Molecular self-assembly behavior of mono[6-O-6-(4-carboxyl-phenyl)]-β-CD in solution and solid state

A novel modified cyclodextrin, mono[6-O-6-(4-carboxyl-phenyl)]-]-β-CD (1), has been synthesized by the reaction of mono[6-(p-toluenesulfonyl)]-β-CD with 4-hydroxybenzoate, and its molecular self-assembly behavior in both solution and solid state was studied by means of crystallography, NMR spectroscopy and microcalorimetry. The results indicate that the bezoic acid groups are successively penetrated intermolecularly into the adjacent β-CD cavities to form helical columnar supramolecules in the solid state. As compared with crystal, the similar self-assembly behavior of 1 in aqueous solution has also been confirmed by the ^1H ROESY spectroscopy. Thermodynamically, the formation of polymeric supramolecules by modified CD in aqueous solution is mainly driven by entropy changes.     

南方温室节水调温自动控制系统的研制

研制了采用新一代单片机的南方温室自动控制系统,该系统测定参数为温室内温度和土壤水分,控制对象为温室天窗和滴灌电磁阀,系统用液晶显示、按键输入并具有自动打印和存储实验数据的功能,本文从硬件和软件方面介绍本自动控制系统的设计与制作,目前该系统已在广东省国营幸福农场的温室投入使用．     

倒立摆控制方法的研究

运用牛顿动力学方法对单级倒立摆系统进行了数学建模,并对基于经典控制理论的PID控制法、基于自适应神经网络模糊控制方法进行了仿真对比分析研究。     

Forecasting the price of crude oil via convenience yield predictions

The paper develops an oil price forecasting technique which is based on the present value model of rational commodity pricing. The approach suggests shifting the forecasting problem to the marginal convenience yield, which can be derived from the cost‐of‐carry relationship. In a recursive out‐of‐sample analysis, forecast accuracy at horizons within one year is checked by the root mean squared error as well as the mean error and the frequency of a correct direction‐of‐change prediction. For all criteria employed, the proposed forecasting tool outperforms the approach of using futures prices as direct predictors of future spot prices. Vis‐à‐vis the random‐walk model, it does not significantly improve forecast accuracy but provides valuable statements on the direction of change. Copyright © 2007 John Wiley & Sons, Ltd.     

基于RBF神经网络在线辨识的永磁同步电机单神经元PID矢量控制

提出一种基于RBF神经网络在线辨识的永磁同步电机单神经元PID矢量控制新方法,该方法针对传统的PI调节器固定参数所造成的不足,利用具有自适应能力的单神经元PID调节器和RBF神经网络相结合,实现了参数在线辨识,转速在线控制.仿真结果表明该方法控制精度高,动态特性好,适合于永磁同步电机的速度控制.     

基于等效介质二维光子晶体平面波展开法的理论研究

应用等效介质理论,提出了一种计算二维光子晶体的新平面波展开法,数值模拟了圆介质柱在空气中正方排列结构的能带,模拟结果与常规的平面波计算结果符合的很好。     

Watchdog在Philips 8XC552单片机系统中的应用研究

介绍了8XC552单片机Watchdog的内部结构和工作原理,提出了在以80C552为CPU的嵌入式pH值智能测控系统中的实现方法,分析了调试中容易出现的问题及解决办法,最后给出了软件设计原理及代码实现.     

晶体铟的德拜温度和格林乃森参量随温度变化规律研究

研究了原子相互作用势与晶体德拜温度的关系．考虑到原子作非简谐振动，得到了格林乃森参量随温度变化的规律．以晶体铟为例，探讨了晶体德拜温度随温度的变化规律，理论计算与实验基本符合．     

光子晶体光纤熔接机理的研究

光子晶体光纤（PCF,Photonic Cpystal Fiber）的熔接技术为PCF产品的应用和开发提供了条件。本文主要介绍了影响PCF熔接的主要因素，比较了传统电弧熔接方法和激光熔接方法的优缺点，阐述了激光熔接的基本原理和工作流程，为PCF激光熔接机的制作打下基础。     

一维有限光子晶体中的单个缺陷

在一维有限光子晶体中利用传输矩阵推导了其反射和透射系数,并讨论了单个缺陷位置对透射系数的影响,发现单个缺陷在晶体中不同位置具有相同的缺陷模频率,但其透射峰具有不同的高度,同时当缺陷在晶体中心时,其透射峰最高。