卢旺达共和国蝗虫的新属和新种（直翅目：蝗总科）

本文记述采自卢旺达共和国蝗虫1新属2新种及2种卢旺达新记录,即paracoplacroides新届、Paracoptacroides rufutibias新种、Odontomelus nigritibias新种,2种卢旺达新记录为Odontomelus brachypterus(Cerstaecker)及Rhabdoplea antusticornis Uvarov。     

Photoelectrical performance of nanocrystalline TiO_2 film electrode sensitized by Ru(Ⅱ)-bipyridine complexes

Two kinds of Ru(Ⅱ)-bipyridine complexes, cis-di(thiocyanate)bis(2,2′-bipyridyl-4,4′-dicarboxylate) ruthenium(Ⅱ) and cis-di(thiocyanate)bis(2,2′-bipyridyl-3,3′-dicarboxylate) ruthenium(Ⅱ), were utilized as the sensitizers to the nanocrystalline TiO-2 film electrodes. Study shows that the two dyes have quite different sensitization properties due to the strong steric effect of carboxyl groups. In addition, the pretreatment to nanocrystalline TiO-2 film electrodes with TiCl-4 was investigated, which is an effective way to improve the photoelectric conversion performances of sensitized TiO-2 electrodes.     

Determination of some carbonyl carboxylic acids using chemiluminescent reaction of Ru(bipy)3 2+−Ce(IV)

A coupled chemiluminescence method for the determination of some carboxylic acids was developed, based on their enhancement the chemiluminescence light emission of the reaction of tirs (2,2′-bipyridine) ruthenium(II) and Ce(IV) in sulfuric acid medium. The conditions for their determination were optimized. The following detection limits were obtained: oxalic acid, 2.67×10⁻⁸ mol/L; propandioic acid, 1.20×10⁻⁶ mol/L; pyruvic acid, 1.35×10⁻⁸ mol/L; citric acid, 5.10×10⁻⁸ mol/L; barbituric acid, 2.48×10⁻⁷ mol/L. The proposed method was successfully applied to determination of oxalic acid. The coupled chemiluminescent reaction mechanism and rate equation are proposed. Foundation item: Supported by the National Natural Science Foundation of China and the Natural Science Foundation of Hubei Province Biography: HAN He-you (1962-), male, Associate professor, phD, graduate candidate     

《宛如约》：男权社会下文人的幻想表达

古典小说《宛如约》作为明末清初的才子佳人小说之一，其所描写的女性才貌兼备，能主动寻找自己可托付终身的才子来作为丈夫。这些其实都是男权社会下文人的自我幻想表达。同时，其所涉及的婚姻由多妻制对妻妾制的代替，也不过是文人自己编织的美梦，是根本不可能实现的。     

一个含有苯并15-冠-5单元的Ru(Ⅱ)多吡啶配合物的合成及性质研究

合成、表征了一个多吡啶配体(L)和相应的Ru(Ⅱ)配合物[(bpy)2RuL](PF6)2.在室温乙腈溶液中,该配合物在452nm显示特征的金属-配体核移跃迁吸收峰,在641nm显示特征发射峰.电化学测试显示配合物有一个基于钌(Ⅱ)的氧化过程和三个基于配体的还原过程.配合物与钠离子的作用通过紫外可见吸收光谱、发射光谱和电化学滴定进行研究.把钠离子加入到配合物的乙腈溶液中,配合物的荧光强度增加、紫外可见吸收蓝移、基于钌(Ⅱ)的氧化峰向阴极移动.     

梁苑辞赋集团简论

汉初，“辞赋盛于藩国”，梁孝王门下的“梁苑集团”就是一个以辞赋创作为主的学集团，它曾发发了辞赋史上的第一创作高潮，为汉初辞赋的发展作出了极大的贡献。梁孝王携诸士入朝及司马相如游梁的时间，就是梁苑集团定型的时间。     

Neutron activation analysis and Mössbauer spectroscopy research on coloring mechanism of Chinese Ru porcelain

The characteristic spectrum and its main wavelength of Ru porcelain glaze are measured by color difference instrument to determine the relations between glaze color and its main wavelength. The content of the 30 coloring elements in Ru porcelain is determined by neutron activation analysis (NAA), which showed that iron is the major coloring element. Mössbauer spectroscopy analysis shows that the iron element in the glaze exists in the form of structural iron (Fe²⁺, Fe³⁺). The quantitative relationship between the main wavelength of glaze in various colors and the relative content of structural iron (Fe²⁺/Fe³⁺) is determined. Thus the coloring mechanism of Ru porcelain is investigated entirely.     

钌卟啉作为双功能模拟酶的研究

以３种钌卟啉［Ｒｕ（ＴＰＰ）（ＣＯ），Ｒｕ（ＯＥＰ）（ＣＯ），Ｒｕ（４－Ｃｌ－ＴＰＰ）（ＣＯ）］作为超氧化物歧化酶（ＳＯＤ）和过氧化氢酶（ＣＡＴ）双功能模拟酶。核黄素－蛋氨酸光照法证实它们在１０＾６￣１０＾５ｍｏｌ·Ｌ＾－１浓度范围内有清除Ｏ２·的作用；分光光度法证实它们能催化Ｈ２Ｏ２的分解，且分解率随浓度增大而增大；用小鼠肝匀浆法测定Ｒｕ（ＴＰＰ）（ＣＯ）、ＳＯＤ和ＣＡＴ，均表明具有较好的抗脂质     

Ru（phen）3^2＋与小牛胸腺DNA和鱼精DNA作用的研究

用吸收光谱、荧光光谱和ＣＤ光谱等方法研究了配合物Ｒｕ（ｐｈｅｎ）３２＋与小牛胸腺ＤＮＡ和鱼精ＤＮＡ的作用．结果表明，配合物Ｒｕ（ｐｈｅｎ）３２＋与小牛胸腺ＤＮＡ作用为插入作用方式，而与鱼精ＤＮＡ的作用却是面式结合方式．该配合物与这两种ＤＮＡ的作用具有不同的立体选择性．     

钙替代锶对钌氧化物磁学性质的影响

研究了钙替代锶对钌氧化物磁学性质的影响,利用Curie—Weiss定律确定了样品的Weiss温度TP,利用交流磁化率随温度变化的关系确定样品的Curie温度TC．测量了各温度下的磁滞回线,得到了样品的矫顽力．利用趋近饱和定律计算了样品的饱和磁矩．研究了Weiss温度、Curie温度、矫顽力和磁化强度随钙替代量的变化规律．