Preparation and properties of antimony thin film anode materials

Metallic antimony thin films were deposited by magnetron sputtering and electrodeposition. Electrochemical properties of the thin film as anode materials for lithium-ion batteries were investigated and compared with those of antimony powder. It was found that both magnetron sputtering and electrodeposition are easily controllable processes to deposit antimony films with flat charge/discharge potential plateaus. The electrochemical performances of antimony thin films, especially those prepared with magnetron sputtering, are better than those of antimony powder. The reversible capacities of the magnetron sputtered antimony thin film are above 400 mA h g^-1 in the first 15 cycles.     

中间相沥青基介孔炭的表征及其用作锂离子电池负极材料的电化学性能

以中间相沥青为碳源、CaCO_3为模板,制备中间相沥青基介孔炭(MPMC)。采用XRD、SEM、TEM等手段表征所制介孔炭的结构和形貌,并将其用作锂离子电池的负极材料,测试电化学性能。结果表明,所制MPMC具有丰富的介孔结构和较大的比表面积及孔体积,随着CaCO_3质量分数的增加,MPMC的比表面积和孔体积先增加后减小,当CaCO_3的质量分数为70%时,所制MPMC的比表面积和孔体积最大;MPMC用作锂离子电池负极材料具有良好的电化学性能,能有效提高锂离子电池的可逆比容量,具有良好的循环稳定性和倍率性能。     

泡沫铝表面处理电解着金黄色试验研究

讨论了泡沫铝着金黄色的工艺过程,泡沫铝经过脱脂、蚀洗、中和、阳极氧化、电解着色和水合封孔等一系列表面处理过程,可在其表面生成均匀的金黄色薄膜,使其美观耐用。     

赤泥的沉积作用及其力学性质演变

从赤泥的沉积条件、赤泥的结构,密实度,固结排水抗剪强度着手,研究赤泥由流体变为固体具有较高强度的工程力学性质的自然演变过程,为利用赤泥筑坝,加高赤泥坝设计,提供理论依据。     

砂与淤泥互层地基中基坑边坡变形特征

以海口市某砂与淤泥互层地基深基坑工程为背景,通过对其施工期间动态监测数据的分析,总结了该深基坑工程的支护结构变形、周边地表沉降变形及水位变化等特征.分析结果表明:支护结构变形主要发生在基坑开挖阶段,最大水平位移位于长边中心处;基坑开挖的影响范围主要集中于0~2 H处(H为基坑开挖深度),最大可延伸至距基坑边缘约为3 H处,产生最大沉降量位置约为支护结构后0.7~0.9 H处;基坑开挖引起的周边水位变化较小,10月份水位变化波动较大,11月后水位比较稳定.     

Ultra fast microwave-assisted leaching for the recovery of copper and tellurium from copper anode slime

The decomposition of copper anode slime heated by microwave energy in a sulfuric acid medium was investigated. Leaching experiments were carried out in a multi-mode cavity with microwave assistance. The leaching process parameters were optimized using response surface methodology (RSM). Under the optimized conditions, the leaching efficiencies of copper and tellurium were 99.56% ±0.16% and 98.68% ±0.12%, respectively. Meanwhile, a conventional leaching experiment was performed in order to evaluate the influence of microwave radiation. The mechanism of microwave-assisted leaching of copper anode slime was also investigated. In the results, the microwave technology is demonstrated to have a great potential to improve the leaching efficiency and reduce the leaching time. The enhanced recoveries of copper and tellurium are believed to result from the presence of a temperature gradient due to the shallow microwave penetration depth and the superheating at the solid-liquid interface.     

生物酶技术在火山岩气藏筛管水平井解堵应用

根据长深气田Ⅰ类火山岩气藏自然产能较高,采用水平井筛管完井,但在钻井过程中泥浆污染严重,使储层受到伤害,影响了自然产能的发挥.为解除钻井泥浆在井壁产生的泥浆滤饼的侵蚀,恢复储层的渗透能力,针对水平井筛管完井的实际情况,应用生物酶对钻井泥浆体系聚合物分子链的降解作用可解除泥浆滤饼污染的特点,进行了室内实验与现场应用.该生物酶解堵技术在吉林油田火山岩气藏水平气井现场应用,成功解除了储层污染,恢复了水平井的自然产能,为长深气田Ⅰ类火山岩气藏水平井产能发挥开辟了新途径.     

高性能锂离子电池SiO/C复合负极材料研究

以SiO为硅源,柠檬酸为碳源,通过高能球磨和高温热解制备了一种循环性能优异的锂离子电池SiO/C复合负极材料.采用X-射线衍射仪（XRD）、扫描电子显微镜（SEM）对复合材料的物相和形貌进行了表征.具有孔状结构的柠檬酸热解碳对纳米SiO不仅具有良好的包覆效果,也能有效缓冲电化学嵌脱锂过程中硅颗粒释放出来的体积变化.电化学性能测试表明,SiO/C复合负极材料电极循环100次后容量仍高达803.1mA.h/g,容量保持率为89%.     

MnO/石墨烯复合材料的制备及其作为锂离子电池负极的研究

通过原位复合方法合成碳包覆MnO/石墨烯(C@MnO/GN)复合材料并探究其作为锂离子电池负极材料的电化学性能.扫描电子显微镜(SEM)以及透射电子显微镜(TEM)表征结果表明,MnO纳米颗粒(直径约为30~50nm)均匀分散在石墨烯片层上,且颗粒外面包裹一层厚度约为5nm的碳层.电化学测试结果表明该材料作为锂离子电池负极具有优异的倍率和循环性能.0.2和0.5A/g电流密度下,比容量分别为800和700mAh/g;10A/g电流密度下比容量仍能保持在372mAh/g;当电流密度调回0.5A/g时,其比容量仍能恢复到730mAh/g.该材料也表现出优异的循环性能,在5和10A/g电流密度下依次循环100圈,容量保持率几乎100%.     

深层爆炸挤淤法处理软弱地基

爆炸挤淤法在处理海岸、河岸水下软弱地基方面得到了广泛的应用和发展,本文介绍了爆炸挤淤法在珠海市湾仔海堤工程软弱地基处理中的应用.