增塑熔融纺丝工艺研究

研究了聚丙烯腈及其共聚物在水增塑条件下的熔融规律,并在经过改造的φ20mm螺杆熔融纺丝机上进行了纺丝工艺研究。研究表明,聚丙烯腈树脂在一定量的水和热的作用下,由于大分子中氰基之间的作用力被拆散或减弱,可使其变成可进行纺丝成形的增塑熔体;不同含水量、不同组成、不同相对分子质量的聚合体具有不同的水增塑熔点;所纺制的纤维都具有较好的物理机械性能。     

PRELIMINARY STUDY ON OPEN END JET SPINNING

A new concept of spinning-open-end jet-spinning, which combines the advantages of the false twist jet spinning and open end winning, was proposed, and a device was designed to practice this concept. The property of thc open-end jet spun yarn was measured and discussed in comparison with that of some other spun yarns.     

高能量密度叠氮硝胺添加剂

通过对硝仿系硝胺进行结构改性，往其中引入一个叠氮甲基，以代替三硝基甲基中的一个硝基，合成了三个新的带偕二硝基的叠氮硝胺，它们具有密度大（１．７—１．８ｇ／ｃｍ３）、氮含量高（质量分数约４０％）、氧平衡较好（质量分数－２３％—－３５％）、标准摩尔生成焓高（约５００ｋＪ／ｍｏｌ）及热安定性较好（热分解温度接近或高于２００℃）等特点，可望作为高能量密度材料的含能添加剂．     

试论价键理论和晶体场理论的统一性

论述了价键理论和晶体场理论的统一性，并将两理论相结合，形成价键－晶体场理论，用于研究配合物的结构问题，取得了满意的结果。     

试论环境生物地球化学

本文从理论上探讨了环境生物地球化学这一新兴交叉学科的形成过程和发展机制,尝试性地提出了该学科的定义和科学使命。着重强调,环境生物地球化学应该服务于环境保护和生态建设;以此可以预料,生物—非生物复合系统中原生/次生化学污染物质的生物地球化学循环的研究,将为有利于全球污染控制和原生与次生化学污染引起的生态恶化和地方病防治的环境战略制定和目的于节省地球自然资源的生态设计提供科学依据。     

软硬酸碱规则与配合物的稳定性

本文从路易斯碱定义出发，以软硬酸碱规则分析配合物的形成特点，探求配合物稳定性规律，并从热力学角度加以说明。