基于模糊策略的荧光光纤测温系统研究

本文分析了荧光光纤温度检测系统中导致荧光寿命存在非线性误差的原因。为更好地实现误差补偿功能提高检测精度,本文采用模糊策略对荧光寿命进行非线性误差补偿,以消除误差产生的影响。利用MATLAB建立仿真模型和实际系统的检测数据进行实验验证,实验结果表明所研究的基于模糊策略的荧光光纤温度检测系统能有效地提高荧光寿命值检测的稳定性和准确性,这对于提高荧光光纤测温系统的精度及鲁棒性具有重要意义。     

水与扶手椅型SWCNT复合环境下α-Ala分子的手性转变机理

采用组合量子化学ONIOM方法,基于氨基作为氢迁移桥梁,考察单壁碳纳米管(SWCNT)与水复合环境下α-丙氨酸分子(α-Ala)的手性转变机理.结果表明:基于氨基作为氢迁移桥梁的手性转变反应有a和b两个通道,其中通道a最具优势;水与扶手椅型SWCNT复合环境对氢迁移反应具有较好的催化作用;在SWCNT(8,8)的限域环境下,3个水分子构成的链使主反应通道的决速步骤能垒从裸反应的266.1kJ/mol降至117.8kJ/mol.表明SWCNT(8,8)与水构成的复合环境可作为实现α-Ala手性转变的理想纳米反应器,生命体内α-Ala分子可在类似的纳米环境实现旋光异构.     

Chemical,mechanical, and thermal expansion properties of a carbon nanotube-reinforced aluminum nanocomposite

In the present study, the chemical and mechanical properties and the thermal expansion of a carbon nanotube (CNT)-based crystalline nano-aluminum (nano Al) composite were reported. The properties of nanocomposites were tailored by incorporating CNTs into the nano Al matrix using a physical mixing method. The elastic moduli and the coefficient of thermal expansion (CTE) of the nanocomposites were also estimated to understand the effects of CNT reinforcement in the Al matrix. Microstructural characterization of the nanocomposite reveals that the CNTs are dispersed and embedded in the Al matrix. The experimental results indicate that the incorporation of CNTs into the nano Al matrix results in the increase in hardness and elastic modulus along with a concomitant decrease in the coefficient of thermal expansion. The hardness and elastic modulus of the nanocomposite increase by 21% and 20%, respectively, upon CNT addition. The CTE of CNT/Al nanocomposite decreases to 70% compared with that of nano Al.     

Conductive and corrosion behaviors of silver-doped carbon-coated stainless steel as PEMFC bipolar plates

Ni–Cr enrichment on stainless steel SS316L resulting from chemical activation enabled the deposition of carbon by spraying a stable suspension of carbon nanoparticles; trace Ag was deposited in situ to prepare a thin continuous Ag-doped carbon film on a porous carbon-coated SS316L substrate. The corrosion resistance of this film in 0.5 mol·L-1 H₂SO₄ solution containing 5 ppm F- at 80℃ was investigated using polarization tests. The results showed that the surface treatment of the SS316L strongly affected the adhesion of the carbon coating to the stainless steel. Compared to the bare SS316L, the Ag-doped carbon-coated SS316L bipolar plate was remarkably more stable in both the anode and cathode environments of proton exchange membrane fuel cell (PEMFC) and the interface contact resistance between the specimen and Toray 060 carbon paper was reduced from 333.0 mΩ·cm2 to 21.6 mΩ·cm2 at a compaction pressure of 1.2 MPa.     

掺铒氟光纤放大器的理论分析

本文对掺铒氟化光纤放大器提出了理论模型,计算了这种放大器的增益、噪声和饱和输出功率特 性,并与掺铒石英光纤放大器进行了比较。     

单模螺旋光纤的本地场

该文从波动方程出发,直接在本地坐标系(Serret-Frenet框架)中求解单模阶跃型折射率分布的圆形芯弱导螺旋光纤,应用微扰分析法得到了基模场分布和传播常数的解析表达式。结果表明:(1)单模螺旋光纤的基模是右旋和左旋圆偏振模;(2)螺旋光纤基模间的传播常数之差为2τ。这两个理论结果和已知的实验结果一致。     

氯化锌法生产活性炭新工艺的研究

<正>本文报道了以氯化锌为主的复合活化剂代替单一的氯化锌作活化剂生产粉状活性炭的新工艺。这种新工艺较传统的氯化锌法有许多优点:1.氯化锌的总单耗低;2.产品质量优良且稳定,糖用炭的主要指标达到或超过林业部颁Ly216-79一级炭标准;3.生产成本低,比同样条件下的老工艺每吨炭降低成本363元;4.活化温度低,活化时间短,氯化锌挥发量少,减少了大气污染;5.木屑的得炭率高,对各种木屑和油茶壳,不论水分含量高低都适应;6.可利用现有的平板炉生产,操作简便。     

软阔叶材炭化、活化的研究

<正>以软阔叶材(美洲黑杨,简称63杨)为原料进行干馏试验,以确定干馏的工艺条件。干馏炭进一步用水蒸汽活化,同时对干馏炭活化时的温度,时间和水蒸汽用量的变化对活性炭的吸附力和得率的影响进行了研究。 结果表明:软阔叶材可以作为制取活性炭的原料,干馏的最终温度约为480℃左右,得率31.4％;活化的最佳条件是:900℃、4h、水蒸汽用量180ml/120g木炭;制得的粉状炭的亚甲蓝脱色力为14.8ml,得率为36.2％。     

波分复用和频分复用光纤通信技术研究

波分复用(WDM)和频分复用(FDM)技术可用来充分开发光纤的宽频带特性,实现超大容量信息传输。在“八五”期间科研成果基础上,完成了4×2.488Gbit/s双向154km无中继波分复用光纤通信系统,并已安装于京九九光缆干线广州-深圳段通信线路上作现场试验和试运行。该系统工作稳定可靠,在5个多月试运行中未发现误码。同时,完成4×155Mbit/s频分复用光纤通信实验系统的研制。该系统频道间距为0.1nm,传输距离为18km。系统实现了模块化结构,具有良好的稳定性,实测24小时无误码。这一成果为FDM的应用打下了基础。     

碳纳米管粉末微电极对儿茶酚的电催化还原

采用粉末微电极来研究修饰和未修饰的碳纳米管电极的电化学特性,结果显示经阳极极化的碳纳米管比未极化的碳纳米管具有明显的催化效果,处理后的碳纳米管修饰的粉末微电极邻苯二酚具有较高的催化活性．