烧结温度对WC-Co(Cu)硬质合金性能的影响

通过粉末直接混合和真空烧结法制备WC-Co(Cu)硬质合金。用XRD、ICP-AES和SEM分析了硬质合金的成分和组织结构。用万能实验机和洛氏硬度计测试了抗弯强度和硬度。结果表明:随烧结温度的升高,显微组织的均匀性先增加后降低,当烧结温度为1460℃时,显微组织分布均匀。真空烧结时,Cu产生挥发,少量的Cu固溶到WC-Co中。随着烧结温度的升高,抗弯强度和硬度呈先增大后减小的趋势,当烧结温度为1460℃时,抗弯强度和硬度最大,分别为2595 MPa和90.7 HRA。     

Effect of TiO<Subscript>2</Subscript> pigment gradation on the properties of thermal insulation coatings

This study was designed to evaluate the thermal performance and mechanical properties of coatings with different gradations of TiO₂ pigments. The solar reflectance, cooling performance, wash resistance, and film adhesion strength of the coatings were investigated. The influence of TiO₂ powder gradation on the final properties of the coatings was studed. The solar reflectance and the thermal insulation were observed to increase with increasing content of nanosized TiO₂. The mechanical properties of the coatings, such as their wash resistance and film adhesion strength, were observed to increase with increased incorporation of nanosized TiO₂. Such improvements in the properties of the coatings were attributed to the greater specific surface area and lower thermal conductivity of nanosized TiO₂ particles compared to normal TiO₂ particles.     

Microstructural evolution and growth kinetics of thermally grown oxides in plasma sprayed thermal barrier coatings

The formation of thermally grown oxide(TGO) during high temperature is a key factor to the degradation of thermal barrier coatings(TBCs)applied on hot section components. In the present study both the Co Ni Cr Al Y bond coat and Zr O_2-8 wt.% Y_2O_3(8YSZ) ceramic coat of TBCs were prepared by air plasma spraying(APS). The composition and microstructure of TGO in TBCs were investigated using scanning electron microscopy(SEM), energy dispersive spectroscopy(EDS) and X-ray diffraction(XRD) analysis. The growth rate of TGO for TBC and pure BC were gained after isothermal oxidation at 1100 °C for various times. The results showed that as-sprayed bond coat consisted of β and γ/γ'phases,β phase reducesd as the oxidation time increased. The TGO comprised α-Al_2O_3 formed in the first 2 h. Co O, Ni O, Cr_2O_3 and spinel oxides appeared after 20 h of oxidation. Contents of Co O and Ni O reduced while that of Cr_2O_3 and spinel oxides increased in the later oxidation stage.The TGO eventually consisted of a sub-Al2O3 layer with columnar microstructure and the upper porous CS clusters. The TGO growth kinetics for two kinds of samples followed parabolic laws, with oxidation rate constant of 0.344 μm/h~(0.5) for TBCs and 0.354 μm/h0.5for pure BCs.     

高温固相法制备Sm2O3掺杂La2Ce2O7热障涂层材料

以La2 O3、CeO2和Sm2 O3为原料,采用高温固相反应法制备了Sm2 O3部分掺杂La2 Ce2 O7热障涂层陶瓷材料,其化学式为(SmxLa1-x)2Ce2O7.采用X射线衍射法研究了试样的物相结构,并通过对比各实验条件下制备的试样的X射线衍射图谱,对试样的掺杂比例、烧制温度及烧制时间进行了探究.结果表明,所制备试样为萤石结构,当掺杂摩尔比Sm：La为1：2或1：3时试样均能保持良好的相结构,以掺杂摩尔比Sm：La=1：2制备的( Sm0.33 La0.67)2 Ce2 O7材料在1600℃下具有良好的相稳定性,且其最佳制备条件为1550℃下烧制10 h,该材料是一种很有潜力的新型热障涂层陶瓷材料.     

Microstructure and high-temperature wear properties of in situ TiC composite coatings by plasma transferred arc surface alloying on gray cast iron

In this work, an in situ synthesized TiC-reinforced metal matrix composite (MMC) coating of approximately 350–400μm thick-ness was fabricated on a gray cast iron (GCI) substrate by plasma transferred arc (PTA) surface alloying of Ti–Fe alloy powder. Microhard-ness tests showed that the surface hardness increased approximately four-fold after the alloying treatment. The microstructure of the MMC coating was mainly composed of residual austenite, acicular martensite, and eutectic ledeburite. Scanning electron microscopy (SEM) and X-ray diffraction analyzes revealed that the in situ TiC particles, which were formed by direct reaction of Ti with carbon originally contained in the GCI, was uniformly distributed at the boundary of residual austenite in the alloying zone. Pin-on-disc high-temperature wear tests were performed on samples both with and without the MMC coating at room temperature and at elevated temperatures (473 K and 623 K), and the wear behavior and mechanism were investigated. The results showed that, after the PTA alloying treatment, the wear resistance of the sam-ples improved significantly. On the basis of our analysis of the composite coatings by optical microscopy, SEM with energy-dispersive X-ray spectroscopy, and microhardness measurements, we attributed this improvement of wear resistance to the transformation of the microstruc-ture and to the presence of TiC particles.     

可见光减反膜的设计原则研究

分析了光学零件表面的光能量的反射损失,从膜系选择、膜料选择、膜层厚度,镀制工艺四个方面,对可见光减反膜的膜系设计特点进行了研究,确定了基本的设计原则.     

车用柴油机气缸套Ni-Co-P-MoS2镀层寿命的智能预测

针对硼铸铁车用柴油机气缸套磨损严重现象,在考虑车用柴油机气缸套工况的基础上,在其基材上电镀Ni-Co-P-MoS2镀层并进行耐磨对比试验,以Ni-Co-P-MoS2镀层磨损量为基础,采用函数链神经网络建立车用柴油机气缸套Ni-Co-P-MoS2镀层寿命智能预测模型.研究结果表明:在相同条件下,车用柴油机气缸套Ni-Co-P-MoS2镀层能在很大程度上提高车用柴油机气缸套的使用寿命;车用柴油机气缸套Ni-Co-P-MoS2镀层的预测剩余寿命比较接近车用柴油机气缸套Ni-Co-P-MoS2镀层的实际寿命.     

微波辐射计用于隐身目标探测的性能分析

研究了微波辐射计用于隐身目标探测的若干基本问题。在分析现有主要隐身技术的基础上,针对隐身目标的特点和隐身材料的电磁热发射特性,提出了利用被动微波遥感器——微波辐射计探测隐身目标的方法。分析了微波辐射计用于隐身目标探测的主要性能指标,并对提高隐身目标被动微波探测性能的研究和发展方向进行了分析。     

等离子喷涂WC-Co涂层的超声波评价

为了解决目前等离子喷涂涂层制备中的质量检测问题及为在役涂层质量评价提供无损评价技术,研究了一种新的涂层超声无损检测方法.该方法考虑超声波在涂层中传播时,不同界面的回波信号相互叠加并发生多重反射的传播特性,运用功率谱分析及互相关函数分析方法,提出了由涂层引起的群速度延迟时间及涂层密度的求解方法,建立了适于涂层材料评价的超声无损检测系统.对等离子喷涂铁基上的WC-Co涂层进行了密度测试,测试结果与质量差法测量结果误差3.7%.对不同厚度的涂层进行了测试,证明延迟时间与涂层厚度成比例,并与最小二乘法吻合.     

HA/YSZ/Ti6Al4V生物复合材料的制备与界面特性

采用磁控溅射法制备出HA／YSZ／Ti6Al4V生物复合材料,利用X-射线衍射仪（XRD）、扫描电镜（SEM）和能谱分析（EDXA）研究复合涂层的相组成、表面微观形貌和界面微观形貌,并用划痕仪测定复合涂层与基体的界面结合力．结果表明：溅射的复合涂层中主要含有HA、ZrO2和Y2O3物相,此外还有少量的TCP和CaO相;该复合涂层表面凹凸不平,呈现网状微孔结构,其孔隙直径约为0．5～2μm,孔隙面积占薄膜表面积的30％～40％．划痕试验表明,复合涂层与Ti6Al4V基体结合力约为80N．复合涂层拉伸试样横断面分析显示,在涂层与基体界面处无裂纹,界面处存在Ti6Al4V基体成分Ti与复合涂层成分Ca、P问互扩散的扩散层,该扩散层厚度为0．5～1．5μm,复合涂层界面的结合机制为机械齿合和扩散结合．