Synthesis of the 3D porous carbon-manganese oxide (3D-C@MnO) nanocomposite and its supercapacitor behavior study

A 3D porous carbon-manganese oxide ([email protected]) nanocomposite is successfully synthesized via a thermal plasma deposition method. The chemical bonds and compositions, phase structures, surface morphologies, etc. of as-obtained [email protected] nanocomposite were characterized by the various equipment, such as X-ray diffractometer, X-ray photoelectron spectroscopy, and electron microscopes. The electrochemical performances of the [email protected] nanocomposite electrode showed a specific capacitance of 780 F g^?1 at a current density of 2 A g^?1 and a capacitance retention rate of 99% after 5000 charge-discharge cycles at a high current density of 10 A g^?1. These excellent capacitive performances may be attributed to the encapsulation of MnO nanoparticles by porous carbon sheets in the [email protected] MnO nanocomposite structure. It is believed that the carbon-encapsulated MnO nanoparticles can be protected from a volume deformation during the charge adsorption/desorption cycle and can be electrically improved by the encapsulated carbon sheets, resulting in better overall capacitive performance. In addition, this study also demonstrates the practical applicability by assembling a supercapacitor using the as-obtained [email protected] nanocomposite to glow a light emitting diode.     

遗留资源再回收顶板运动及压力显现特征

为分析遗留下分层开采时再生顶板的运动规律及矿压显现特征,以北皂煤矿油页岩分层下行开采为背景,结合前期研究中建立的下分层再生顶板碎裂结构模型及其分带特征,通过改进传统的相似材料配比构建了下分层再生顶板碎裂结构相似材料试验模型,并对下分层开采中的顶板运动、支承压力分布及支架受力特点进行了研究.结果表明:受二次采动影响,再生顶板垮落岩块碎胀系数较小,压实程度较好.上、下分层采高接近情况下,下分层工作面支承压力影响范围及峰值均小于上分层,分别为上分层的38%和51%;下分层支架受力为上分层的91.6%;下分层采出后顶板中不规则冒落带及规则冒落带高度均增加至采前的3倍;裂隙带高度增加为采前的1.6倍.为类似条件的下分层采场设计、支架选型提供依据.     

碱性与中基性粗集料影响混凝土抗冻性能对比

粗集料作为混凝土的重要组成材料,其品质直接关系到混凝土的各项性能.通过试验对比研究了碱性矿料石灰岩(ω(SiO_2)为1.01%)和中基性矿料玄武岩(ω(SiO_2)为53.5%)混凝土的抗冻性能,分析了两类试件的质量损失率和相对动弹性模量.结果表明:碱性矿料能够提高混凝土的抗冻性能,这对解决混凝土抗冻性能具有重要意义.     

苯并[1，2-b：4，5-b’]二噻吩-thieno[3，4-易]thiadiazole导电性的理论研究

采用密度泛函理论，在B3LYP／6—31G（d）水平下，对苯并[1，2-b：4，5-b’]二噻吩（BDT）-thieno[3，4-b]thiadiaz01e（TD）的低聚物和聚合物进行了理论计算．其中，BDT为电子供体，TD为电子受体，以1：2的方式结合形成化合物，并计算了二面角、分子内的电荷传输、桥键键长和中心键电荷密度．结果显示：随着聚合链增长，共轭程度增加．NICSs值显示：中心环比边环的共轭程度更大．聚合物的能带结构表明：该聚合物的带隙比较低（0．87eV），故其可以作为潜在的导电材料．     

基于正交设计的膨胀岩相似材料试验研究

为了能够较准确配制出膨胀岩的膨胀性相似材料,以满足小比例相似模型试验的需要,采用正交试验的方法对膨胀岩的膨胀性相似材料配比进行研究.试验以砂、膨润土、石灰、外加剂(羟丙基甲基纤维素)及拌合用水为材料,采用自由膨胀率和体积膨胀量为直接指标,干燥饱和吸水率为间接指标,并考虑单轴抗压强度,设计4因素4水平的试验方案.试验结果表明,本次试验的配合比可用于膨胀性岩石的相似材料模型试验,为膨胀岩实验室模拟研究提供较为理想的材料.     

应用型本科“材料成型及控制工程专业英语”教学改革的研究与探索

材料成型及控制工程专业英语课程教学在课程地位、教学方法、教学内容、考核方式、教师素质等五个方面存在一些问题,针对这些问题,根据应用本科人才的培养要求,提出了专业英语课程地位提升方法,建立了科学的教学方法和完善的教学内容,提出了教师素质和学生自主学习能力的提升措施.     

浅谈写作素材的采撷——谈选材

其实写作的素材是发掘不完的,面对“新颖”这个要求,无数同学陷入寻找素材的误区.以为素材的 “新颖”便是别人没有见过的,没写过的.其实,素材“新颖”与否,并不在于是新是旧.关键是要选择一个什么样的角度利用素材、用好素材.     

浅谈图书书标的材质要求和粘贴方法

介绍了图书书标的材质要求和粘贴方法,指出材质要求包括对书标的颜色、边线、中间线、大小、纸质等的要求,粘贴方法包括粘贴位置、粘贴方向、加固方法等。     

Flame spread over the surface of thermal insulation materials in different environments

Experiments were conducted in a plateau area in Lhasa and a plain area in Hefei China to investigate the flame spread characteristics on thermal insulation materials under different environmental conditions (pressure and oxygen concentration).Molded polystyrene foam (EPS) and extruded polystyrene foam (XPS) samples were placed horizontally on a small-scale flame spread experimental bench.Changes in the average length of the pool fire,flame spread speed,average flame height,and length of preheating zone were used to determine the effect of the plateau and plain environments on flame spread characteristics.These parameters were all larger in Hefei than in Lhasa,which indicates the fire hazard in Hefei will be higher than that in Lhasa if insulation materials of the same size are used.     

Graphene-based hybrid materials and their applications in energy storage and conversion

Graphene attracts more and more scientists and researchers owing to its superior electronic,thermal,and mechanical properties.For material scientists,graphene is a kind of versatile building blocks,and considerable progress has been made in recent years.Graphene-based hybrid materials have been prepared by incorporating inorganic species and/or cross-linking of organic species through covalent and/or noncovalent interactions.The graphene-based hybrid materials show improved or excellent performance in various fields.In this review,we summarize the synthesis of graphene and graphene-based hybrid materials,and their applications in energy storage and conversion.