相转移条件下钯催化合成邻氯苯乙酸

报道在相转移催化剂存在下，以Ｐｄ（ＰＰｈ３）２Ｃｌ２作羰基催化剂，用邻氯氯苄、一氧化碳为原料在常压下羰基化合成邻氯苯乙酸，收率６２．２％，并考察了该反应的影响因素。     

Г空间中量子态密度的计算

我们用两种方法计算了设计的积分,得出Γ空间中的相体积和量子态密度,并给予讨论。     

一种用于PSK及QAM的全数字低频载波恢复环路

介绍了一种新型的全数字化载波恢复环，用来直接从ＭФＰＳＫ或ＮＱＡＭ信号中提取同步的载波信号。由于实现了全数字的环路，这种环路将具有高度的稳定性、简洁性、实验结果表明环路具有良好的载波恢复性能和很小的相位抖动。     

苦杏仁酸合成方法的改进

采用聚乙二醇(PEG)代替季铵盐作为相转移催化剂合成苦杏仁酸。     

几种调制分类方法的原理与仿真试验研究

准对数似然函数比 (qLLR)、相位统计矩和不同阶幅度矩是调制分类的新方法。用qLLR方法构造检测MPSK信号的假设检验及其对数似然函数比 ,并求其数学期望 ,得到qLLR以BPSK/QPSK信号分类。相位统计矩方法利用MPSK信号符号初相位偶阶统计矩为M的单调递增函数的特性 ,并进行M进制识别复合假设检验。不同阶幅度矩进行调制分类的方法利用MPSK/MQAM信号每符号段波形起始点与其它点幅度的乘积统计矩特征进行调制分类。给出了计算机仿真试验评估。     

Effect of Zr addition on the stability of precipitated Laves phase and mechanical properties of Fe–Cr–Al-based alloys at high temperatures

The effect of a small amount of Zr addition on the temperature-dependent stability of Laves phase particles and mechanical properties of Fe-13.5Cr-4.73Al-2.07Mo-(0.34–0.5)Nb-(0.65–0.98)Ta-(0–0.33)Zr (wt. %) ferritic alloys was investigated in the present study. The designed alloy ingots were hot-rolled, aged at 1073 ?K for 24 ?h, and then re-treated at 1273 ?K, 1323 ?K, 1373 ?K, and 1473 ?K for 1 ?h, respectively. It was found that the Zr addition could not only stabilize the Fe₂M Laves phase (M ?= ?Mo,Nb,Ta,Zr) to a much higher temperature, but also induce the formation of stable Fe₂₃Zr₆ phase. The high-temperature (HT) microstructural stability of the alloys significantly was improved, as evidenced by the fact that a certain amount (0.66–1.19%) of precipitates (Fe₂M, Fe₂₃Zr₆, and core(Fe₂₃Zr₆)-shell(Fe₂M)-structured particles) with an appropriate size (～1.0 ?μm) uniformly distributed in the ferritic matrix even after being re-treated at 1473 ?K. Particularly, the formation of core-shell-structured particles at HTs was studied from the viewpoint of both solid solubility and diffusion coefficient of M in the matrix. All these aged alloys exhibited prominent mechanical properties at both room and elevated temperatures, showing high yield strength with σ_YS ?= ?490–560 ?MPa at room-temperature and σ_YS ?= ?80–85 ?MPa at 1073 ?K. The strengthening effect was further discussed in light of various strengthening mechanisms, and the calculated strength are in good agreement with the experimental results.     

利用高细度法布里-珀罗装置传输的低发散度高斯光束

本文分析了通过一高细度法布里-珀罗装置的低发散度高斯光束的传输，推算出了所讨论的传输光波相关参数，分析了在低反射率和高反射率两种情况下光束经法布里-珀罗装置的传输情况。     

渗流模型在临界现象和相变中的应用

本文阐述了渗流模型及其特征和它与临界现象及相变的联系，举例说明它在临界现象与相交中的应用，并给出了用计算机模拟座渗流的例子．     

相转移催化法合成ACC

ACC(1—氨基环丙烷—1—羧酸)是一种新型植物生长调节剂。本文报导的是通过相转移催化法以氰乙酸乙酯为原料合成ACC的方法。该法具有反应步骤少、时间短、产率高的特点,是适用于生产的合成路线。     

第三类边界的空心圆柱相变问题分析

本文分别利用正则摄动法和数值法,求解了第三类边界条件下的熔解物完全排除的空心圆柱内相变问题(烧蚀),并对两种方法进行了比较,符合程度相当好.当ste≤0.5时,最大偏差不超过3.6％.文中还讨论了无量纲参数ste、Bi、Bj和气流温度Qg对熔化速度的影响.