Mn^＋注入GaAs中Ga—Mn二十面体准晶的形成

利用选区电子衍射及明暗场电子衍射成像技术，在Ｍｎ＾＋注入ＧａＡｓ及随后退火的样品表层发现有二十面体准晶颗粒形成。能谱及电子能量损失谱分析表明，这些粒子不含Ａｓ，由Ｇａ和Ｍｎ元素组成，约含５０ａｔ％的Ｍｎ；其结构具有五次对称性和非周期分布的电子衍射斑点，这些具有２／ｍ３５↑－对称性的ＧａＭｎ准晶粒子同具有闪锌矿结构的ＧａＡｓ基体之间具有确定的取向关系：ｉ－５↑－／／〔１１０〕ＧａＡｓ；ｉ－３↑－／／     

BCN薄膜的硬度和剩余应力的研究

类金刚石结构的立方“BCN”材料由于兼有金刚石和立方氮化硼超硬、低摩擦的优点, 如有低摩抗磨、高的热稳定性和化学稳定性,并克服了它们的缺点,因而BCN薄膜材料被作为耐磨保护层,在电学、光学方面的性能也得到广泛应用。应用反应磁控溅射法将高质量的BCN 薄膜沉淀在硅基底上,通过用微压痕测量和弯曲技术研究了他们硬度和剩余应力,发现施于薄膜沉淀物上的偏压对其硬度和剩余应力均有重要影响。     

负偏压对六方氮化硼薄膜沉积特性的影响

利用射频磁控溅射法在n型Si(100)衬底上沉积六方氮化硼薄膜(h-BN),采用AFM、Raman、XPS、FTIR等技术研究负偏压对所沉积薄膜生长模式、结构、表面粗糙度、薄膜取向、相变等特性的影响。结果表明,当负偏压为0V时,沉积所得h-BN薄膜表面粗糙度较低、结晶性良好、c轴垂直于衬底且以层状模式生长;随着负偏压的增加,薄膜由层状模式生长转变为岛状模式生长,表面粗糙度增加,且h-BN经亚稳相E-BN和wBN向c-BN转变,使得BN薄膜相系统更加混乱,不利于高质量层状h-BN薄膜的获取。     

Ga12－nAs n（n＝0～12）系列团簇基态结构及稳定性的研究

在基于第一性原理的ADF程序平台上,对Ga12－n Asn （n＝0～12）系列团簇的基态结构、能量、能隙、电离能和亲和势等物理性质进行了随机筛选和精确计算．对结果的分析表明,随着 n的增加,团簇的总能量几乎呈线性下降,电离能从5．9eV上升到7．3eV,亲和能在2．0～2．7eV之间波动,电离能比亲和能大,HO‐MO‐LUMO能隙从0．6 eV上升到2．2 eV ,并在 n＝4～9之间,呈现明显的奇偶性振荡,与能量的二阶差分所显示的相一致,表明在 n＝3、5、11处团簇将具有较高的稳定性．     

Spatial and temporal distribution of trace elements in Yangtze Estuary, China: Significance of diluted setting

The present study is to examine the spatial and temporal distribution of eight trace elements (Sr, Ba, B, Ga, Ni, V, Cu, and F) in various Holocene marine subfacies in the Yangtze Estuary, including its subaqueous delta by sediment borehole and vibrocore. Results demonstrate that grain size is the determinant factor in controlling the concentration of most trace elements discussed. Prodelta mud that occurs usually below the normal wave base can serve as a depository sink for trapping trace elements over the long-term time period. For example, copper concentration is 5-6 times higher than those found in the estuarine sediment. Boron, which is used to be a salinity indicator, shows a strong negative correlation with paleosalinity (using sediment phosphate method), implying desalinized water setting in the Yangtze Estuary, into which a large quantity of the Yangtze freshwater (924 × 10⁹ m³/a) has discharged. Trace element concentrations of the study area were compared with those collected from the middle and lower Yangtze River reaches, and from the east China continental shelf, including the Okinawa Trough. Result tends to show a terrigenous derivation of most geochemical components of the study area. Concentrations of strontium and barium are correlated with an increase in distance away from the estuary, rather than affected by grain size. Variation of trace elements in downcore Holocene sediment sections are fairly consistent with concentrations revealed by the modern vibrocore transect that extends from nearshore delta front, to offshore prodelta and to the delta-shelf transit zone. The overall distribution of geochemical elements discussed is capable of environmental implication to characterize the Yangtze estuarine transit between land and sea.     

电致发光材料酚基-吡啶硼配合物的合成及发光性能

合成一种新型硼配合物蓝光电致发光材料（酚基吡啶氟化硼PPBF₂, PP： 2-(2-酚基吡啶)）. 配合物PPBF₂在溶液和固态下均显示强的蓝色荧光（440 nm）. 用PPBF₂作发光层电发光器件, 依靠不同器件结构能显示不同颜色的发光.     

硫铝酸钙水泥制备及贝利特掺硼活化

采用粘土、铝矾土、碳酸钙为主要原料制备以贝利特（C2S）、硫铝酸钙（C4A3S?）和铁铝酸钙为主导矿物的水泥熟料（BCSAF）,分析熟料矿物组成对水泥净浆抗压强度发展的影响,并通过硼（B）掺杂对贝利特矿物进行活化,研究其对于熟料烧成工艺及水化性能的作用机理。采用X射线衍射、扫描电子显微镜和差热-热重分析等测试方法表征熟料组成与结构。研究结果表明：C4A3S?有助于BCSAF水泥早期强度发展,而C2S主要影响BCSAF水泥的后期强度,铁铝酸钙有助于熟料烧成中的传质过程,但含量过高时,不利于获得具有较高水化活性的C2S。掺杂B可在常温下稳定α’-C2S,活化贝利特矿物,提高BCSAF水泥熟料早期水化活性,同时降低烧成反应温度,促进反应进行,减少硅铝酸钙（C2AS）过渡相的生成,而显著提高水泥3d抗压强度。     

无定形硼粉的HTPB团聚新方法改进

以端羟基聚丁二烯（HTPB）为主要原料,乙醇、乙酸乙酯为溶剂,对无定形硼粉进行了团聚改性处理,研究了团聚改性后硼粉对密度的影响,采用XPS光电子能谱,透射电镜、红外光谱等手段分析了硼粉改性效果,总结了其相关性能的表征结果,并对无定形硼粉改性前后与HTPB混合物黏度进行了测试分析。结果表明,无定形硼粉团聚改性后,硼粒子的球性度提高,松装密度大大增加,其表面明显有一层包覆层,而且与HTPB混合物的黏度较无定形硼粉的大大降低,这对制备推进剂药浆工艺性能有利。