自蔓延高温合成Ti/Al_2O_3金属陶瓷复合材料的研究

本研究利用Al/TiO_2自蔓延高温反应直接一步合成了极细Ti/Al_2O_3金属陶瓷复合粉末和复合材料块。运用X光衍射和电镜扫描对制备的材料进行了物相组织结构分析。结果表明:用自蔓延高温合成法可以制备结构独特的极细Ti/Al_2O_3金属陶瓷复合粉末;制备的Ti/Al_2O_3金属陶瓷复合材料较致密、细小的Al_2O_3粒子分布均匀。最后用燃烧波前沿激冷淬火法结合差热分析对反应过程进行了分析探讨。     

Fabrication and magnetic properties of Co nanowire arrays of different crystal structures

It is important to find some developing high-density magnetic recording materials in magnetic recording field with the development of information and technique, in which vertical magnetic recording is a very important way and has received considerable attention[1—3]. The vertical magnetic recording materials require high squareness, suitable coercivity, and small size of storage element[4]. Someone used nanoporous anodic aluminum oxide as templates to fabricate uniform arrays of multi magneti…     

固溶处理对7A55铝合金断裂韧性的影响

采用金相组织观察、拉伸实验、Kahn撕裂试验、扫描电镜、透射电镜等方法研究固溶处理对7A55铝合金断裂韧性的影响。研究结果表明:固溶温度对7A55铝合金断裂韧性影响显著,7A55铝合金在450～490℃时固溶,随着温度上升,可溶性粒子减少,断裂韧性增加,到480℃时断裂韧性达到最大值;当温度超过480℃时,由于晶粒的长大,断裂韧性又开始下降;7A55铝合金有很大的淬火敏感性,当以慢速淬火时,晶界非共格析出物尺寸粗大,对断裂韧性不利。     

Authigenic sulfide minerals and their sulfur isotopes in sediments of the northern continental slope of the South China Sea and their implications for methane flux and gas hydrate formation

This is a report of the study of the authigenic sulfide minerals and their sulfur isotopes in a sediment core (NH-1) collected on the northern continental slope of the South China Sea, where other geo-physical and geochemical evidence seems to suggest gas hydrate formation in the sediments. The study has led to the findings: (1) the pyrite content in sediments was relatively high and its grain size relatively large compared with that in normal pelagic or hemipelagic sediments; (2) the shallowest depth of the acid volatile sulfide (AVS) content maximum was at 437.5 cm (>2 μmol/g), which was deeper than that of the authigenic pyrite content maximum (at 141.5-380.5 cm); (3) δ 34S of authigenic pyrite was positive (maximum: 15‰) at depth interval of 250-380 cm; (4) the positive δ 34S coincided with pyrite enrichment. Compared with the results obtained from the Black Sea sediments by Jorgen-sen and coworkers, these observations indicated that at the NH-1 site, the depth of the sulfate-methane interface (SMI) would be or once was at about 437.5-547.5 cm and the relatively shallow SMI depth suggested high upward methane fluxes. This was in good agreement with the results obtained from pore water sulfate gradients and core head-space methane concentrations in sediment cores collected in the area. All available evidence suggested that methane gas hydrate formation may exist or may have existed in the underlying sediments.     

用铝渣和石灰对铁水预脱硫的热力学

通过热力学计算分析了Al在铁水中与氧和硫反应的平衡活度,当CaO和Al同时加入铁水中,适量的Al会提高CaO的脱硫能力.探讨了在Al的参与下,CaO作为脱硫剂时的脱硫热力学反应机理,以及Al2O3和CaF2对铁水脱硫的作用.     

Al—Ti—CN细化工业纯铝工艺参数测定

继Al—Ti—C中间合金之后,又开发了Al—Ti—CN中间合金,通过大量细化工业纯铝试验,从中间合金加入量、加热温度、保温时间等工艺试验,找出Al—Ti—CN中间合金细化工业纯铝的最佳工艺.对Al—Ti—CN用于工业生产提供有益参数.     

含磷洗涤助剂的性能及作用

简述洗涤剂组成、各组分作用;比较正磷酸盐、多聚磷酸盐的助洗性能;介绍三聚磷酸钠的结构、性质、作用及对环境的影响。     

超临界流体干燥半工业化在氧化铝粉体制备上的应用

醇洗后的拟薄水软铝石(Al2O3·XH2O)的醇凝胶,采取超临界流体干燥处理技术制得了超细氧化铝粉体。采用透射电镜对试验粉体粒子的大小和分散度进行了表征,结果表明:在260℃×7MPa×1h.的超临界流体条件下,得到平均粒度小于10nm,高的比表面积的纤维状Al2O3粉体。有效地改善了粉体的团聚程度。     

韧性断裂机理的理论探讨与基于铝合金薄板韧性断裂准则的修正

对韧性材料的断裂机理进行理论研究.当裂纹尖端附近两个相邻的材料微单元体的破坏面共面或共线时,裂纹可以通过破坏面扩展并传递到相邻的单元;当两个单元体的破坏面与两单元体中心线成一定角度时,两单元体之间将产生相对滑动或旋转,使得两破坏面之间重新共面或共线,从而使得裂纹可以扩展,形成一个连续的裂纹开裂面.基于铝合金6063薄板修正韧性材料的断裂准则,并用简单的平面应力状态下的平板拉伸试验和平面应变状态下的缺口拉伸试验,结合有限元ABAQUS计算求得韧性断裂准则中的材料常数.     

天然气水合物渗流特征及其描述

天然气水合物渗流是一个多相多组分非等温的物理化学渗流过程,这个过程包含了相变、能量变化以及储层介质的物理性质的变化。提出了天然气水合物藏孔隙度、渗透率、饱和度等参数的定义方式。应用渗流力学理论,结合水合物开采方式,对其渗流过程进行了描述,建立了天然气水合物藏开采的基本数学模型,并探讨了目前天然气水合物渗流研究存在的问题,为下一步天然气水合物藏的物理模拟和数值计算提供了理论基础。