NURBS曲面G2光滑拼接算法

非均匀有理B样条(NURBS)曲线、曲面的造型方法,是当前CAD/CAM领域中研究的热点之一.对NURBS而言,虽然具有参数连续性,但为了实用,仍需要构造具有一定光滑程度的合成曲面,以满足局部设计和修改的需要.本文给出了实用的具有三次公共边界曲线的NURBS曲面片G2光滑拼接条件,得到了不移动控制顶点,不修改权系数的具体算法,而构造的三次公共边界曲线是一个显式参数方程,在工程设计中易于实现.     

双硫腙萃取富集-石墨炉原子吸收光谱法测定水体中痕量钴

介绍利用双硫腙(D2)作为螯合萃取剂,对水体中痕量钴进行萃取富集,采用基体改进技术由自动进样器注入石墨炉测定水中痕量钴的方法.本法操作简便、价廉、灵敏度和回收率高,加标回收率为97.4%～104.4%,RSD<3.47%.     

纳米催化剂KF/Al2O3制备条件的正交设计与优化

采用正交设计法优化了浸渍法制备固体超强碱KF/Al2O3催化剂工艺参数.以丙烯腈和丙二酸二乙酯的Michael加成反应收率为考察指标,对催化剂制备工艺进行优化,并采用SPSS统计软件包对制备工艺参数进行多元回归统计,并根据回归拟合的多项式数学模型,讨论了浸渍法制备的较佳工艺.     

经食管心房起搏终止房室结内折返性心动过速方法探讨

目的：为探讨经食管心房起搏终止房室结双径路所致的折返性心动过速．方法：共47例，采用超速抑制、亚速抑制．比较超速抑制与亚速抑制二者对心动过速的终止效果．结果：亚速抑制19例，成功11例（57．9％），8例未成功改用超速抑制．超速抑制36例，成功34例（94％），2例超速抑制、亚速抑制均无效，应用猝发脉冲后终止．结论：猝发脉冲终止室上性心动过速效果已经肯定．超速抑制终止效果明显高于亚速抑制（P〈0．05），而该种心动过速比较容易用起搏终止，缺点为不能预防复发．     

二阶抛物问题的扩展混合元方法

对二阶抛物问题提出了一种新的混合元方法一扩展混合元方法．该方法能同时逼近未知函数、未知函数的梯度和流体的流量，较好地模拟了带有混合型边界条件的二阶抛物问题．通过数值分析进一步证明了未知函数、未知函数的梯度和流体的流量的最优L^2-误差估计。     

氨基磺酸催化合成环己酮1,2-丙二醇缩酮

以氨基磺酸为催化剂,对以环己酮和1,2-丙二醇为原料合成环己酮1,2-丙二醇缩酮进行了研究。较系统地研究了酮醇摩尔比,催化剂用量,反应时间诸因素对收率的影响。最佳反应条件为:n(酮)∶n(醇)=1∶1.5,催化剂用量为1 g,带水剂环己烷15 mL,反应时间60 m in。上述条件下,环己酮1,2-丙二醇缩酮的收率可达71.15%。     

水滑石与氢氧化镁纳米晶的液相法制备及其生成机制

研究了纳米晶镁铝水滑石Mg6Al2(OH)16CO3·4H2O与 Mg(OH)2 的液相法制备及其物相变化.X射线衍射(XRD)和透射电镜(TEM)分析表明,在制备温度分别为30 ℃的低温和190 ℃的高温,可获得纯度大于99%的氢氧化镁针状纳米晶,在45~150 ℃的中间温度范围,可获得纯度大于 99%的镁铝水滑石针状纳米晶.合成温度由35 ℃提高到45 ℃时,生成物相由氢氧化镁变成镁铝水滑石相;合成温度由 170 ℃提高到190 ℃时,生成物相由镁铝水滑石相变成氢氧化镁相.提出低温时生成物的变化与瞬间生成无定形态的Mg(OH)2 有关,无定形态的Mg(OH)2 沉淀为Al13(OH)7 32 中铝离子以及CO2-3 扩散进入Mg(OH)2提供了更为有利的条件.高温时生成物的变化,是由于温度的升高,使含结晶水的镁铝水滑石纳米晶中间层中的高极性水分子堆积所要求的一定的物理条件受到破坏所致.     

A Novel Degradation Pathway of Zn（dmid） （ phen）2 in Pyridine

The light-oxidation degradation processes of Zn(dmid)(phen)2(dmid = 4, 5-dimercapto-1,3-dithiole-2 one, phen = 1,10-phenanthroaline) in pyridine solvent has been monitored, h has been found under the light, dmid^2- of Zn(dmid)(phen)2 in pyridine solution could generate NCS^- and NCS^-replaces dmid^2- to form Zn(NCS)2 (phen)2 simultaneously. The crystal structure of Zn(NCS)2 (phen)2 has been determined. In the crystal of Zn(NCS)2 (phen)2. two NCS^- ligands are arranged in syn-configuration, and there is strong π-π interaction between the two adjacent parallel phen.     

Stereo- and regio-selectivity in the photosensitized dimerization of 1, 3-dimethylthymine in solution

The effects of reaction pathway and temperature on stereo- and regio-selectivity of photocycloaddition of 1, 3-dimethylthymine (DMT) which gives four cyclobutane type dimers in solution using acetone as the photosensitizer, are investigated by measuring the product distribution. It is demonstrated that the ground-state aggregation between DMT molecules mainly leads to (h-t)dimers, and the diffusion-controlled triplet dimerization is favorable to the formation of (h-h) dimers.     

A template of rat brain based on fMRI T*2 imaging

The development of functional magnetic resonance imaging (fMRI) technology has made it possible to carry out functional brain imaging experiments in small animals. Usually, group data is required to form the assessment of population, which can not only increase the sensitivity of the overall experiment, but also allow the generalization of the conclusion to the whole population. In order to average the signals of functional brain images from different subjects, it is necessary to put all the mapping images into the same standard space (template image). However, up to now, most animal brain templates remain unavailable and it must be done by ourselves. In this study, a template image based on the brains of eight male Wistar rats is obtained, and it is successfully used in our present Alzheimer disease (AD)-like rat model studies as template for spatially normalizing images to the same stereotaxical space. The fMRI results processed with statistical parametric mapping (SPM99) software are in agreement with the results from immunohistochemical experiment, which proves that this method is universally applicable to the pathologic models of other small animals and to human brain lesion studies.