Improved dehydriding property of polyvinylpyrrolidone coated Mg-Ni hydrogen storage nano-composite prepared by hydriding combustion synthesis and wet mechanical milling

In this work, polyvinylpyrrolidone(PVP) coated Mg_(95)Ni_5 nano-composites were prepared by hydriding combustion synthesis(HCS) plus wet mechanical milling(WM) with tetrahydrofuran(THF) and donated as WM-x wt% PVP(x = 1, 3, 5 and 7) respectively. The phase compositions, microstructures and dehydriding property, as well as the co-effect of PVP and THF were investigated in detail. XRD results showed that the average crystal size of MgH_2 in the milled Mg_(95)Ni_5 decreased from 23 nm without PVP to 18 nm with 1 wt% PVP. The peak temperature of dehydrogenation of MgH_2 in the milled Mg_(95)Ni_5 decreased from 293.0 ℃ without THF to 250.4 ℃ with THF. The apparent activation energy for decomposition of MgH_2 in WM-7 wt% PVP was estimated to be 66.94 kJ/mol, which is 37.70 kJ/mol lower than that of milled Mg_(95)Ni_5 without THF and PVP. PVP and THF can facilitate the refinement of particle size during mechanical milling process. Attributed to small particle sizes and synergistic effect of PVP and THF, the composites exhibit markedly improved dehydriding properties.     

Study on the hydrogen storage property of (TiZr0.1)xCr1.7-yFeyMn0.3 (1.05

Jigang Li  Li Xu  Xiaojing Jiang  Xingguo Li 《自然科学进展(英文版)》2018,28(4):470-477

Effect of cold rolling process on microstructure and mechanical properties of high strength β titanium alloy thin sheets

The microstructure and mechanical properties of Ti-3.5Al-5Mo-6V-3Cr-2Sn-0.5Fe high strength titanium alloy sheets prepared by unidirectional cold rolling and two-step cross cold rolling were investigated. Results showed that the β phase grains were refined significantly by cold rolling followed by solution treatment for a short time.Compared to unidirectional cold rolling, the short time solution treatment after two-step cross rolling could significantly reduce the non-uniformity of the microstructure of the alloy sheets. After aging treatment at 550 ℃,the anisotropy of the mechanical properties still existed in the unidirectional rolled sheets, and the tensile strength was highest along the rolling direction. After solution and aging treatment, the anisotropy of the mechanical properties of the two-step cross rolling process sheet was not obvious than unidirectional cold rolling,and alloy had good strength and plasticity matching.     

医用可降解Mg-3Zn-0.5Sr合金耐蚀性及细胞毒性

采用仿生法在Mg-3Zn-0.5Sr合金表面制备涂层,通过SEM,EDS和XRD分析表征涂层形貌和结构;采用电化学实验和浸泡腐蚀实验来研究涂层对合金降解速率的影响;采用生物毒性实验验证有无涂层Mg-3Zn-0.5Sr合金的毒性等级.实验结果表明:在Mg-3Zn-0.5Sr合金表面可以沉积致密的羟基磷灰石(HA)涂层,厚度约为30~40μm,HA涂层可以有效地降低Mg合金的降解速率;在体积分数为25%的有无涂层合金浸提液中培养细胞4d,细胞相对增值率均超过100%,有无涂层合金的细胞毒性均为0级.     

Ni-W-Co三元合金镀层电镀工艺的研究

采用电化学沉积法在316L不锈钢基体材料上制备Ni—W—Co三元合金镀层。利用正交试验初步确定电镀液的配方。通过拉伸试验和电化学腐蚀试验分别测试镀层的结合性能和耐腐蚀性能。另外,测试了镀层的显微硬度。结果表明,镀液主要成分对镀层粗糙度影响程度大小为：硫酸镍 > 柠檬酸钠 > 光亮剂1 > 光亮剂2。镀液pH为5.0～5.5、电流密度为3 A·dm^—2时,镀层抗拉强度可达21 MPa。镀液的pH为5.0时,镀层硬度值最高。Na₂WO₄含量为30 g·L^—1时,镀层硬度高达590（HV）。CoSO₄含量为30 g·L^—1时,镀层的耐蚀性能最佳。     

铝型材模具盐浴氮化工艺研究

研究了过渡金属元素氧化物对铝型材模具在盐浴氮化中的影响。实验结果表明,过渡金属元素氧化物的加入可加速盐浴氮化的过程,具有催渗效果,并能改善其性能,满足铝型材模具盐浴氮化的技术要求,延长模具使用寿命。     

Examination of dynamic recrystallization during compression of AZ31 magnesium

This study aimed to investigate dynamic recrystallization(DRX)behavior during compression of magnesium alloy AZ31. Cylinder samples were cut from the extruded rod and hot rolled sheet AZ31 for compression test.The samples were compressed using a Gleeble 1500D at a temperature of 300℃and a strain rate of 0.01 s-1.Grain orientations and misorientation angles across grain boundaries for the tested samples were obtained by using electron backscatter diffraction(EBSD)technique.The results showed that strong basal texture was observed after 50%compression(ε=0.69)on both the extruded and hot rolled samples,which have different initial textures.It was observed that with increased strain,DRX grains gradually rotated to basal orientation,and grain boundaries with misorientation angle of near 30°was formed in the samples.At the strain of 0.69,a high fraction of high-angle(60°)boundaries was present in the extruded sample,whereas almost no high angle boundaries were observed in the hot rolled sheet sample.     

巨磁阻抗效应及其应用

近年来在FeCoSiB等非晶和纳米晶丝带中发现了巨磁阻抗效应,由于其灵敏度高,因而在磁传感器技术中有巨大的应用前景,受到国内外专家的广泛关注 本文简单介绍了巨磁阻抗效应的原理,并结合近年来具有巨磁阻抗效应的非晶和纳米晶铁磁合金的应用研究进展情况,提出了巨磁阻抗效应可能广泛应用的领域     

粉末烧结法合成FeSi_2合金的反应机理研究

对于按Si∶Fe=2∶1充分混合均匀的Fe-Si粉体,在传统粉末烧结FeSi2合金的过程中,随着温度升高,在690℃附近,首先发生的反应是:Fe+Si=FeSi,在850℃附近,发生的是FeSi和Si反应生成α相FeSi2.常规的固相烧结和激光烧结两种制备方法均证实:由高温向低温冷却的过程中α相的FeSi2均没有完成向β相的转变;在1 200℃附近Fe-Si处于液相状态时,Fe+2Si=FeSi2的反应是优先进行的;激光烧结可以直接生产α-FeSi2.     

蚀刻型高密度引线框架铜合金带材的研制进展

综述了蚀刻加工的工艺特点以及用于蚀刻型铜合金带材的特殊技术要求,分析了国内蚀刻型高密度引线框架铜带的研制进展及存在的问题。蚀刻型引线框架带材的产品质量与国外还存在一定差距,全蚀刻产品已实现国产化,产品质量有待提高;半蚀刻产品还处于研制阶段;板形控制、残余应力消减及均匀分布等核心技术有待突破;残余应力检测方法及检验标准有待建立。