Influence of Mg_5Ga_2 compound on microstructures and electrochemical properties of Mg-5%Hg-22%Ga alloy

The Mg-5%Hg-22%Ga(mole fraction) alloy was melted.Aging at 573-673 K for different times was carried out to ensure the fine dispersion of the Mg_5Ga_2 compound.Scanning electron microscopy(SEM),X-ray diffractometry(XRD) and energy spectrum analysis(ESA) were employed to characterize the microstructures and phases of the Mg-5%Hg-22%Ga alloy.The electrochemical and corrosion behaviors of the above alloy were studied by potentiodynamic,galvanostatic and electrochemical impedance spectroscopy(EIS) measuremen...     

Development of thermodynamic and kinetic databases in micro-soldering alloy systems and their applications

Recent progress in the development of thermodynamic and kinetic databases of micro-soldering alloys,which were constructed within the framework of the Thermo-Calc and DICTRA software,was presented.Especially,a thermodynamic tool, ADAMIS(alloy database for micro-solders) was developed by combining the thermodynamic databases of micro-solders with Pandat,a multi-component phase diagram calculation software program.ADAMIS contains 11 elements,namely,Ag,Al,Au,Bi,Cu, In,Ni,Sb,Sn,Zn and Pb,and can handle all c...     

Corrosion and electrochemical behavior of as-cast Mg-5Y-7Gd-1Nd-0.5Zr magnesium alloys in 5% NaCl aqueous solution

The corrosion mechanism of the as-cast Mg-5Y-7Gd-1Nd-0.5Zr magnesium alloy immersed in 5% NaCl aqueous solution was investigated by electrochemical test and SEM. The electrochemical results indicate that the corrosion resistance of Mg-5Y-7Gd-1Nd-0.5Zr alloy in 5% NaCl aqueous solution gradually deteriorates with immersion time increasing from 2 h, 24 h, 60 h, to 108 h, which is consistent with th e SEM observation of corrosion morphologies. The Cl^-anion leads to the initiation and development of the corrosion pits, and Mg-5Y-7Gd-1Nd-0.5Zr alloy exhibits filiform type of attack under significant anodic control of magnesium solution reaction. The corrosion potential becomes noble with increasing immersion time.     

镁合金定向凝固技术研究的意义与进展

作为一种先进的材料制备技术与凝固研究技术,镁合金定向凝固技术具有很大的发展潜力与意义。文章分析讨论了镁合金定向凝固技术发展的必要性和研究与发展情况,并提出了该技术继续发展的重点与方向。     

电化学沉积法制备Co-Ni合金及其磁性能研究

室温下,分别采用恒电位沉积法和脉冲电位沉积法制备面心立方fcc(Co)和密排六方hcp(Co)混晶Co-Ni合金材料,利用XRD、SEM、EDX等手段对其结构和组成进行表征,并利用振动样品磁强计研究其磁性能.结果表明:脉冲电位沉积法比恒电位沉积法更有利于具有致密织构的Co-Ni纳米晶合金的生成,同时有利于合金中Co含量的增大.     

Fe-Si-B-Nb-Cu-Zr非晶（纳米晶）合金的磁性机理研究

采用单辊甩带法制取了Fe-Si-B-Nb-Cu-Zr非晶合金薄带。利用X射线衍射仪（XRD）、差示扫描量热法（DSC）和振动样品磁强计（VSM）等手段对非晶态和晶化后的薄带的微观结构和磁性能进行了表征和测试,研究了Fe-Si-B-Nb-Cu-Zr合金中磁性能随着Zr含量以及退火温度变化的磁性机理。结果表明,在铸态Fe-...     

长纤维局部增强铝合金中的宏观残余应力

采用钻孔法测定了长纤维局部增强的铝合金试样中增强区与非增强区之间的宏观残余应力,利用有限元法对此进行了模拟计算.结果表明:增强区与非增强区之间存在着明显的宏观残余应力,但分布很不均匀.在增强区和非增强区大部分区域,残余应力并不大,而宏观边界附近的非增强区以及增强区的局部存在高残余拉应力微区.在50%纤维局部增强的试样中...     

Preparation and properties of low cost porous titanium by using rice husk as hold space

The present study demonstrates an effective low cost effective process for the production of porous titanium with 50-60 vol% porosity using 20 wt% rice husk(RH) with the hold spaces in the size ranges of 100-180,180-250,250-380,and 380-550 μm.The analysis of the samples revealed an interconnected pore microstructure consisting of a mixture of coarse channel pores,created during burnout of RH.The compressive strength of the developed samples was in the range of 17-70 MPa and depended strongly on their porosity and pore size.Large amounts of cleavage steps appeared on the brittle fracture surface after compression of the samples.The 3D morphology of porous titanium surface with rice husk sizes of 100-180μm and 380-550μm can be characterized by the micro-hole surface of pore size,and the size of the hole diameter and husk.The developed porous titanium is considered potentially useful in future medical or industrial application of biomass.     

超声外场对SiCp/7085复合材料颗粒微观团聚与界面结合的作用机理

采用半固态混合-机械搅拌-超声施振的方法制备了体积分数为10%的SiCp/7085复合材料,通过金相显微镜、扫描电镜和X射线衍射对颗粒分布与界面进行研究,重点研究超声外场对复合材料颗粒团聚与界面结合的作用机理.实验结果表明:单纯机械搅拌对400目颗粒的团聚与界面结合的作用效果有限;超声外场下,空化作用产生的微射流与瞬时高温高压能够有效破除颗粒团聚体的包裹层,打散颗粒;超声破除颗粒表面氧化膜,除去气体层,使熔体中的镁元素与颗粒直接接触并反应是改善熔体与颗粒润湿性的重要因素;最终在界面处生成MgAl2O4强化相,从而获得更优的界面结合.     

二氧化钛-硫化镉/氧化石墨烯复合材料光催化降解废水中有机物的研究

本论文采用溶剂热法制备出TiO₂-CdS/rGO三元复合光催化材料,并对其降解亚甲基蓝、罗丹明B的光催化活性进行研究,发现TiO₂-CdS/rGO对于亚甲基蓝、罗丹明B的光催化降解活性优于TiO₂-CdS,催化效率明显提高,降解时间大大缩短;在可见光照射下,以TiO₂-CdS/rGO为光催化剂,光反应时间40 min,亚甲基蓝、罗丹明B的降解率可达100%。本文还研究了催化材料的稳定性、催化剂用量对光催化降解效果的影响。