中空纤维膜萃取器内流动特性

对中空纤维膜器内流动特性的研究是膜器设计和放大的基础。该文通过测量装填因子不同的 3个聚丙烯中空纤维膜萃取器壳程和管程的停留时间分布曲线 ,研究了不同流速下膜器的流动状况 ,并用轴向扩散模型描述了流动的非理想性。结果表明 ,中空纤维膜萃取器的管程和壳程流动与理想平推流和理想全混流相差较大 ,装填因子与流速对二者均有较大影响。采用轴向扩散模型得到的响应曲线的计算值与实验值符合较好 ,且中空纤维膜萃取器中轴向返混的影响不可忽略。     

Is there an anatomical endophenotype for neurodevelopmental disorders？ A review of dual disorder anatomical likelihood estimation （ALE） meta-analyses of grey matter volumes

The term "neurodevelopmental disorder" broadly encompasses conditions thought to arise early in development and includes schizophrenia, bipolar disorder and autism among others. These conditions share a number of genetic and environmental risk factors postulated to lead to common difficulties in socio-emotional processing, communication and cognitive function. The alternative position is that, while the same traits are affected across these conditions, the nature or direction in which they are modified may be distinct. MRI studies provide a rapidly expanding and rich database which we propose can be used to contribute to this debate. Anatomical likelihood estimation (ALE) is a method of meta-analysis applied to voxel-based MRI studies. We have adapted this method to explore the extent to which schizophrenia and bipolar disorder and schizophrenia and autism share a common brain structural phenotype. We will review this work here and discuss whether there is sufficient other evidence to justify a common framework for further research into the inter-relatedness of such conditions.     

Pyrolysis of Iron(III) porphyrin coated Pt/C toward oxygen reduction reaction in acidic medium

Design and synthesis of highly active and durable electrocatalysts toward oxygen reduction reaction (ORR) is of particular importance for proton exchange membrane fuel cells (PEMFCs), yet remains a grand challenge. Herein, we report the deposition of iron (III) porphyrin (FeP) on house-made Pt/C by rotary evaporation of the mixture of FeP and house-made Pt/C dispersed in chloroform, followed by pyrolysis at 650 °C in argon atmosphere. This approach led to the synthesis of new non-precious metal electrocatalyst (NPME)-Pt/C composites (Pt/C–FeP) with an average nanoparticle diameter of 3.1 ± 1.5 nm without aggregation. According to X-ray photoelectron spectroscopy (XPS), the binding energy of Pt 4f_7/2 became larger due to the presence of pyrolyzed FeP. In addition, the electrochemically active surface area (ECSA) of Pt/C–FeP-650 is 65 m²/g less than that of house-made Pt/C (80.2 m²/g). This implies that the pyrolyzed FeP may have partially covered the surface of Pt nanoparticles and thus lowering the ECSA. Interestingly, the mass activity (MA) of Pt/C–FeP turns out to be 349.0 mA/mg_Pt @0.9 V vs. RHE, which is 2.6 times and 1.5 times of house-made Pt/C and commercial Pt/C, respectively. It is speculated that the electronic interaction and possible synergy between Pt and pyrolyzed FeP as NPME might have contributed to the ORR activity improvement despite of partial loss of ECSA. During accelerated durability tests (ADTs), the MA of Pt/C–FeP-650 degrades 64.3% inferior to commercial Pt/C (52.2%). The main reason likely arises from the degradation of pyrolyzed FeP, which is a bottleneck problem confronting NPMEs.     

C度规(m=0,e≠0)的时空结构

采用ｘ－ｙ方块图及虚Ｗｅｙｌ坐标的方法研究了Ｃ度规（ｍ＝０，ｅ≠０）的时空结构，特别研究了Ｃ度规（ｍ＝０，ｅ≠ｍ）的视界内部区域，进一步证明了用这２种方法所描述的时空区域是完全相同的．     

大型挑檐式膜结构制造与施工的质量控制

大型挑檐膜结构施工的质量关键技术：膜结构作为一种新型的结构体系,在大跨度,大悬挑空间结构中应用越来越广泛,例如奥运场馆＂鸟巢＂和＂水立方＂都是膜结构的代表作。本文依据本人多年的工程实践,论述膜结构在施工质量控制的施工技术,总结膜结构施工质量的具体技术经验。为该类型结构在制造与施工的质量控制应用提供了依据。     

尼龙PA6/CuCl_2复合膜表面金属化研究

以聚己内酰胺(尼龙6,PA6)为基体制备PA6/CuCl_2复合膜,在NaBH_4溶液中用化学还原法制得导电薄膜。研究了复合膜组成、还原剂浓度、还原时间、还原温度对导电薄膜表面电阻的影响,得到较优的反应条件:温度为35℃-40℃,PA6与CuCl_2的质量比为5:1,还原剂浓度0.1%,还原时间90 s-100s,测得薄膜的最小电阻为2Ω/cm~2-5Ω/cm~2。     

膜分离在生物工程应用中存在的问题及对策

膜分离作为一种高新的分离技术，可用于化工、食品、医药、环保、生物工程等方面的物质分离、提纯和净化。文章较为全面地分析了膜分离在生物工程应用中存在的问题，即主要是菌体的吸附、粘附使膜过滤流速下降、膜分离精度不高等。并分析了解决上述问题的方法与思路。     

N80油管钢腐蚀产物膜的研究

通过分析腐蚀产物膜的结构、成分及影响因素.对不同环境和条件下N80油管钢腐蚀产物膜进行了研究.