Preparation of (R)-and (S)-2-Allyl-1,3,2-Dinaphtho(α,β)[d.f]dioxaborepin and Their Reactions with Aldehydes

0　IntroductionEnantiopure 1,1′ bi 2 naphtholspossessingC2 chiralityhaveprovedtobeversatilechiralauxiliariesinanumberofasym metricreactions[1 \|6] .Althoughsomeboroncompoundsofthemhavebeenprepared[7 1 6] ,chemistryoftheirallylboranederivativeshasneverbeenreported .Toexplorepossibilityofapplyingseven memberedcyclicchrialallylboronateesterstoasymmetricsynthesisofchiralβ alkenylalcohols,whichareimportantintermediateinthepreparationofopticallyactivenaturalproducts,werecentlyat temptedtosynthesi…     

A surface-based DNA algorithm for the minimal vertex cover problem

Abstract DNA computing was proposed for solving a class of intractable computational problems, of which the computing timewill grow exponentially with the problem size. Up to now, many achievements have been made to improve its performance and increase itsreliability. It has been shown many times that the surface-based DNA computing technique has very low error rate, but the technique hasnot been widely used in the DNA computing algorithms design. In this paper, a surface-based DNA computing algorithm for minimal ver-tex cover problem, a problem well-known for its exponential difficulty, is introduced. This work provides further evidence for the abilityof surface-based DNA computing in solving NP-complete problems.     

Discovery of the granulite xenoliths in Cenozoic volcanic rocks from Hoh Xil,Tibetan plateau

Two-pyroxene granulite and clinopyroxene granulite xenoliths have been recently discovered in the Late Paleogene toNeogene volcanic rocks (with ages in the range of 4.27～44.60 Ma) that outcropped in Hoh Xil, central Tibetan plateau. Based on theelectron microprobe analysis data, the xenoliths provide constraints for the formation equilibrium temperatures of the two-pyroxene gran-ulite being about 783 to 818℃ as determined by two-pyroxene thermometry and the forming pressure of the clinopyroxene granulite beingabout 0.845 to 0.858 GPa that is equivalent to 27.9～28.3 km depth respectively. It indicates that these granulite xenoliths represent thesamples from the middle part of the thickened Tibetan crust. This discovery is important and significant to making further discussion onthe component and thermal regime of the deep crust of the Tibetan plateau.     

磁空间群Pб_ 3/m''''m’c''''不可约共表示的计算

群表示理论在群论的发展和应用中占有十分重要的地位,它对求解C-G系数,同位标量因子及母分系数是必不可少的。本文主要以P6_3”m′m′c′的对称点L点为例,应用诱导表示的方法,介绍磁空间群不可约共表示的计算方法。     

光滑流形在(Z2)2作用下信息为{(2,2,0),(2,0,2),(0,2,2)}的上协边类

设(Z2)^2作用于光滑闭流形M^n，其不动点集的法丛的信息为P＝{(2，2，0)，(2，0，2)，(0，2，2)}，Jn^4，2(P)是有代表元M^n且具有上述性质的n维上协边类[M^n]构成的集合．作者通过构造上协边环M0n的一组生成元决定了Jn^4，2(P)的群结构．     

加入WTO后我国金融管理分析

当前我国的金融业,有商业银行不良债权,上市公司质量隐患等问题。加入WTO对我国金融业既是机遇也是挑战,应对WTO;中国金融业应当从健全金融法规,加强金融监管,进行金融创新等方面积极应对金融业进一步开放。     

2-氨基-3-氰基-4-(2’,4’-二氯苯基)-4H-萘并[1,2-b]吡喃的合成和晶体结构

标题化合物C22H17Cl2NO3的晶体由α-乙氧羰基-2,4-二氯肉桂腈、β-萘酚在TEBA存在下合成并经DMF与水的混合溶剂重结晶而得.其结构通过元素分析、IR和1HNMR进行了表征,用X射线单晶衍射法测定了该化合物的晶体结构.结果表明,晶体属于单斜晶系,P21/n空间群。a=1.450 5(2)nm,b=0.903 7(1)nm,c=1.491 3(2)nm,α=90°,β=101.21(1)°,γ=90°,Mr=414.27,V=1.917 5(4)nm3,Dc=1.435 g·cm-3,Z=4,μ(MoKα)=0.362 mm-1,F(000)=856.晶体结构用直接法解出,经全矩阵最小二乘法修正,最终偏离因子R=0.044 44,Rw=0.117 7.化合物分子中,原子C(1),C(2),C(3),C(4),C(5)和O(1)形成一个六元环,该六元环中C(1)-C(2)键长为0.134 6(3)nm,表明为双键.此六元环为船式构象.     

DV数字视频的采集和编辑

分析了DV视频和1394采集卡的主要性能特点,介绍了基于PC的DV视频的采集和编辑技巧,为初学者提供一些解决影视编辑中常见问题的经验和方法。     

用ASP.net制作动态网页

随着互联网的发展，网页的制作由静态转向动态，即网页已具备交互性与自动更新的功能，分析了微软的新战略，NET，以及基于．Net framework sdk的ASP．net和ADO．net，利用ASP．net制作了一个实用的动态网页．     

Oxidative Treatment of Some Reactive Dyes by Fenton Reagent

Nine kinds of reactive dye solutions: Reactive K-2RL, H-E2R, X-6B1Y, HE-4G, X-3B, K-2R,H-E7B, X-4RN and S-F3B were treated by usingFenton reagent. While the concentration of dye is 400mg/L, the FeSO_4 dosage 100-180 mg/L, H_2O_2 240～540 mg/L, that is the stoichiometric numbers of Fe~(2+)and H_2O_2. are between 1: 9～1: 12, pH=3, reaction