Synthesis and luminescence properties of Mn4+-dopant Ca14Zn6Ga10−xAlxO35 solid solution

Mn~(4+)-activated oxide phosphors,owing to their desirable spectral features,eco-friendly and low cost,are emerging as a new class of non-rare-earth red phosphors for warm white LEDs.However,these phosphors possess low photoluminescence quantum efficiency excited by blue chip currently.Herein we report an isostructural solid solution of Ca_(14)Zn_6Ga_(10-x)Al_xO_(35):0.15Mn~(4+)(0≤x≤10)synthesized by a traditional solidstate reaction route.The microstructure and luminescent performance of this red-emitting phosphor are investigated in detail with the aids of X-ray diffraction,diffuse reflection spectra,photoluminescence spectra/decay/QE,and temperature-dependent PL/QE measurements.Blue shift of energy peaks of~4A_2→~4T_1and~4A_2→~4T_2transition is illustrated by the Tanabe–Sugano diagram and the configurational coordinate diagram.The crystal field strength(Dq)and the Racah parameters(B and C)are carefully calculated to estimate the nephelauxetic effectβrespectively.Particularly we achieve external and internal quantum efficiencies as high as26.1%and 40.3%for Ca_(14)Zn_6Ga_6Al_4O_(35):0.15Mn~(4+)excited by 466 nm,the highest one ever reported in Mn~(4+)activated oxide phosphors under the similar condition.     

Experimental investigation and thermodynamic assessment of the yttriumhydrogen binary system

A coupled experimental investigation and thermodynamic study of the yttrium-hydrogen(Y-H) binary system were carried out to provide more comprehensive and quantitative insights into the key thermodynamic properties of this system. Y-H system in the full range of H/Y = 0–3.0 was investigated by accurate pressure composition isotherm(PCI) measurement to provide credible phase equilibria information and thermodynamic data.The phase boundaries obtained were in agreement with previous experimental data but with improved accuracy.With the guide of the crystal structures, all the solid phases were modelled using the three sublattice model. The Y-H phase diagram and thermodynamic parameters were calculated and assessed with the CALPHAD technique.The obtained results are in very good agreement with our experimental data and the published data reported in literature. The obtained thermodynamic database of Y-H system can be used to predict the hydrogenation behavior and decomposition temperatures of hydrides.     

帽形加劲复杂卷边槽钢柱偏压性能试验研究

对共计18个简支试件进行偏心受压试验,分析并研究了未加劲、腹板中央帽形加劲、腹板和翼缘中央帽形加劲3种截面复杂卷边槽钢的极限承载力、失稳模式及变形特征等特性.结果表明:有效形心移动对偏心承压构件的承载能力有很大影响.在板件中央设置帽形加劲可以适当减小板件的宽厚比,显著提升受压构件的极限承载力及钢材利用率,但畸变屈曲在构件失稳模式中起控制作用.在同等条件下,板件中央帽形加劲偏压构件的承载效率提升了15%~70%.     

长篇小说史诗性的流变——兼论张翎的长篇新作《阵痛》

随着时代的变迁，长篇小说引以为骄傲的史诗性元素逐渐淡化和消解。摈弃了英雄主义价值取向的现代小说家们，审视、质疑、静观历史的潮变，揭示人物内心的冲突、痛苦、绝望……张翎的长篇新作《阵痛》成功地给中国当代文学以启示：在告别宏大历史叙事、告别强而硬的政治激情之后，建立在男权基础上的历史解构之后，小说应以怎样的讲述来开辟新径，来完成影像时代里自身的重新建构。     

考虑退货需求转移的在线渠道决策与协调

通过借鉴现实中的在线渠道运营模式,建立了由一个加盟商和一个在线零售商组成的在线渠道模型,其中在线零售商为主导者,加盟商为跟随者,两参与者销售的是相互间完全替代的产品,并且,将消费者退货的那部分需求在两渠道间转移的情况引入到模型中.分别分析了分散决策和集中决策下的最优决策情况,并对两类决策下的收益情况进行了对比.结果发现,集中决策在一定情况下能够实现渠道总收益的增加.结果还表明,位于约束边界和不在约束边界下的最优决策随各参数的变化情况差异很大.最后,通过激励相容契约和借鉴Nash的议价模型来协调在线渠道.     

Fe3O4表面逆水煤气反应的DFT研究

采用密度泛函理论（DFT）研究了Fe3O4（111）表面逆水煤气反应的机理（氧化还原机理和中间产物分解机理）。通过优化初始构型,得到了最稳定的吸附构型。对两种机理主要的基元反应活化能进行了比较,结果表明：氧化还原机理是主要的反应机理,中间产物分解机理较难发生。计算结果还表明八面体Fe原子在吸附和活化过程中起着重要作用。     

基于自适应特征融合的均值迁移目标跟踪

提出了一种基于自适应多特征融合的目标跟踪算法.分别利用RGB颜色和LBP纹理特征建立目标模型,通过线性加权将两类目标子特征模型代入目标相似性函数并用均值迁移算法进行目标位置优化计算.在跟踪过程中,引入S igmoid函数动态调整两类子特征权重,并利用子特征相关系数和可靠性指数对目标特征模型选择性自适应更新.实验结果表明,该算法能在跟踪场景和目标外观变化时自适应调整两种子特征权重,避免了特征失效导致的跟踪失败;特征模型选择性更新策略有效抑制了模型漂移.与单一特征和模型直接更新的跟踪方法相比,该算法在复杂跟踪环境更具有鲁棒性,能进行准确稳定的实时跟踪.     

受激布里渊散射慢光系统中强度调制器的应用研究

基于Mach-Zehnder干涉式的强度调制器具有移频特性,用于受激布里渊散射的慢光系统可以用来产生具有布里渊频移的信号光.理论和实验分析了M-Z干涉式电光强度调制器的频移特性.受激布里渊散射慢光实验中利用12.5 Gbit/s的电光强度调制器产生了相对于泵浦光具有9.394 GHz布里渊频移,脉宽为50 ns的信号光.在泵浦功率20 mW的情况下,该脉冲在2.5 km长的高非线性光纤中获得了32 dB的非饱和增益,脉冲延迟了25 ns.     

“杜西结论”的推广

研究和推广"杜西结论",设α∈φn={(a1,a2,…,an)|ai∈N,i=1,2,…,n},定义杜西变换:D(α)=(|a1-a2|,|a2-a3|,…,|an-a1|),利用离散动力系统的分析方法,研究更一般的问题,得出结论:n(n=2k,(k=1,2,…))个自然数形成一个环形,再进行相邻两数大数减小数,则在有限步内n个数必都变为零,即对任意α∈φn,当n=2k,(k=1,2,…)时,存在m∈N,有Dm(α)=θ,并得出几个相关的结论.     

多用户正交多级差分混沌键控通信系统

针对传统差分混沌键控(differential chaos shift keying, DCSK)采用多电平方式传输多进制信息导致误比特率(bit error rate, BER)高的缺点,提出一种多用户正交多级DCSK(multi-user orthogonal multi-level DCSK, MOM-DCSK)通信系统。该系统将传输的多进制信息映射为不同的传输系数,多个传输系数分别乘以对应的Walsh码后调制在信息承载信号上,并且通过不同的延时传输多用户信息。在加性高斯白噪声(additive white Gaussian noise, AWGN)信道和多径Rayleigh衰落信道中推导了系统的理论BER公式并进行了仿真分析。结果显示,该系统在传输多进制信息时拥有较好的误码性能,并且在多用户传输领域中有较好的实际应用价值。