蓖麻油烷醇酰胺硼酸酯(RAB)的合成

本文以蓖麻油为原料，通过醇解，酰胺化得到蓖麻油烷醇酰胺（ＲＡ），ＲＡ与硼酸进行酯化反应，最终合成了一种新型的有机硼表面活性剂———蓖麻油烷醇酰胺硼酸酯（ＲＡＢ）。并确定了工艺条件：ＲＡ∶Ｈ３ＢＯ３＝２∶１，温度１３０～１４０℃。对产物ＲＡＢ用红外光谱，核磁共振作了表征。     

A位La和Dy替代Bi2O3-ZnO-Nb2O5陶瓷结构及介电性能的研究

研究了A位La,Dy替代对BZN基陶瓷结构和介电性能的影响.在替代量x≤0.2的范围内,La替代样品均保持单一的立方焦绿石结构;在x<0.15的范围内,Dy替代样品为单一的立方焦绿石相;当x=0.2时,结构中出现杂相.随着La、Dy替代量的增加,陶瓷样品的晶粒尺寸、密度和介电性能发生有规律的变化;低温介电弛豫峰的峰形逐渐宽化;La替代样品的峰值温度向低温方向移动,Dy替代样品的峰值温度向低温方向移动.与x为0.1、0.15和0.2相对应的La替代样品弛豫峰峰值温度tm分别为-95℃,-99℃,-104℃,Dy替代样品弛豫峰峰值温度tm分别为-96℃,-89℃,-85℃.     

新的三类Abel型微分方程的求积定理

借助变量替换法、交换变量位置法、高次二项式定理等方法，在一定条件下，给出新的三类Abel型微分方程，论证它们的可积性，并提供其通积分的表达式，扩充了微分方程的可积类型．     

Microstructure characterization and hydrogen storage properties study of Mg2Ni0.92M0.08 (M = Ti, V, Fe or Si) alloys

In the present study Mg_2Ni-type compounds alloyed independently with Ti,V,Fe and Si were successfully prepared by wet-milling followed by sintering.Although these alloyed Mg_2Ni compounds exhibited a similar hydrogen storage mechanism as that of pure Mg_2Ni,the dissolution of Ti,V or Fe into the Mg_2NiH_4lattice had a considerable catalytic effect on hydrogen desorption from additional MgH_2.The further structure investigations clearly indicated that the substitution of Ti for Ni could suppress the formation of the micro-twined low-temperature phase(LT2)and promote the formation of the high-temperature phase(HT),thus resulting in remarkably improved hydrogen desorption kinetics for the Mg_2Ni_(0.92)Ti_(0.08)–H system.     

Effect of Mg substitution for La on microstructure, hydrogen storage and electrochemical properties of La1−xMgxNi3.5 (x=0.20, 0.23, 0.25 at%) alloys

The effect of Mg substitution for La on microstructure, hydrogen storage and electrochemical properties of the annealed La_(1-x) Mg_x Ni_3.5(x=0.20, 0.23, 0.25 at%) alloys have been studied. All the samples were mainly composed of(LaMg)_2Ni_7,(LaMg)Ni_3, and LaNi_5 phases. Mg substitution for La changed the phase abundance, but did not change the constitution of all phases, which is con fi rmed by the results of backscattered SEM images and EDS analysis. The P–C isotherms indicated that the La_(1-x) Mg_x Ni_3.5alloys reversibly absorbed and desorbed hydrogen smoothly at 298 K. The hydrogen absorption cyclic stabilities of La_(1-x) Mg_x Ni_3.5alloy after 5 hydrogen absorption/desorption cycles reached the maximum values of91.9% and 96.0% at 298 K and 323 K, respectively. The hydrogen desorption capacity and plateau pressure for the La_(1-x) Mg_x Ni_3.5alloy reached the maximum values of 1.055 H/M and 0.074 MPa, respectively. The desorption capacities of La_(1-x) Mg_x Ni_3.5reached 0.193 H/M and 0.565 H/M in the fi rst minute at 298 K and 323 K, respectively. Electrochemical property measurement indicated that La_(1-x) Mg_x Ni_3.5(x=0.20,0.23, 0.25 at%) alloys possessed excellent activation capability and were completely activated within3 cycles. Discharge capacities of La_(1-x) Mg_x Ni_3.5alloys reached 378.2 m A h/g(x = 0.20 at%), 342.7 m A h/g(x = 0.23 at%), and 369.6 m A h/g(x = 0.25 at%), respectively. Moreover, energy density of La_(1-x) Mg_x Ni_3.5alloy was much larger than that of La_0.80Mg_0.20Ni_3.5 alloy and nearly approaches the maximum value of La0.75Mg0.25Ni3.5. Thus, the La_(1-x) Mg_x Ni_3.5alloy exhibits optimum comprehensive properties of hydrogen storage and electrochemistry.     

π0与N- (N-)重整化链传播子的"精确"收敛公式与辐射修正

采用中性介子π0与核子(N-)反核子-N强相互作用Lorentz不变耦合模型,对π0与N- (N-)两类重整化链图传播子函数级数收敛性问题作了全面考察与深入研究,并利用链图传播子函数的精确理论计算结果,通过相关理论分析、推导后获得重整化链图传播子函数级数"精确"收敛公式;在此基础上又对两类重整化链图传播子"辐射修正"问题作了理论计算与分析.     

纤维素月桂酸酯的制备及其结构和性能表征

在均相体系下,以微晶纤维素为原料,以月桂酰氯为酯化试剂,吡啶为催化脱酸剂制备纤维素月桂酸酯,研究了酯化试剂用量、反应温度、反应时间对纤维素月桂酸酯取代度和得率的影响,确定了合成纤维素月桂酸酯的适宜条件为：酰氯用量16 mol（基于纤维素上羟基摩尔数）,反应温度100 ℃,反应时间10 h,此时纤维素月桂酸酯的得率为3108 %,取代度达248。采用红外光谱和核磁共振氢谱对纤维素月桂酸酯的结构进行了表征,证明了纤维素已发生酯化反应。接触角实验结果表明,所得纤维素月桂酸酯的接触角随取代度增加而增加,取代度>16时产物具有极强的疏水性。     

专家系统规则启发式划分和并行推理

本文提出了一个启发式规则划分办法并分析了并行规则推理的代价,设规则集合被划分为π=(π_1,π_2,…,π_k),则对于任何一个规则R_i∈π_i,在π_(i-1)中至少有某个R_i,R_i与R_i在某种代换下相关,如果串行推理对规则进行一次遍历所费时间代价为C,对于同样规则划分π进行多处理机或进程并行推理一遍遍历代价至多为C′,C′≤(k/~#R)C。其中~#R是规则集合R的基数,同时给出一个实例和推理代价的实验数据。     

关于生产函数的理论构架：与周方同志商榷

本文指出由周方同志关于生产函数的理论构架的公理化系统,不可能得出C—D函数是唯一的生产函数的结论。本文证明了C—D函数是唯一的生产函数的充要条件是要素弹性为常数。文中构造了两类满足上述公理化系统而替代弹性可以不是常数的生产函数。     

关于ln2的渐近展开公式

通过引进变量代换和级数求和法得到ｌｎ２的若干新的渐近展开式，并且比较了计算ｌｎ２的收敛速度。所得结果有利于计算和判断收敛速度，对估计ｌｎ２近似计算中的误差提供了依据。