Enatioselective[2 2 2] Cycloaddition as A Synthetic Tool

1 Results Transition metal-catalyzed [2 2 2] cycloaddition is one of the most efficient protocols for the construction of six-membered ring system.Our group has comprehensively studied various types of highly enantioselective [2 2 2] cycloaddition for the synthesis of chiral cycloadducts; we already reported an iridium-catalyzed intermolecular [2 2 2] cycloaddition between α,ω-diynes,having various tethers and substituents on the alkyne termini,and monoalkynes,possessing oxygen or/and nitrogen functiona...     

抗冰导管架平台结构动力安全评估

基于现场冰激振动监测资料，论述了抗冰导管架平台进行动力失效评估的必要性，分析了在动冰荷载作用下抗冰导管架平台的动力失效模式，指出动力失效模式主要包括振动失效模式和疲劳失效模式，并介绍了基于现场实测冰力数据建立的直立结构冰力谱的计算方法．作为应用实例，利用ANSYS软件建立了Jz9—3GCP平台的有限元模型，分析了其结构特性，并对其进行动力结构安全评估． 此方法对于抗冰平台的设计和安全评估具有一定的借鉴意义．     

组合柱内力分析

通过理论与电测实验方法，分析完成了组合柱结构在承担外来荷载作用时的内力分量计算，验证了其内力分析及分布规律的正确性。     

旧桥结构内力及变形的非线性影响

采用材料非线性理论,从刚度退化的角度考虑了结构损伤的累积效应,分析了既有钢筋混祆凝土刚架拱桥结构内力及变形,并依托实体工程进行了结构损伤诊断的数值模拟和非线性分析计算.结果表明,考虑结构损伤的累积效应和材料的非线性性质,结构的内力重分布显著,开裂单元范围加大,适用性能和耐久性能降低,这与实桥检测结果吻合.因此,对钢筋混凝土旧桥进行静力评价或拟定加固方案时,应当考虑结构内力及变形的非线性影响.     

冗余并联机床驱动力优化解析

驱动冗余可有效消除并联机构在作业空间中的奇异位形,但其导致驱动力分配不唯一。该文针对一台4自由度的冗余并联机床进行了驱动力解析。在运动学分析基础上,得到各支链的偏速度矩阵及偏角速度矩阵,解算各支链的合力/力矩,利用虚功原理建立了该机构的逆动力学方程,并将其变换为线性格式,然后针对驱动冗余的特点,对驱动力分别进行了力优化及能耗优化,其中,力优化计算简单,而能耗优化可降低最大驱动力。该模型适用于冗余并联机构的动力学参数辨识以及动力学控制。     

二氧化碳在金属丝网的毛细动力学实验与分析

二氧化碳(CO2)作为制冷剂具有环保及良好的热力特性,已经越来越受到重视,并将率先应用在航天毛细驱动的两相循环冷却技术(CPL)和环路热管(LHP)中,但是由于它的工作压力较高,对其毛细动力特性研究还没有实验支持。文章的目标是通过实验测量CO2在不锈钢丝网爬升的动态结果,进行毛细上升的动力学分析,并将实验结果与几个经典的公式进行比较,找出最佳适用公式。     

Influence of long-period pesticide force on genetic polymorphism of wolf spider Pardosa pseudoannulata (Lycosidae: Araneae)

Wolf spiders are predators in large quantities in the fields. How wolf spiders keep their dominant species status under long-period pesticide force? To answer this question, eight geographical populations of Pardosa pseudoannulata were used as materials to test the influence of geographical habitats on their genomic DNA polymorphism. The RAPD pattern showed polymorphic variations among and within different populations. Total 84 bands amplified by 10 random primers, of which 62 (73.81%) are polymorphic, were generated from 55 individuals of eight geographical populations. Meanwhile, Shannon’s index (Ho= 0.5177) showed a rich genetic diversity of P. pseudoannulata, and most of the genetic variation (64.24%) was found within populations. Multiple regression analysis suggested that it is the climatic variation (such as annual average temperature etc.) that results in adaptive eco-geographic differentiation, and it is the long-period pesticide force that speeds up the genetic differentiation of P. pseudoannulata which changed the genetic diversity of the population.     

磁场中弱电离气体二维平板超音速边界层扰动演化研究

数值模拟了6种不同外加磁场下M∞=4．5、弱电离的二维平板边界层的基本流场及边界层中第二模态不稳定波的非线性演化。发现：外加磁场使边界层附近同—γ处的流向速度减小从而使边界层的厚度增加；很大程度地改变法向速度；壁面摩擦系数减小；很大程度地抑制第二模态不稳定波的增长。这些影响主要决定于外加磁场的强度，而对外加磁场的产生方式不很敏感。外加磁场的存在还使得压力产生波动，在边界层内，压力波峰的位置与流向磁场力绝对值极大的位置基本一致；在边界层外，压力波峰的位置滞后于流向磁场力绝对值极大的位置，并且离边界层越远，这种滞后就越明显。     

基于法向力活动轮廓模型的医学图像分割

提出法向力活动轮廓模型并应用到医学图像分割中，实验结果表明该模型能扩大初始轮廓曲线收敛范围，正确分割侧脑室图像．而且，初始轮廓曲线愈接近目标真实边界，迭代次数愈少，分割速度愈快．     

Exoskeleton arm with force feedback for robot bilateral teleoperation

A novel 6 degrees of freedom (DOFs) wearable exoskeleton arm,ZJUESA,based on man-machine system is present- ed.It can be used in robot bilateral teleoperation as master arm with force-feedback.With introducing the revolute-prismatic-spherical (RPS) parallel mechanism and planetary gear mechanism,it is designed based on the anatomy of human upper-limb.With the sensors on this external mechanical structure,the human operator motion is detected and converted to the slave robot control command.Additionally the pneumatic system on it generates a force feedback by using hybrid fuzzy control.As a result,the human operator may have a feeling of doing the work directly.