钡硼硅酸盐玻璃中Ti的结构及其作用

采用顺磁共振和X射线光电子能谱,结合密度和折射率测定研究了BaO-SiO2-B2O3-TiO2系统玻璃中Ti的价态及Ti3 和Ti4 的结构状态,分析了TiO2结构对玻璃性能的影响.研究结果表明:在正常空气气氛下熔制的玻璃中,Ti主要以Ti4 形式存在,所产生的顺磁信号归因于玻璃的本征缺陷和熔制时TiO2中氧的逸出而形成的氧空位捕获电子,且随温度升高,氧空位浓度减少;在还原性气氛下,有部分Ti3 形成,出现g∥＝1.9954,g⊥=1.9823两处顺磁峰,随温度升高,g∥峰增强,g⊥峰降低;Ti3 处于带四方畸变的[TiO6]八面体配位场中;玻璃中Ti4 的配位数以[TiO4]为主,且随TiO2含量增加,[TiO4]有向[TiO6]转变的趋势,这种转变发生在TiO2含量约为20%处;TiO2的加入能提高玻璃结构网络的连接程度和堆积密度,从而使玻璃的密度和折射率线性增大.     

Synthesis of PbS–K2La2Ti3O10 composite and its photocatalytic activity for hydrogen production

Photocatalyst, lead sulfide (PbS )-intercalated layer perovskite-type compound (K2La2Ti3O10), was synthesized via ion-exchange reaction, butylamine pillaring and sulfuration processes under the assistance of the microwave irradiation. The structure of the photoc atalysts was determined by means of powder X-ray diffraction, scanning electron microscope, ultraviolet- visible diffuse reflection spectra and photoluminescence measu rement. And the photocatalytic activity of the composite compound for hydrogen production was also investigated. The experimental results showed that the intercalation of PbS in the layered space of K2La2Ti3O10 greatly improved the absorption edge and the photocatalytic activity. Hydrogen production of the PbS–K2La2Ti3O10 was 127.19 mmol/(g cat) after 3 h irradiation of ultraviolet light.     

掺镍对钛过量钛酸钡粉体及其陶瓷的结构及介电性能的影响

采用溶胶-凝胶(Sol-Gel)法制备了Ti/Ba=1.02的掺镍钛酸钡纳米晶粉体及其陶瓷。通过XRD、SEM和TEM对掺镍钛酸钡基粉体及陶瓷进行表征,并测定了陶瓷的介电性能。结果表明:Ti/Ba=1.02的掺镍钛酸钡基粉体约40 nm,主要相组成为立方相钛酸钡,并有少量的碳酸钡,经烧结后全部转化为四方相钛酸钡。掺镍明显降低了钛酸钡基陶瓷的烧结温度(约降低100℃);随着掺镍量的增大,陶瓷粒径先增大后减小,掺镍量mol比为3.0%时陶瓷εm大(5 571),并且tanδ小(0.011);与Ti/Ba=1.00的掺镍钛酸钡陶瓷相比,钛过量掺镍钛酸钡陶瓷粒径细小,ε-T谱峰值降低。     

Millennial climate changes since MIS 3 revealed by element records in deep-sea sediments from northern South China Sea

High resolution elemental MD05-2903 from the northern South records in core China Sea were obtained from XRF scanning and grain size and mineral component analyses. The K/Ti curve reveals climate changes since MIS 3 on a millennial scale, representing one of the best such records so far from deep-sea sediments of the South China Sea. When compared our K/Ti record with other climate records from high latitude ice cores and from East Asia stalagmites, variations in the K/Ti record show some typical saw-shaped features of rapid climate changes in the Northern Hemisphere. Grain size analysis reveals a close relationship between variations in K/Ti and in the fine end-member grain size. XRD analysis confirms that high K/Ti layers were dominated by K-rich weathering minerals, especially illite, while low K/Ti layers contain low illite but high abundance of Ti-rich heavy minerals. Therefore, the K/Ti record reflects changes in the input and deposition of fine weathering minerals and heavy minerals in the northern South China Sea region during stadials and interstadials. These elemental changes were largely con- trolled by variations in rainfall, erosion, and fluvial trans- portation induced by East Asia Monsoon.     

Nb-Ni-Ti系低Ti侧三元化合物及其相平衡

采用合金平衡组织结构分析法,利用扫描电镜组织观察和能谱成分分析、电子探针定量成分分析以及X射线衍射结构分析,并结合热分析,对Nb-Ni-Ti系低Ti侧化合物XB及其相关相平衡进行了研究.结果表明,在Nb-Ni-Ti三元系1000℃和1100℃等温截面相图中都存在着三相区XB+(Nb)+TiNi,化合物XB可与Nb基固溶体(Nb)和TiNi相保持固态相平衡直到约1133℃.Nb-Ni-Ti三元系在1133℃发生三相共晶转变LTiNi+XB;由于液相L的形成,XB相不再与TiNi相和Nb基固溶体平衡.1150℃时Nb-Ni-Ti三元系等温截面相图中存在着XB+(Nb)+L三相区,XB相与Nb基固溶体和液相平衡共存.     

掺钛蓝宝石激光器自锁模机制分析

掺钛蓝宝石自锁模激光器中产生自锁模的主要因素是自振幅调制（ＳＡＭ）、自相位调制（ＳＰＭ）和群速度色散（ＧＶＤ）。本文详细地分析了三要素在锁模脉冲形式的不同阶段所起的作用,指出在整个过程中自振幅调制对脉宽压缩起主要作用,而引入的适量负群速度色散在后期对ＳＰＭ效应与正ＧＶＤ起补偿作用,可获得最窄脉冲。最后,讨论了形成不稳定锁模脉冲的可能性。     

Multi-peak spectrum of KML Ti: Sapphire pulse

The multi-peak spectrum of Ti:sapphire pulses observed experimentally under ultra-broad bandwidth conditions (< 15 fs pulse length) has been explained theoretically. It is shown that the self-phase-modulation effect is equivalent to the process of degenerate four-wave frequency-mixing. Based on this theoretical underpinning, the presence or absence of a multipeak spectrum provides a practical measure of whether the intracavity group-velocity-dispersion is ideally compensated for or not.     

地域文学视域下的清人论清文：《国朝文棷题辞》与清代文集叙录

平步青《国朝文棷题辞》以千余卷规模的清文总集《国朝文棷》为基础,对清代散文作了集成式叙录。此书从地域文学视角出发,挖掘出清初江西散文与清代浙东散文发展的内在细节与地域集群性特征,揭橥出桐城文派之外丰富的散文创作事实,对于还原文学史真实面目、梳理文派流衍、重写清代散文史,均有比较重要的价值与意义。     

Ti3SiC2/TiC复合材料的制备及力学性能研究

弓网系统中,各种类型的受电弓滑板承担着传输电能的重要功能,其严酷的工作条件对受电弓滑板材料的性能提出了非常苛刻的要求。目前最主要的受电弓滑板有：粉末冶金滑板,纯碳滑板和浸金属碳滑板。其中碳滑板材料性能较好但价格昂贵,粉末冶金滑板材料价格便宜,但性能明显逊于前者。Ti3SiC2/TiC是一种兼具陶瓷与金属性质的新型材料,与碳滑板材料相比,其电阻率低,且具有良好的抗氧化性和自润滑减摩性,因此Ti3SiC2/TiC将可能成为一种工艺简单、成本更低、而性能则更高的新型受电弓滑板材料。本研究以Si、Ti和C为原料,利用熔渗反应烧结技术制备出Ti3SiC2/TiC复合材料,研究结果表明,制备样品的弯曲强度与硬度分别达到 423MPa~564MPa 和169~249HB。同时,本文对Ti3SiC2/TiC复合材料的断裂机理进行了研究。     

论《乌夜啼》曲牌来源及其填制

《乌夜啼》之名最早见诸中古乐府,唐代教坊曲中亦有《乌夜啼》,其后唐宋词中出现了大量以《乌夜啼》为词牌的词。通过考察其本事,可以看出,词牌之《乌夜啼》是以唐教坊曲《乌夜啼》为近源,以中古乐府《乌夜啼》为远源,哀怨婉曲是其声情的基本特点。南唐李煜首创《乌夜啼》之后,两宋时期有四十八字左右《乌夜啼》和三十六字《乌夜啼》,后一种情况是以《相见欢》为词调,当视为《相见欢》的别称。北宋时期创作此调的词人除欧阳修以外,比较鲜见,然南宋逐步繁盛,陆游、卢祖皋等是其代表,而且往往一题多作,促进了《乌夜啼》创作的发展。