相转移催化一步合成三唑酮的研究

研究了ＰＧＥ为固液相转移催化剂，固体Ｋ２ＣＯ３碱一步合成三唑酮，考察了二元溶剂，碱，ＰＴＣ，不同滴加方式对三唑酮收率的影响。结果表明：在适当条件下，三唑酮收率可达６５．４％。     

Experimental Studies on Ultrasonic Vibration Grinding of the Workpiece Made from Fine-crystalline Zirconia Ceramics

The performances of fme-crystalline zirconia ceramics in workpiece ultrasonic vibration grinding （WUVG） and conventional grinding （CG） with diamond wheel were researched. The effects of WUVG and CG on material removal rate, grinding forces, surface roughness and microstructure of zirconia ceramic were investigated. Experimental results indicated that： （1） The material removal rate （MRR） in ultrasonic grinding process is two times as large as that of in conventional grinding. The material removal rate increases with increasing grinding depth in both ultrasonic grinding and conventional grinding. （2） The ultrasonic vibration grinding force is lower than that of conventional grinding force, and the increase of the worktable speed leads to a decrease of the grinding force, while the grinding force increases with larger grinding depth in both WUVG and CG. （3） The surface of ultrasonic vibration grinding has no spur and build-up edge and its surface roughness is smaller than that of CG significantly. Surface quality of WUVG is superior to that of conventional grinding, it is easy for ultrasonic vibration grinding that material removal mechanism is ductile grinding.     

电致发热SiC多孔陶瓷导电性能研究

研究了Al，B和Zr元素对电致发热多孔碳化硅陶瓷导电性的影响。室温电阻率测定表明，加入Al，B和Zr都可显著降低电致发热多孔碳化硅陶瓷的电阻率，随着Al，B和Zr加入量的增加，试样的室温电阻率下降。讨论了Al，B和Zr在碳化硅中的存在形式，并分析了试样的导电机理。     

泡沫陶瓷的制作及其吸附和脱色作用探讨

以膨润土、陶土，滑石粉和稀土氧化物为主要原料，用聚氨酯泡沫塑料作载体，制作成一种泡沫陶瓷吸附剂，其比表面达７．８５×１０４ｃｍ２／ｇ，对溶液中铬的吸附和对污水的脱色处理作了初步试验，结果表明能使含铬浓度由１０００μｇ／Ｌ降至４００μｇ／Ｌ，能使污水色度降低１／８倍     

原料种类对C－B_4C－SiC复合材料性能的影响

就原料种类对Ｃ－Ｂ４Ｃ－ＳｉＣ碳／陶复合材料性能的影响进行了研究，当使用β－ＳｉＣ代替α－ＳｉＣ作原料时，复合材料的性能明显提高，特别是断裂韧性，提高幅度达２０％；鳞片石墨代替石油焦作碳原料时，复合材料表面密度和电阻率明显地降低，抗弯强度因鳞片石墨的各向异性及添加剂的不同，数据也各不相同。     

大气压下多孔陶瓷内放电的特征(英文)

在外加交流高压的条件下,多孔陶瓷内可以产生稳定的大气压微放电.通过对放电的图片以及电压、电流的分析得出微放电的部分物理特性.结果显示:陶瓷微孔内的微放电并不是由陶瓷的表面放电转变而成;多孔陶瓷孔内微放电的起始放电电压随着陶瓷厚度增加而升高,而随着多孔陶瓷孔隙率的增加而降低.     

Compound machining of silicon carbide ceramics by high speed end electrical discharge milling and mechanical grinding

A compound process that integrates end electrical discharge (ED) milling and mechanical grinding to machine silicon carbide (SiC) ceramics is developed in this paper. The process employs a turntable with several uniformly-distributed cylindrical copper electrodes and abrasive sticks as the tool, and uses a water-based emulsion as the machining fluid. End electrical discharge milling and mechanical grinding happen alternately and are mutually beneficial, so the process is able to effectively machine a large surface area on SiC ceramic with a good surface quality. The machining principle and characteristics of the technique are introduced. The effects of polarity, pulse duration, pulse interval, open-circuit voltage, discharge current, diamond grit size, emulsion concentration, emulsion flux, milling depth and tool stick number on performance parameters such as the material removal rate, tool wear ratio, and surface roughness have been investigated. In addition, the microstructure of the machined surface under different machining conditions is examined with a scanning electron microscope and an energy dispersive spectrometer. The SiC ceramic was mainly removed by end ED milling during the initial rough machining mode, whereas it is mainly removed by mechanical grinding during the later finer machining mode; moreover, the tool material can transfer to the workpiece surface during the compound process.     

铌、铈、锰掺杂对钛酸钡基陶瓷性能的影响

在钛酸钡中以五氧化二铌、三氧化二铈形式引入铌、铈元素,采用了固相法反应制备Nb、Ce双施主掺杂的微米级钛酸钡基正温度系数(PTC)陶瓷粉;同时研究了加入受主元素Mn对PTC陶瓷材料性能的影响。利用XRD和SEM分析了样品的物相及微观相貌,发现样品结晶完整,颗粒均匀。实验表明,以Ce、Nb、Mn进行掺杂可有效改善材料在室温条件下的PTC性能;当掺入0.2 mol%Nb_2O_5、0.3 mol%Ce_2O_3、0.08 mol%Mn(NO_3)_2时,制出室温电阻率为616Ω·cm、升阻比大于10、居里温度为60℃的PTC热敏陶瓷;并利用制成的PTC材料作为加热源对受控器件进行加热实验。     

CaO-MgO-Al2O3-SiO2系微晶玻璃晶化和性能

CaO MgO Al2O3 SiO2系微晶玻璃主要用于生产高档装饰材料,而影响微晶玻璃性能最主要因素是主晶相的种类及晶粒粒度·通过XRD,SEM等分析方法,探讨氧化镁在微晶玻璃中的作用以及氧化镁加入量对微晶玻璃密度和显微硬度的影响·实验结果表明:随着氧化镁含量的增加,一方面析晶温度有所升高,不利于微晶玻璃的晶化,但有利于烧结的进行;另一方面试样的显微形貌由放射状或纤维状集合体向粒状块体转变,使密度和显微硬度增大,提高了它的性能·     

成坯压强对PZN 基陶瓷性能的影晌

用二次合成法制备了 0 .75Pb( Zn1/ 3 Nb2 / 3 ) O3 - 0 .1 5Ba Ti O3 - 0 .1 0 Pb Ti O3 固溶体陶瓷 ,并研究了成坯压强的变化对该类材料的密度、晶粒尺寸、介电性能和电致应变性能的影响 ,结果表明 :随着成坯压强的增加 ,陶瓷的密度有所增加 ,其介电性能和电致应变性能也得到了提高。