Applications of Transition Metals in Organic Synthesis and Polymerization

1 Results Classic oxidants require rigorous control of the experimental conditions added with the problem of lack of selectivity. Catalysis by transition metals with environmentally safe oxidants provides synthetic routes to minimize pollution by giving environmental benign by-products. Fe (Ⅵ) is a powerful and a selective oxidant with Fe(Ⅲ) as a by-product, while hydrogen peroxide is clean with water as the only by-product. Separation of sodium or potassium ferrates requires tedious processes. Associat...     

一类特殊逆M-矩阵的判定

主要讨论了逆M-矩阵的判定，给出了一类逆为三对角矩阵的特殊逆坼矩阵，研究了该矩阵的一些特征和性质，存其特殊情况下便推出了D-型矩阵，从而间接的证明了D-型矩阵的一些优良的性质。     

关于可对称化矩阵的Weyl-Лидский型定理

建立了可对称化矩阵情形下的型定理和与近似不变子空间相关的特征值扰动分析.拓广了W Kahan的相应结果.     

奇摄动非线性微分方程周期边值问题解的估计

本文考虑一类二阶非线性微分方程奇摄动周期边值问题。利用微分不等式技巧,不仅研究了解的存在性,而且还给出解及其导数的估计,从而提供了研究解的导数估计的一种方法。     

利用积分算子方程的小波－矩量法分析频率选择反射面

小波－矩量法以小波基作为矩量法中的基函数，通过Ｇａｌｅｒｋｉｎ法可以获得很稀疏的阻抗矩阵，用迭代法求解时可减少计算机内存和计算时间。该文以有限尺寸的频率选择反射面为例，用小波－矩量法分析散射特性和电流分布，着重讨论了阻抗矩阵的稀疏化程度对计算精度的影响。结果表明，当非零元素仅为１０％时，仍能达到满意的精度，因此小波－矩量法不失为分析电大尺寸问题的一种有效方法     

一类拟线性耦合方程组的初边值问题

引用带权的Sobolev模和牛顿迭代格式,讨论了拟线性对称双曲抛物耦合方程组的初边值问题,得到了可微解的存在和唯一性定理。     

Cu（Ⅱ） effect on the conformation of regenerated silk fibroin in dilute aqueous solution

Much attention has been paid to the natural mechanism of silkworm spinning due to the impressive mechanical properties of the natural fibers. In this work, we studied the effect of Cu（Ⅱ） ions on the secondary structure of Bombyx mori regenerated silk fibroin （SF） in dilute solution by circular dichroism （CD）. The results indicate that a given amount of Cu（Ⅱ） induces the SF conformational transition from random coil to β-sheet, however, further addition of Cu（Ⅱ） is unfavorable for this conversion. Meanwhile, the conformational changes induced by Cu（Ⅱ） follow a nucleation-dependent aggregation mechanism, which is similar to that found in Prion protein （PrP） denaturation and Aβ-peptide aggregations, leading to the neurodegenerative disease. This work would help one understand further the natural spinning process of silkworm. Additionally, it would be significant for the study of the nervous system diseases, because silk fibroin, extracted in large amounts from Bombyx mori silkworm gland, could be a proper model to study PrP denaturation and Aβ-peptide aggregations.     

基础解系的一种算法

文章用矩阵理论得出几个新结论,从而应用新结论得出基础解系的一种算法.     

Glauber和Kawasaki动力学下正方格子上伊辛模型居里温度的蒙特卡罗计算

利用蒙特卡罗方法研究正方格子上的伊辛模型的相变问题．讨论了不同翻转方式(随机翻转和顺序翻转)以及不同动力学规则(Glauber动力学和Kawasaki动力学)对正方格子上的伊辛模型的居里温度Tc的影响．结果表明，当Glauber动力学占主要地位时，在两种翻转方式下都可以计算出居里温度Tc的值，当Kawasaki动力学占主要地位时，只能用随机翻转的方法获得居里温度Tc．