原子序数与镧系离子理化性质的相关性研究

用原子序数(N)代表镧系离子(Ln^3 )大体结构效应的因素，并将N对镧系离子的16种理化性质(P)进行线性回归，回归方程均在0．001显水平下通过F检验，估算值与实验值都很好吻合。     

Atomic-scale computer simulation for early precipitation process of Ni75Al10V15 alloy

The kinetic model for a ternary system is introduced based on the microscopic diffusion form of the phase-field equations for a binary alloy. The equation is solved in the reciprocal space. This model is used to investigate the early precipitation process of Ni75-Al10V15 by simulating the atomic pictures of the two ordered phases and calculating the order parameters of γ′(Ni3Al) phase. Simulation results show that the γ′ ordered phases precipitate from the disordered matrix by a non-classical nucleation mechanism, and the nonstoichiometric γ′ ordered phase appears first and then transforms into the stoichiometric one. Clusters of V atoms appear at the γ′ phase boundaries followed by the formation of the nonstoichiometric θ ordered phase. The farther the location from γ′ phase boundary is, the lower the order degree of θ phase is. There exist two kinds of DO22 ordered domains: a horizontal one and a vertical one, related to their adjacent γ′ phase boundaries. The model could describe the atomic ordering and composition clustering simultaneously, and any a priori assumption about the new phase structure and precipitation mechanism etc. is unnecessary.     

Computer simulation for the precipitation process of Ni75Al7.5V17.5 alloy

The precipitation mechanism of Ni75Al7.5V17.5 alloy above the L12 instability line, between the L12 and D022 instability lines and below the D022 instability line are studied using microscopic phase-field kinetic equation. This paper is aimed at investigating the effect of temperature on precipitation mechanism and morphological evolution of the alloy. Our simulations demonstrate that the precipitation is a mixed mechanism of non-classical nucleation growth and spinodal decomposition above the L12 instability line. It needs certain thermal fluctuations for nucleation and the number of θ phases is small at this temperature. The precipitation mechanism of γ'phase is congruent ordering followed by spinodal decomposition, and θ phase is a mixed mechanism of non-classical nucleation growth and spinodal decomposition between the L12 and D022 instability lines. The mechanism below the D022 instability line is similar to that between the L12 and D022 instability lines. With the decrease of the temperature, ordering and phase separation becomes fast, the dimension of γ'phase becomes small, the shape transforms from equiaxed to block, the dimension of θ phase becomes large and the shape transforms from strip to circle.     

Effects of Ca on the distribution, structure and morphology of aluminum species in polyaluminum chloride

The flocculation efficiency of polyaluminum chloride (PAC) is closely related to the distribution and structure of its AI species, and Al13 is the optimal species in PAC for flocculation. A series of PAC containing Ca was prepared by adding Ca before and after the basifying reaction. The effects of Ca on the Al species were studied by ^27Al nuclear magnetic resonance (NMR) and atomic force microscope (AFM) techniques. The experimental results show that the introduction of Ca increases the content of Alm and Al13 in PAC and decreases their chemical shifts in NMR spectra due to the electric repulsion between the positive Ca species and AI species and the formation of AI-O-Ca complexes.With the rise of Ca/AI molar ratio, the AI species in PAC tend to scatter. It is observed that the formerly branch-aggregated clusters are tending to form granule-aggregated ones whose diameter gets smaller and smaller, and the floccule aggregates are formed at a higher Ca/Al molar ratio. The introduction of Ca to PAC, which increases the Al13 content, is certainly to enhance the flocculation efficiency of PAC in water treatment.     

以多巴胺为配体示差脉冲伏安法间接测定生物体液中的铝

建立了用神经递质多巴胺作电活性配体示差脉冲伏安法间接测定生物体液中的铝的方法 .多巴胺在玻碳电极上的氧化峰电流随铝浓度的增加而线性下降 .在最佳测定条件 (pH 7.0 ,2 .4× 1 0 -4 mol/L多巴胺 ,0 .0 8mol/LNH4Ac缓冲溶液 )下 ,铝的检测下限、相对标准偏差 (4× 1 0 -6mol/LAl(III) ,n =8)、线性范围分别为 1 .7× 1 0 -7mol/L、3 .4%、4 .0× 1 0 -7～ 42×1 0 -7mol/LAl(III) .对许多生物体液中可能存在的物质进行了干扰试验 .采用标准加入法将所建立的方法应用于实际样品如人全血、脑病患者的脑脊液、糖尿病患者的尿、肺癌患者的腹水、合成肾透析液及合成脑脊液等样品中铝测定 ,结果表明回收率在 95 %～1 0 8%之间 ,所测得的样品中铝含量与文献值和ICP法值吻合 .通过紫外光谱、拉曼光谱及 1 3 C核磁共振谱探讨了测定方法的原理 .加入铝后多巴胺氧化峰电流的下降原因是铝与多巴胺的邻羟基配位 ,从而使电活性的多巴胺浓度下降     

2-D连续-离散系统的平衡模型降阶

基于局部能达性与局部能观性的分析给出2-D连续-离散系统状态空间模型的平衡实现,这一实现的第i个状态分量的重要性由系统的能达、能观阵的第i个对角元素所度量,去掉平衡实现系统弱能达、弱能观的部分,从而得到2-D连续-离散系统的模型降阶。所给示例表明,该方法具有良好的降阶效果。     

高性能面向对象场景图系统

描述了一种高性能场景图系统的设计与实现。主要的设计目的是使三维图形应用开发者从繁琐的低级API(如OpenGL)中解放出来并获得最高的图形性能。该系统可以工作在Windows和各种UNIX变体(如IRIX、Linux等)操作系统上，主要的目标操作系统是Windows，主要针对低端(单处理器)硬件平台(如个人电脑)。应用范围包括视景仿真、虚拟现实、科学可视化、临场感娱乐及其他实时三维图形应用。     

海军指挥作战自动化系统试验中的模拟测试软件

首先分析了模拟测试软件在C3I系统的开发、使用过程中的应用目的和重要作用，然后描述了模拟测试软件与指挥作战自动化系统的接口，最后介绍了利用新型仿真技术研制的模拟测试软件的功能，详细说明模拟测试软件的组成和实现和工作流程。     

基于Direct3D的虚拟战场环境中动态地形的实现方法

动态地形技术突破了以往地形结构不可破坏的限制，能够体现环境自身的内力作用和仿真实体的行为对环境的作用而引起的地形结构的变化，拉近了仿真与现实之间的距离。以最常用的不规则地形网格为研究对象，提出了通过建立“参照网格”来规则化的管理不规则网格的方法，分析了Direct3D环境中地形数据库的存储格式，给出了确定地面上任意一点在地形网格中的投影位置的遍历方法，基于以上，通过修改地形数据库内存数据实现地形外观的局部修改。     

基于UML的铁道车辆动力学仿真建模研究

铁道车辆动力学仿真活动包括仿真软件开发和使用软件建模仿真两个阶段。以面向对象的观点和方法重新研究了铁道车辆动力学仿真建模的需求和仿真软件设计。使用统一建模语言UML记录了3D组态动力学仿真建模需求，系统、部件、状态变量三级结构下的动力学计算机制，仿真软件结构和应用领域中重要的类及其关系。实现了一个基于部件影射的6自由度全量非线性的铁道车辆动力学仿真软件。