Facile immobilization of heparin on bioabsorbable iron via mussel adhesive protein (MAPs)

Motivated by adhesive proteins in mussels, strategies using dopamine to modified surface have become particularly attractive. In the present work, we developed a novel and convenient method to modify the biodegradable Fe plates with heparin. Iron was first treated by a facile one-step p H-induced polymerization of dopamine, and then a high density heparin was successfully grafted onto the surface via coupling with polydopamine(PDA) active layer. Heparin immobilization contributed much longer blood clotting coagulation time than the pure Fe sample, and hence reduced the risk of thrombosis. Cell viability tests suggested that the heparin modified Fe plates were more favorable to the proliferation of ECV304 cells. In summary, the heparin modified Fe plates with good anti-thrombus properties and inhibiting the proliferation of VSMC cells provide great prospects for biodegradable iron.     

典型机械加工表面形貌统计参数分析

为得到粗糙接触表面接触模型的计算参数,开展了典型机械加工表面的统计参数分析与研究.采用表面轮廓仪测量了典型加工方法下得到的不同粗糙值的表面形貌数据,根据ISO 11562标准,使用零相移高斯滤波对表面轮廓进行处理得到表面粗糙度数据;基于三次样条曲线拟合的方法和凸峰独立的原则,提出一种新的凸峰定义方法,分析拟合后的数据得到表面凸点的高度分布函数、凸点平均半径和密度等接触模型计算参数.分析结果表明:粗糙度参数对高度分布函数、凸点平均半径和密度均有显著的影响,而加工方法对平均曲率半径影响较小,对高度分布函数和密度影响较大.     

纯二维晶体中表面极化子的光学声子平均数

研究了纯二维晶体中与光学声子相互作用的表面极化子的性质，采用幺正变换和线性组合算符法，导出了晶体中强、弱耦合电子周围光学声子的平均数．并与用改进的线性组合算符和拉格朗日乘子法所得结果相比较，并讨论之．     

Insight into the covalent grafting of organic films onto carbon steel surfaces for protection

The novel use of p-nitrophenyldiazonium tetrafluoroborate salt(GG salt)as a protectant that is electrochemically grafted onto carbon steel has been investigated in0.05 mol L-1H2SO4and 5 wt%NaCl solutions using various corrosion monitoring techniques,such as electrochemical impedance spectroscopy,potentiodynamic polarisation,infrared spectra and scanning electron microscopy measurements.The electrochemical study reveals that this compound is a mixed inhibitor that predominantly controls the cathodic reaction.The surface-grafted film decreases the double-layer capacitance and obviously increases the charge transfer resistance relative to a bare carbon electrode.The values of inhibition effect remain nearly unchanged with an increase in temperature range of 298–318 K.The aryl diazonium is covalently bonded on the steel surface,causing a slight decrease in the apparent activation energy.Overall,the surface-grafted films exhibit excellent inhibition performance in acid and saline solutions within the studied temperature range.     

新型三联季铵盐表面活性剂的合成与性能研究

本文合成了一种三聚阳离子表面活性剂—三(2-氯化十二烷基二甲铵基乙基)胺(TCDAEA)。以三乙醇胺、氯化亚砜为原料,经分子内亲核取代合成了中间体三(2-氯乙基)胺并通过乙酰化法测定其转化率;然后以三(2-氯乙基)胺与N,N-二甲基十二烷基叔胺经季铵化反应合成了TCDAEA。并通过单因素条件实验考察了催化剂质量分数、反应温度、反应时间、溶剂质量分数、N,N-二甲基十二烷基叔胺与三(2-氯乙基)胺物质的量比等因素对产品产率的影响及其对产品溶液表面张力的影响。结果表明：当氢氧化钾质量分数为0.3%、nN,N-二甲基十二烷基叔胺：n三(2-氯乙基)胺=3.9、溶剂质量分数为20%、反应温度为80℃、反应时间为6h时,产品收率可达96.56%;在上述条件基础上,在25℃、临界胶束浓度为4.2?0-4mol/L时,产品溶液的表面张力降低至25.2mN/m。此外,用FT-IR方法对中间体和产物TCDAEA进行了分析表征,研究表明,TCDAEA是一种新型的三聚季铵盐阳离子表面活性剂,具有更高的表面活性。     

Comparison of sensible and latent heat fluxes during the transition season over the western Tibetan Plateau from reanalysis datasets

The sensible and latent heat fluxes during the transition season over the western Tibetan Plateau from the NCEP-1 (NCEP/NCAR Reanalysis 1), AR-II (NCEP-DOE Reanalysis 2) and ERA40 reanalysis datasets were compared and analyzed. The results show that the phase change in soil moisture has a significant effect on the sensible and latent heat fluxes over the western Tibetan Plateau (TP) due to the freezing–thawing processes during the transition from the dry to the wet period. The uncertainties in the sensible and latent heat fluxes over the western TP are quite high in the reanalysis data, and depend largely on the success of the soil moisture simulations in the models. Improving the hydrological process simulations in the land-surface models in seasonally frozen ground and in the active frozen soil layer may be an effective way of enhancing the reliability of the surface heat fluxes from the reanalysis data over the Tibetan Plateau.     

共振金属纳米天线近场区域单分子荧光增益性质的研究

从理论上研究了发生表面等离激元共振时, 银纳米天线对其周围近场区域单分子荧光性质的影响。最优的荧光增益效果在电场增益率和弛豫系数变化率的比值(即优化系数)较大时发生。通过对优化系数的计算, 发现当荧光分子的偶极矩与入射光偏振相同时, 并且在距离纳米天线30～100 nm的近场区域内, 荧光增益效果最佳。讨论了不同偏振方向荧光分子在天线周围不同距离、不同方向的平面以及入射波长变化时对于荧光性质的影响, 可以为金属纳米天线调控荧光行为的实验给予指导。     

N型GaAs单晶表面复合速度的宽谱光伏测算

提出适用于可见光全波段的光伏测算ＧａＡｓ单晶表面复合速度的新方法．实验结果表明，对于掺Ｓｉ的Ｎ型弱简并ＧａＡｓ单晶（ｎ０＝２．０×１０１７ｃｍ－３），其表面复合速度Ｓｐ＝１．６×１０５ｃｍ·ｓ－１，与有关报道基本一致．     

基于金属表面等离子激元的侧耦合半圆形腔-波导透射谱分析

设计了一种新型的基于金属表面等离子激元（Surface Plasmon Polaritons,SPPs）的亚波长金属-介质-金属型滤波器.该滤波器由一个半圆形谐振腔和一个直波导组成.使用时域耦合模理论和传输变换矩阵方法对结构进行理论分析,并通过时域有限差分方法(the finite difference time domain method,FDTD)进行数值模拟得出光谱响应.讨论了几何参数对透射曲线的影响, 并设计了一种双腔结构来获得高对比度的透射曲线.     

Schwarzschild黑洞视界的熵

本文对具有物质性的Schwarzschild黑洞之视界作出物质均匀分布其上及具有负表面张力系数的假定。在此基础上,利用广义相对论的方法及热力学定律计算出了黑洞视界物质所具有的熵。结果表明,视界的熵与黑洞的总熵可达到同一数量级。