噻唑烷并手性恶唑硼烷催化剂结构和性质的量子化学研究

采用量子化学从头计算方法研究了噻唑烷并手性恶唑烷催化剂及其硼烷加合物的结构和性质，选用Hartree-Fock方法从6-31g基组下进行了全优化计算，并计算了催化剂其加合物的红外振动光谱，催化剂具有扭曲的椅式构型，与硼烷在N原子处配位形成加合物，反应是放热的，加合物的形成，一方面使得催化剂上B原子所带正电荷增加，有利于与酮羰基氧的配位反应进行；另一方面使得BH3中B-H键被削弱，有利于后续反应中H从BH-3到酮羰基碳的转移，从而增强了催化反应的活性。     

合成表面活性剂烷基多苷的催化剂研究

对以木薯淀粉和十六醇为原料合成表面活性剂－烷基多苷(APG）的催化剂进行了研究，试验结果表明，无机酸催化剂以硫本为好，有机酸催化剂以对甲苯磺酸为好，复合催化剂以硫酸－磷酸为好。     

江油地区含硫酸盐岩浅层地下水中CaCO3析出的化学热力学机理

含硫酸盐岩浅层地下水一般存在于该矿物的溶孔与裂缝之中，同时它的表面又有大量的ＣａＣＯ３ 析出．本文仅从化学热力学的角度解释这一特征地貌的形成     

Investigation of microenvironment-depended photoluminescence in Eu3+-implantation of GaN

GaN thin films grown on sapphire were implanted by Eu~3+ with three different fluences (5.0×10~14 , 2.5×10~15 and 5.0×10~15cm~-2 ). The photoluminescence (PL) spectra show that, after annealing, the samples exhibit strong emission at around 622.0 nm under 325 nm laser excitation. The intensity of this emission increases by one order of magnitude after annealing at from 600 ℃ to 900 ℃. Moreover, it increases less than 2 times when the fluence increases from 5×10~14 cm~-2 to 5×10~15 cm~-2 for the sample annealing at 900 ℃. The PL emission peaks around 622 nm of samples annealing at 900 ℃ can be well clarified by Gaussian fitting into 620.2, 622.0 and 625.0 nm, which are due to the Eu~3+ related with defects, Eu~3+ occupied at substitutional positions of Ga, and that located at interstitial sites, respectively. It shows that the different microenvironments and positions of Eu~3+ are responsible for these peaks, and especially the defects introduced by implantation play an important role in the behavior of the PL because they set up an energy transmission bridge from exotic photons to Eu~3+ .     

高职室内设计专业3DS MAX课程教学探讨

在总结高职室内设计专业＂3DS MAX＂课程教学经验的基础上,对教学对象、教学内容、教学手法等方面进行了初步的研究和探讨。     

化学工程与工艺专业综合实验的教学设计与实践——用废旧铝制品制备超细Al（OH）3粉体

通过设计化学工程与工艺专业综合实验,采用化学沉淀方法制备出超细Al(OH)3粉体,并对制备出的粉体进行表征测定。通过该实验掌握化学沉淀法制备超细粉体的基本方法,了解IR、TEM和化学分析等测试方法,并树立变废为宝的思想。     

投影三维重建中基础矩阵的鲁棒性估计方法

在未定标系统中 ,基础矩阵给出了图像间对极几何关系的代数描述 ,解决了许多视觉问题的关键环节 ,本文提出了一种新的鲁棒性基础矩阵估计方法 ,它引入了能够较好表达代数余数标准方差的Sampson加权算子 ,并且用迭代法来满足图像点噪声为非高斯白噪声的情况 .实验结果表明 ,在较大噪声干扰的条件 ,仍能较为准确地估计基础矩阵 ,具有良好的鲁棒性和较快的运算速度 .     

CaO、SiO_2、Al_2O_3和MgO四元渣系脱硫

根据石钢生产条件 ,研究了 Ca O、Si O2 、Al2 O3和 Mg O四元渣系脱硫性能 ,实验结果表明 :炉渣碱度在 1 .1 0～ 1 .2 0之间 ,Mg O≯ 1 0 % ,Al2 O3≯ 1 5%时能获得最佳的脱硫效果     

Auto-measuring System of 3-Dimensional Human Body

To realize the automation of fashion industry measuring, designing and manufacturing, the auto-measurement of 3D size of human body is of great importance.The auto-measurement system of 3D human body based on Charge Coupled Devices ( CCD) and infrared sensors is presented in this paper. The system can measure the bare size of human body that excludes the effect of clothing quickly and accurately.     

Synthesis and magnetic property of a nitroxide based on C60

The compounds containing stable nitroxide radicals possess magnetic properties for the free radical have net magnetic moment. Oxidization of the [60]fulleropyrolidine obtained from the reaction of C60 with diketone and 2-aminoisobutyric acid by m-chloroperoxybenzoic acid gives a new nitroxide integrated with C60. The stable nitroxide based on C60 is confirmed to be antiferro- magnetism with quantum design superconducting quantum interference device (SQUID).