Compositional complexity dependence of dislocation density and mechanical properties in high entropy alloy systems

This study focuses on a quantitative analysis of dislocation accumulation after cold plastic deformation and mechanical properties of FeNiCoCrMn and TiNbHfTaZr high entropy alloys (HEAs) which are single phase fcc and bcc solid solutions, respectively. In order to study the role of compositional complexity from unary to quinary compositions on dislocation accumulation and mechanical properties after plastic deformation, the single solid solution phase forming sub-alloys of the two HEAs were investigated. All studied samples revealed a large plastic deformability under cold-rotary swaging process by 85–90% area reduction without intermediate annealing. The dislocation density of all studied samples, determined by Williamson-Hall method on synchrotron X-ray diffraction patterns, were between 10¹⁴ - 10¹⁵ m⁻² dependent on the alloy composition. The level of dislocation density after plastic deformation is not only affected by the number of constituent element but the lattice distortion and intrinsic properties in terms of stacking fault energy, modulus misfit, and melting point also impact the dislocation storage. The level of dislocation density determines the level of mechanical properties because of a resistance to dislocation motions. The hardness and yield compressive strength of the studied samples are proportional to the level of dislocation density.     

一种基于变分模态分解参数优化的轴承故障诊断方法

为解决变分模态分解方法在提取齿轮箱滚动轴承的故障特征频率时受模态个数和惩罚项系数影响的问题,提出了一种基于人工鱼群算法优化变分模态分解的轴承故障诊断方法.首先,利用人工鱼群算法优化变分模态分解方法的模态个数和惩罚项系数;其次,故障振动信号经优化的变分模态分解方法分解,获得若干模态分量;最后,筛选包络熵值最小的分量进行包络分析,提取故障特征频率.实验结果表明:在优化参数过程中,寻优收敛时间缩短46％,并最终有效提取轴承故障特征频率.研究结果可解决变分模态分解方法受参数影响的问题,实现轴承故障诊断,具有实际意义.     

相似关系下变精度粗糙集的阈值选取分析

针对相似关系下的变精度粗糙集模型,讨论了该模型下的阈值选取问题。阈值选取包括相似阈值和分类阈值的选取。通过粗糙熵的计算,给出了最优相似阈值的选取方法。对于分类阈值的选取,提出先将模型的边界域进行细划分,分析各边界域与分类阈值之间的影响关系;之后确立基于边界域的近似分类的准则,通过基于近似分类准则的优化计算,达到对分类阈值区间的合理选取。文末的仿真实例验证了该阈值选取方法的可行性和优越性。     

离子型CoFe_2O_4磁性液体的宏观链径分布

利用Massart法制备了体积分数为0.4%的CoFe2O4磁性液体,在100～800Oe(1Oe=79.5775A/m)均匀磁场中利用光学显微镜分别观察了磁性液体宏观链的形态,测出了宏观链链径的分布.发现磁性液体在磁场100～500Oe内,链径满足双正态分布.提出磁性液体成链是由双因素主导的.利用六角模型,并构造链体系的混合熵,将链体系自由能最小化,得出了两个平均链径与磁场的数值关系.根据计算结果提出,宏观链径显双正态分布时,磁性液体处于两相混合相,随着外磁场增加,磁性液体内本身存在的微小预团聚体作为链核成链方式,逐步变为磁性液体内类"气"的颗粒受磁场"压缩"成链方式,磁性液体微结构也由混合相向六角("固")相转变.     

金属间化合物的标准熵估算模型

在分析已有的热力学数据基础上,建立了估算二元金属间化合物标准熵的双参数模型.用此模型可估算由简单金属形成的二元金属间化合物的标准熵,涉及Fe、Si、Nb、Ti、Cu、Co和Mg等多个体系.估算了132个已知金属间化合物AlCa、AlCo、CrNi、FeTi、FeSi、FeNb和MoSi等的标准熵,平均误差为4.86 J.mol-1.K-1,标准差为6.24 J.mol-1.K-1.用双参数模型估算的标准熵精度高,其估算误差小于离子束缚模型.     

High entropy state of orientationally-disordered clusters in Zr-based bulk metallic glass

A phase transformation of a metastable Zr2Ni intermetallic crystalline phase to vitrify was studied with molecular dynamics (MD) simulations based on a plastic crystal model (PCM), which utilizes the orientational disorder of molecules of plastic crystals in a class of soft matter. The simulation results show ed that computational operations in MD-PCM for the random rotati ons of the clusters in the crystalline phase around their center of gravity and subsequent annealing lead to form a dense random pa cking structure from the metastable Zr2Ni phase. These randomly-rotated clusters provide high degrees of freedom in terms of atomic positions, which results in enhancing the glass-forming ability of the alloy. The critical fraction of the number of rotated cl usters for forming the glassy phase ( fc^R) is evaluated to be 0.75 ? 0.80. Thus, the critical fraction of the number of un-rotated clusters (fc^U=1?fc^R) is close to the critical concentration of site percolation for metallic materials. The mechanism of the metastable Zr2Ni phase to vitrify with increasing f^R was analyzed with a concept of communal entropy in the free volume theory with solid- and liquid-like cells proposed by Cohen and Grest. The MD-PCM for the metastable Zr2Ni phase suggests that Zr-based bulk metallic glass (BMG) can be regarded as an alloy in a high rotation entropy state of cl usters and that glass transition takes place by percolation of th e nuclei of a liquid-like glassy phase.     

基于熵权的产品广义质量模糊综合评价

以提高产品质量为出发点,深入分析了产品广义质量的内涵,建立了产品广义质量模糊评价的目标体系,即包含有结构性能、工作性能和工艺性能在内的产品全性能和全功能的综合指标体系,而且较全面地考虑了产品广义质量的层次性和复杂性.采用熵权与主观权重相结合的方法来确定各个评价指标的权重值,使产品质量评价更具客观性和科学性.与模糊综合评价法相比,该方法克服了凭经验确定指标权重的主观性,增强了权重的可信性,评价结果具有较高的可信度.     

耗散结构原理在边防情报系统中的应用

阐述了耗散结构原理,分析了边防情报系统的耗散结构特性,提出了利用耗散结构原理改善边防情报系统有序性的方法,以期指导边防情报实际工作。     

矿井围岩与支护系统复杂性研究

为研究围岩与支护技术问题,对近十年来相关研究工作进行了系统分析,发现围岩与支护是相互作用、相互制约的一个复杂非线性系统。利用力学与非线性系统理论建立了围岩与支护系统的耗散结构模型,论述了围岩熵产生与支护熵流的相互关系。根据信息熵的原理建立了矿井支护可靠熵模型,并与结构可靠性进行对比分析。最后提出深部巷道断面优化设计,降低巷道底角的非线性应力集中状态,实际应用中使巷道底鼓量减少20%以上。     

光场调制下的两个二能级原子的线性熵研究

本文应用J-C模型研究了两个二能级原子依次穿过一个高Q光场时系统的状态波函数和密度矩阵,并计算了两个二能级原子子系统的线性熵,分析了此时两个原子的纠缠特性。