Nd:YIG磁和磁光性质理论研究

应用量子力学理论计算了Ｎｄ：ＹＩＧ和Ｎｄ＾３＋在ＯＫ～３００Ｋ热力学温度范围内的磁矩及它对Ｆａｒａｄａｙ偏转的贡献，结果表明Ｎｄ：ＹＩＧ稀土次点阵的磁光疚主要来源于离子内４ｆ＾３→４ｆ＾２５ｄ电偶极跃迁，晶场和交换作用是决定磁矩和磁光效应的两具重要因素。在计算基组态的晶场劈裂时，必须考虑＾４Ｉ谱项的４个多重态间的混合，否则会引起较大误差，计算结果与实验符合良好。     

Quantum Size Effect of the Magnetism of an Electron in a Metal Layer of the Layered Compounds M/I/M/I…

The energies and the magnetization of an electron in a piece of metal in the structure of Metal/Insulator/Metal/Insulator…(M/I/M/I…), in a magnetic field, at high temperature, and in range of quantum size thickness of the piece of metal layer have been obtained. The results show that when the thickness of the metal layer becomes smaller, the orbital magnetism of the charged particles which collide with the wall of the metal layer is to vary from diamagnetism to paramagnetism. The smaller the thickness of the metal layer becomes, the more particles will collide with the boundary of the metal layer, and then the paramagnetism becomes stronger. Finally, when the thickness of the metal layer becomes very small (＜100 nm), all of the orbital diamagnetism will reverse to paramagnetism, and then the paramagnetization will be almost a maximum constant.     

αFe磁化特征的唯象分析

利用铁磁性分子场理论的基础上,通过引入热无序能、冷无序能、与自发磁化相关的有序能之间的竞争机制下,引入了有效分子场系数.利用考虑与温度相关的有效分子场系数λ(T)的分子场理论研究了αFe的磁化特征,得到了与实验相符的结论,解释了铁磁性物质的约化自发磁化强度与温度的关系,解释了C/χ-T曲线在磁相变温度附近向上弯曲的原因,解释了顺磁居里温度θP大于铁磁居里温度TC的实验结果,解释了铁磁性物质中的有序-无序竞争与宏观磁性的关系.     

极化矢量■与磁化矢量■的关系

本文讨论电磁场与介质的相互作用。认为在一般情况下,介质既产生极化,也产生磁化。因此,极化对介质的磁化有贡献。同样,磁化对介质的极化也有贡献。     

电导法研究固体自溶液中的吸附

用电导测定法研究固体自溶液中吸附电解质吸附质的可能性,发现在室温下,有机酸的pka≤2.0时,其水溶液的电导率与浓度在一定范围内具有良好的线性关系。研究了活性炭自溶液中对乙二酸的吸附,从饱和吸附量所计算出的活性炭的比表面S值与文献值相等。     

DNMR 研究金属烯烃内质子交换的动力学行为

该文用完全线形分析法、磁化强度迁移法和自选锁定技术等三种具体的DNMR法对含有不同取代基的金属烯烃有机化合物中因碳碳键转动引起的分子内质子的化学交换的动力学行为进行了较为详细的研究。结果表明，测得的化学交换的速率常数是合理的。它们满足Eyring 和Ar-rehenuius 关系式；由此获得的化学交换的活化能参数和活化自由能的变化与化合物中的取代基的Hammett 常数6存在很好的一致关系。     

自旋分别为1/2及3/2的双层铁磁薄膜磁性分析

采用变分累积展开的方法．考察了由自旋分别为1／2及3／2的两个铁磁单层膜组成的双层膜系统的自发磁化强度随温度的变化情况，特别是在自旋为3／2单层的单粒子各向异性对这种变化的影响，获得了这种变化的特征行为．     

Measurement of Magnetization Curve and Magnetic Relaxation for 2H-NbSe2 Crystals

The characteristics of electronic transport properties: behaviors of magnetization curve and magnetic relaxation of a typical normal superconductor 2H-NbSe2 are investigated. The results show that Tc and △Tc of the samples are 7. 2,0. 18 K, indicating that superconducting energy gap at zero temperature is 1. 1 meV. No fish tail shape is found in the magnetization curves at several temperatures. The relationship between remnant magnetic moment and time reveals that the magnetic flux creep of the sample agrees with the Kim-Anderson thermal activation model with the relaxation rate S=0.000 36 at T=6 K.     

非晶Tb-Gd-Co合金薄膜特性研究

磁光存储材料的研充,最重要的是探求实用化磁光介质薄膜材料和制备工艺.非晶稀土-过渡金属(以下缩写为RE-TM)材料,适于使用制作磁光盘已崭露头角,由三元合金Gd-Fe-Co或Tb-Fe-Co膜做成的磁光盘样机已经问世.在以(Tb,Gd)_x-(Fe,Co)_(1-x)为基础的合金薄膜系列里,Tb-Gd-Co比Gd-Fe-Co有更大的矫顽力,这对提高存储密度是有利的.此外,Tb-Gd-Co材料还可以提供稍大的克尔(Kerr)旋转角θ_k和宽温特性.近年来,人们很重视非晶Tb-Gd-Co膜的研究,Togami首先报道Tb-Gd-Co膜,随后,Luborsky等人从实验肯定Tb-Gd-Co膜用作磁光介质的稳定性.为使Tb-Gd-Co材料达到实用化,本文研究了溅射参数对非晶Tb-Gd-Co合金薄膜特性的影响,获得了比较好的     

GIANT MAGNETORESISTANCE EFFECTS IN Co／Cu （111） SUPERLATTICE

We present a spin-dependent scattering theory to explain the new type of magnetoresistance effect and magnetization in Co/Cu(111) su-perlattice with atomically smooth interfaces. Our model is simple, but the calculated results are consistent with the experimental ones.