微波高压硝酸消化原子荧光法测定微量砷

采用微波消化测定煤和土壤中微量元素砷。用硝酸高压消解，然后用原子荧光仪测定。方法的检出限0.011ng／L，线性范围0～40ng／L，其回收率为90．95～104．25％。该方法简便了煤和土壤中砷的消化和测定，精密度高，检出限低。     

利用“球壳失稳”理论确定煤与瓦斯突出瓦斯压力临界值

通过实验分析得出了马家沟矿9—12、12煤层初始释放瓦斯膨胀能与瓦斯压力的线性关系，从而确定了马家沟矿深部水平9—12、12煤层煤与瓦斯突出瓦斯压力临界值，为深部水平煤与瓦斯突出预测提供了依据。     

国外流域水资源配置模型研究进展

对国外水资源配置模型研究进行了综述，总结了水资源配置模型研究发展的趋势，即单目标模型向多目标模型发展，模拟与优化模型相结合，以及不确定性和模糊优化模型的建立．建议开发多目标、多层次、多用户、群决策的流域水资源优化配置模型系统，为流域水资源合理配置与科学管理实践提供科学的决策依据。     

晋城矿区综采放顶煤工作面顶煤冒放性分析

根据晋城煤业集团综采放顶煤开采实际情况,从影响顶煤冒放性的煤体裂隙、开采工艺和支架与围岩关系3个方面进行分析,对综放工作面的布置、采放比、放煤步距、支架架型与工作阻力提出了建议.     

冲击破煤过程中能量耗散的理论分析

介绍了能量在冲击式破煤过程中的产生、传递和耗散过程以及能量最终的分布范围;运用应力波的方法分析了应力波在煤体中传播过程,并得出能量在衰减过程中衰减率的计算方法;还分析了剥落厚度的计算方法,并得出正弦应力波在煤体中传播时的冲劈厚度和最大煤块尺寸的关系;根据冲击规律和能量的传递特征对能量的传递过程进行了分析,并求出冲击消耗能量和最小散逸能之间的关系,指出了要使煤块破碎必须满足冲击消耗能量要大于最小散逸能。     

柴达木盆地东部"走廊域"中新生代构造特征及构造演化

通过横穿柴达木盆地东部的“走廊域”剖面地表地质、航磁、重力、大地电磁测深和地震资料的综合分析，认为在东昆仑构造带与南祁连构造带之间，包括巴颜喀拉地块北缘，柴达木地块和祁连地块南缘等3个一级构造单元，柴达木地块内则包括了昆中构造带、昆北构造带和柴达木盆地3个二级构造单元。受东昆仑构造带和南祁连构造带相向挤压作用，柴达木盆地东部持续沉降，但由于具有稳定的花岗质基底，盆地坳陷幅度较小，且断裂及褶皱构造不发育。由此造就了柴达木盆地东部中新生代地层厚度小，烃源岩不发育，构造圈闭缺乏，除第四系天然气外，中生界、古近系和新近系油气资源前景受到极大限制。     

煤与生物质共超临界水催化气化制氢的实验研究

在压力为20～25MPa、停留时间为15～30s、：NaOH添加量(质量分数)为0．1％、反应器外壁温度为650℃的条件下，对煤与生物质的模型化合物羧甲基纤维素钠(CMC)在超临界水环境中的催化气化制氢性能进行了研究，探讨了物料浓度、压力以及停留时间对煤与CMC共气化制氢的影响．实验结果表明：煤与CMC二共超临界水催化气化制氢的主要气体产物是H2、CO2和CH4，H2的体积分数可高达60％以上；增加物料浓度、升高压力有利于提高产氢率，但延长停留时间不利于氢气的制取．     

The fate of injectant coal in blast furnaces: The origin of extractable materials of high molecular mass in blast furnace carryover dusts

The aim of the work was to investigate the fate of injectant coal in blast furnaces and the origin of extractable materials in blast furnace carryover dusts. Two sets of samples including injectant coal and the corresponding carryover dusts from a full sized blast furnace and a pilot scale rig have been examined. The samples were extracted using 1-methyl-2-pyrrolidinone (NMP) solvent and the extracts studied by size exclusion chromatography (SEC). The blast furnace carryover dust extracts contained high molecular weight carbonaceous material, of apparent mass corresponding to 10⁷?10⁸ u, by polystyrene calibration. In contrast, the feed coke and char prepared in a wire mesh reactor under high temperature conditions did not give any extractable material. Meanwhile, controlled combustion experiments in a high-pressure wire mesh reactor suggest that the extent of combustion of injectant coal in the blast furnace tuyeres and raceways is limited by time of exposure and very low oxygen concentration. It is thus likely that the extractable, soot-like material in the blast furnace dust originated in tars is released by the injectant coal. Our results suggest that the unburned tars were thermally altered during the upward path within the furnace, giving rise to the formation of heavy molecular weight (soot-like) materials.     

Influence of overpressure on coalbed methane reservoir in south Qinshui basin

In theory, from the high temperature and pressure during the coal generating gas to the present low temperature and pressure of coalbed methane reservoir, the accumulation of coalbed methane was from oversaturated to undersaturated. The gas content of the coalbed methane reservoir in the south Qinshui basin was 12-35.7 m3/t. According to the isotherm and measured gas content of No. 3 coal, the adsorbed gas content in some wells was highly saturated and oversaturated, which was hard to theoretically understand. In addition, there were no thermogenic and biogenic gases at the late stage in the south Qinshui basin. This article proposed that the overpressure was the main reason for the present high saturation of the coalbed methane reservoir. In early Cretaceous, the coalbed methane reservoir was characterized by overpressure and high saturation caused by gas generation from coal measure source rocks. In late Cretaceous, the coalbed methane reservoir was rapidly uplifted, and with the temperature and pressure decreasing, the pressure condition of adsorbed gas changed from overpressure to normal-under pressure, which resulted in the high saturation and gas content in the present coalbed methane reservoir.     

黑龙江省煤炭城市地质灾害及防治对策

论述了黑龙江省煤炭城市地质灾害的类型、成因及危害 ;并针对目前地质灾害现状提出了相应的防治对策 .