Effect of nanoparticle (Pd, Pd/Pt, Ni) deposition on high temperature hydrogenation of Ti-V alloys in gaseous flow containing CO

The hydrogenation properties of Ti-V hydrides coated with nanoparticles have been studied in gaseous mixtures of argon and hydrogen with and without additions of 1% CO. Nanoparticles of Pd, Ni, and co-deposited Pd/Pt with particle sizes of ~30–60 nm were formed by electroless deposition on the hydride surfaces. The alloy resistance to CO could be significantly improved by particle deposition. Large amounts of hydrogen were absorbed in a CO-containing gas when Ni and Pd/Pt deposition had been applied, while pure Pd deposition had no positive effect. Ni was found to have a stronger effect than those of Pd/Pt and Pd, possibly because of the size effect of Ni nanoparticles.     

搅拌法生产金属基／非金属粒子复合材料的辅助工艺措施

本文综述了采用搅拌法生产金属基/非金属粒子复合材料的几种辅助工艺措施及其作用.     

表面S钝化技术与金属／GaAs界面异质结构

本文详细讨论了GaAs表面S钝化技术的发展过程，总结了近年来人们对S钝化技术的研究成果，并针对该技术在金属／GaAs异质结构领域的广泛应用前景进行了讨论。     

HCR金属冷冲压润滑剂的研究

本文以合代油为基础油,开发了适宜的极压添加剂研制了一种新型水系金属冷冲压润滑剂,介绍了生产工艺,技术条件,产品性能。     

GaAs中过渡金属深能级的量子化学计算

本文采用17个原子的原子蔟,用电荷-组态自洽的EHMO方法,计算了中性过渡金属原子Cr、Mn、Fe、Co、Ni在半导体GaAs中的深杂质态,所得杂质能级在能隙中的位置与实验结果较好地符合.     

金属硅化物—硅功率肖特基二极管

本文用X射线衍射（XRD）方法、俄歇电子能谱（AES）分析和电学测量方法研究了Ti/Si、Ni/Si和Cr/Si三种结构的金属硅化物的形成和特性。用电流－电压法和电容－电压法测量分析了TiSi2/n-Si、Nix/n-Si和CrSi2/N-Si三种肖特基势垒二极管特性，其势垒高度分别为0．61eV、0．66eV0．66eV，理想因子均接近1。用此项技术制作的金属硅化物－n型硅肖特功率二极管有优异的电学性能。     

金属基复合材料的研究现状与应用

金属基复合材料是一类新型的复合材料，它因具有高比强度、高比模量、高耐磨性高优异性能而引起人们的关注。本文综述了金属基复合材料的研究现状，制造工艺和性能。同时介绍了这种材料在航天、航空、先进武器系统、汽车工业等领域中的广泛应用。     

复合无机盐法分离铜包钢复合金属

铜包钢复合材料的出现在节约了大量有色金属,也带来了资源再利用的难题,为了减少复杂的物理回收方法带来的能源浪费和环境压力,实现资源的合理利用,借助合成氨工业上的铜氨液工艺,在催化剂的作用下,把铜包钢废弃物中的铜提取出来。经过滤、蒸发、浓缩、灼烧后转化为黑色氧化铜粉末,最佳配料比是Cu：NH3：（NH4）2CO3：催化剂为...     

金属橡胶辊压成形工艺及力学性能关联分析

针对新型辊压和传统冲压两种成形工艺制备薄壁平板状金属橡胶的微观结构和力学性能差异性,利用ABAQUS软件对成形过程进行有限元仿真,预测了两种金属橡胶内部细观结构的变形特征,验证了金属橡胶力学性能与结构的关联性,并确定了辊压优选参数。试验结果表明,不同成形工艺过程影响金属橡胶内部螺旋丝的钩连和接触形式,辊压比冲压得到的试样的刚度明显更低,但对金属橡胶的宏观损耗因子影响并不大;辊压时采用多道次、小压下量可以提高金属橡胶的阻尼性能,辊压速度和进料方向对金属橡胶的力学性能影响不明显。本研究工作为辊压成形制备金属橡胶的工艺设计及工程化应用提供了参考价值。     

High efficiency synthesis of HKUST-1 under mild conditions with high BET surface area and CO2 uptake capacity

This study focuses on the development of a hydrothermal method for the rapid synthesis of good quality copper benzene-1,3,5-tricarboxylate(referred to as HKUST-1)with high yield under mild preparation conditions to address the issues associated with reported methods.Different synthesis conditions and activation methods were studied to understand their influence on the properties of HKUST-1.It was found that mixing the precursors at50°C for 3 h followed by activation via methanol refluxing led to the formation of a product with the highest BET specific surface area of 1615 m~2/g and a high yield of 84.1%.The XRD and SEM data illustrated that the product was highly crystalline.The sample was also tested on its capacity in CO_2 adsorption.The results showed strong correlation between surface area of the sample and its CO_2 uptake at 1 bar and 27°C.The HKUST-1 prepared in this study demonstrated a high CO_2 uptake capacity of 4.2 mmol/g.It is therefore concluded that this novel and efficient method can be used in the rapid preparation of HKUST-1 with high surface area and CO_2 uptake capacity.