DIMOX工艺制备复合材料熔体表面Mg蒸气扩散动力学研究

从热力学角度分析了Al-Mg-Si合金直接氧化生长Al2O3/Al复合材料工艺过程中,熔体表面Mg蒸气层的存在,按照气体扩散传质支力学原理,解析了Mg蒸气层的厚度。结果表明：熔体上方Mg蒸气层的厚度δ与熔体表面距坩埚上沿的距离L成正比,坩埚上沿处O2的摩尔分数增加,Mg蒸气层厚度减小。Mg蒸气层厚度与材料自氧化生长速度密切相关。     

锦州市女儿河底泥中重金属元素污染状况评价

针对女儿河沿岸铁合金厂冶炼废渣的排放,上游多家个体钼矿的开采带来的污染的现实,采用原子吸收光谱法对底泥中的Cu、Pb、Cd、Cr、Ni、Zn进行测定分析,并运用不同方法和标准来评价女儿河底泥重金属的环境状况。无论以自然背景值、单因子污染指数还是内梅罗污染指数法对该河段各底泥样品重金属污染程度进行综合评价。底泥重金属都超过污染指标,污染程度为Zn>Cr>Ni>Cu>Pb>Ca。对表层底泥重金属及分布规律的研究表明,污染程度与铁合金厂废渣排放和矿区位置成正态分布,是主要重金属污染源。     

制备CeO2纳米涂层的重复性研究

用MOD法制备CeO2纳米涂层薄膜,研究和分析了CeO2薄膜的成相重复性和表面重复性,得出了1 000℃为最佳烧结温度、烧结气氛中氧元素的摩尔百分含量为0.01%的条件;研究了不同烧结工艺对CeO2薄膜表面形貌的影响,发现随着烧结温度的提高和时间的延长,薄膜的晶粒增大,表面起伏增大,表面粗糙度也随之增大,60 min为最佳保温时间;前驱溶液的浓度也会影响薄膜的致密性,浓度过大会使薄膜出现孔洞。     

Effects of doping in 25-atom bimetallic nanocluster catalysts for carbon–carbon coupling reaction of iodoanisole and phenylacetylene

A trio of thiolate-protected atomically precise gold nanoclusters, [Au_(23)(S-c-C_6H_(11))_(16)]~–, Au24(SCH_2pH~tBu)_(20)and [Au_(25)(SCH_2CH_2pH)_~(18)]~–, are utilized as catalysts for 4-nitrophenol(4-NP) reduction to 4-aminophenol(4-AP).Despite nearly identical sizes(~1 nm), the three nanoclusters possess distinctly different atomic packing structures and surface ligand binding modes, which contribute to different catalytic performance. The [Au_(23)(Sc-C_6H_(11))_(16)]~–nanocluster shows the highest activity with a kinetic rate constant of 0.0370 s~(-1), which is higher than those of Au24(SCH_2pH~tBu)_(20)(0.0090 s~(-1)) and [Au_(25)(SCH_2CH_2pH)_~(18)]~–(0.0242 s~(-1)). Such a trio of gold nanoclusters indicate that the atomic packing mode and electronic structure play a crucial role in determining their catalytic performance.     

太原市污灌区重金属污染现状评价

本文对太原市污灌区水质、土壤和作物中Hg、Cd、As三种元素的污染状况进行了研究.结果表明,二坝灌区水质属轻度污染;土壤中Hg和Cd含量超过背景值;土壤与作物中三种元素的含量之间存在一定的相关性,其中Hg的相关系数为显著水平.     

High efficiency synthesis of HKUST-1 under mild conditions with high BETsurface area and CO2 uptake capacity

This study focuses on the development of a hydrothermal method for the rapid synthesis of good quality copper benzene-1,3,5-tricarboxylate(referred to as HKUST-1)with high yield under mild preparation conditions to address the issues associated with reported methods.Different synthesis conditions and activation methods were studied to understand their influence on the properties of HKUST-1.It was found that mixing the precursors at50°C for 3 h followed by activation via methanol refluxing led to the formation of a product with the highest BET specific surface area of 1615 m~2/g and a high yield of 84.1%.The XRD and SEM data illustrated that the product was highly crystalline.The sample was also tested on its capacity in CO_2 adsorption.The results showed strong correlation between surface area of the sample and its CO_2 uptake at 1 bar and 27°C.The HKUST-1 prepared in this study demonstrated a high CO_2 uptake capacity of 4.2 mmol/g.It is therefore concluded that this novel and efficient method can be used in the rapid preparation of HKUST-1 with high surface area and CO_2 uptake capacity.     

MOCVD法制备云母珠光颜料光学性能及微结构研究

在流化床反应器中以碳基铁为物源，用金属有机化学气相沉积(MOCVD)法制备了云母珠光颜料．由颜料的SEM和EPMA图分析表明：云母微粒为片状结构，平均粒径为50μm；沉积在云母表面上的是均匀分布的30-nm的透明氧化铁微粒，这种结构对光能产生多重散射、折射、反射，从而呈现出绚丽的珠光光泽．     

Synthesis, characterization and antibacterial activity of copper, nickel and bimetallic Cu– Ni nanoparticles for potential use in dental materials

The antibacterial effect is a desirable property in dental materials.Development of simple methods for the preparation of nanosized metal particles has attracted significant attention because of their future applications due to unusual size-dependent antibacterial properties.Copper(Cu),Nickel(Ni) and bimetallic Cu–Ni nanoparticles were prepared by a simple chemical method and their antibacterial activity was tested against the widely used standard human pathogens Staphylococcus aureus(gram-negative) and Escherichia coli(gram-positive).Additionally,these nanoparticles were tested against the dental pathogen Streptococcus mutans.Our results are promising for potential use in dental materials science.     

金属硅化物—硅功率肖特基二极管

本文用X射线衍射（XRD）方法、俄歇电子能谱（AES）分析和电学测量方法研究了Ti/Si、Ni/Si和Cr/Si三种结构的金属硅化物的形成和特性。用电流－电压法和电容－电压法测量分析了TiSi2/n-Si、Nix/n-Si和CrSi2/N-Si三种肖特基势垒二极管特性，其势垒高度分别为0．61eV、0．66eV0．66eV，理想因子均接近1。用此项技术制作的金属硅化物－n型硅肖特功率二极管有优异的电学性能。     

X70管线钢用低氢型立向下焊条的研制

阐述了用于X70高强度微合金化控轧管线钢的低氢型立向下焊条的研制结果.分析了大理石、萤石、钛铁、硅铁等物质含量及CaF_2/CaCO_2值对熔渣性能的影响规律.确定了具有良好立向下焊工艺性能的药皮配方.经化学分析、力学性能试验、金相分析和工艺性能试验证明,这种焊条初步达到现国标GB5118—85E5515型(相当于AWSE8015或JISD5815)的要求。且每100g熔敷金属扩散氢含量低于4mL,因而具有优良的抗裂性和低温冲击韧性.