ZnAl_(27)Cu_1Mg_(0.01)合金人工时效过程的研究

利用X射线衍射和TEM较系统研究ZnAl_(27)Cu_1Mg_(0.01)合金经360℃均匀化处理后,在100℃时效过程中的相和组织转变顺序及其转变机制。观察分析发现:人工时效过程中相及组织转变顺序为βAl→ηZn→αAl→调幅分解→共析组织→胞状反应。     

Effect of Co addition on crystallization and magnetic properties of FeSiBPCu alloy

The effects of Co addition on the microstructure,crystallization processes and soft magnetic properties of(Fe1 xCox)83Si4B8P4Cu1(x?0.35,0.5,0.65)alloys were investigated.The experimental results demonstrated that the addition of Co decreased the thermal stability against crystallization of the amorphous phase,and thus improved the heat treatment temperature of this alloy.Fe Co Si BPCu nanocrystalline alloys with a dispersedα0-Fe Co phase were obtained by appropriately annealing the as-quenched ribbons at 763 K for 10 min.Theα0-Fe Co with grains size ranging from 9 to 28 nm was identified in primary crystallization.The coercivity(Hc)markedly increased with increasing x and exhibited a minimum value at x0.35,while the saturation magnetic flux density(Bs)shows a slight decrease.The(Fe0.65Co0.35)83Si4B8P4Cu1nanocrystalline alloy exhibited a high saturation magnetic flux density Bsof 1.68 T,a low coercivity,Hcof 5.4 A/m and a high effective permeability meof 29,000 at 1 k Hz.     

Influence of hot-rolling on the microstructure and mechanical properties of a near β-type Ti-5.2Mo-4.8Al-2.5Zr-1.7Cr alloy

In this work, the 90° clock rolling and the uni-directionally rolling processes at high temperature were carried out on the near β-type Ti-5.2Mo-4.8Al-2.5Zr-1.7Cr titanium alloy cutting from an ingot, respectively. The corresponding microstructures were quantitatively characterized, and its effect on the dynamic mechanical properties and fracture mechanism were emphatically investigated. It was found that after 90° clock rolling, the microstructure composed of equiaxed primary α phase(α_p) with an average size of about 2 ?μm and the β transformed regions containing the acicular secondary α phase(α_s) with an average thickness of about 50 ?nm and the separated β phase was obtained. However, in the uni-directionally rolled titanium alloy, no acicular α_s was observed, and the corresponding microstructure consisted elongated lamellar α phase (average thickness: about 1.3 ?μm), few equiaxed α phase (average grain size: about 300 ?nm) and the inlaid β phase. The microstructural difference of the hot-rolled titanium alloys was closely related to the deformation process. Moreover, a great number of α_p and α_s in the 90° clock rolled titanium alloy effectively enhanced the strength, and the dynamic compressive strength reached to 1730 ?MPa. Furthermore, equiaxed α_p was conducive to the homogeneous deformation, which counteracted the localized deformation caused by acicular α_s to a certain extent and made the 90° clock rolled titanium alloy exhibit an acceptable critical fracture strain of about 10.5%. Moreover, the fracture microstructures showed that the main failure mode of the 90° clock rolled and the uni-directionally rolled titanium alloy were ductile fracture and brittle fracture, respectively.     

Optimization of mechanical properties of Sn-3.8Ag-0.7Cu alloys by the additions of Bi,In and Ti

Bi, In and Ti were added to Sn-3.8Ag-0.7Cu (SAC387) solder alloy to optimize the mechanical performance. The alloying effects of Bi, In and Ti on the microstructure, thermal and mechanical properties of SAC387 based solder alloys were investigated. The results demonstrate that adding 3.5 ?wt % of Bi could refine the microstructure, optimize the thermal properties, and improve the tensile strength. Meanwhile, the ductility of the solder alloys reduced evidently. Adding 2.8 ?wt % of In into SAC387–3.5 ?wt %Bi alloy could increase both the strength and ductility, which is attributed to the beneficial effect of In addition, as adding In could improve the solubility of Bi in the β-Sn matrix. Meanwhile, the melting point was reduced, and the wettability improved with the addition of In. Introducing amounts of Ti into SAC387–3.5 ?wt % Bi-2.8 ?wt % In alloy could further increase the strength. However, the ductility was significantly reduced when 0.8 ?wt % of Ti was added due to the formation of the coarse Ti₂Sn₃ phase. The undercooling was remarkably reduced with the addition of Ti. The nanoindentation tests demonstrate that the hardness increased mainly due to the hardening effect of the Bi addition. Among all the samples prepared, alloy SAC387–3.5 ?wt % Bi exhibited the highest creep resistance at the ambient temperature. Further adding In and Ti into SAC387–3.5 ?wt % Bi alloys reduced the creep resistance of the solder alloys. The mechanism associated with the different mechanical responses is also discussed in this study.     

Stability of thermal cycling and high temperature mechanical properties for Ti–V–Al–B lightweight shape memory alloy

The microstructure of the Ti–V–Al shape memory alloy with refined grain and in-situ TiB phase was modified by doping minor Boron (B), which contributes to the superior mechanical performances and strain recovery characteristics. Compared with other quaternary Ti–V–Al-X alloys, the Ti–V–Al–B alloy showed the largest ultimate tensile stress due to the solution strengthening, grain refinement and precipitation strengthening of in-situ TiB phase. Moreover, the Ti–V–Al alloy added 0.1 ?at.%B possessed the maximum yield stress of 701 ?MPa and the largest tensile fracture strain of 27.6% at the temperature of 150 ?°C. Meanwhile, the excellent strain recovery characteristics with fully recoverable strain of 4% could be obtained due to B addition. Besides, B addition suppressed the precipitation of ω phase during thermal cycling and further improved the thermal cycling stability of the Ti–V–Al alloy.     

稻壳灰在超高性能混凝土中的研究应用进展

稻壳灰(Rice Husk Ash,RHA)是通过低温控制焚烧稻壳得到的一种具有高火山灰活性和巨大比表面积的火山灰质掺合料。相关研究表明,RHA由于其微观结构的纳米尺度SiO2胶凝粒子和大量纳米尺度的孔隙而获得高火山灰活性和大比表面积。将RHA替代硅灰(SF)应用于超高性能混凝土中,由于RHA的微填充效应,超细微孔结构及孔隙水的内养护作用,可改善混凝土的孔结构,获得高强度和高耐久性和低收缩性。因此,将稻壳灰作为一种绿色资源应用于超高性能混凝土中,在使混凝土获得超高性能的同时,可有效降低成本和充分利用资源,具有广阔的应用前景。     

Ni48.7Mn30.1Ga21.2铁磁性形状记忆合金的显微组织和相变行为

本文主要研究了Ni48.7Mn30.1Ga21.2铁磁性形状记忆合金的相变行为和显微组织。XRD结果表明：室温下合金为5M马氏体和母相共存,金相结果表明合金的显微组织为双相组织,在母相的晶粒中存在少量的马氏体片,合金的室温微观断口形貌表明该合金为典型的沿晶断裂,DSC结果表明该合金在升降温过程中发生了一步马氏体正逆相变。     

酚醛树脂—高铝水泥基无宏观缺陷材料的微结构

以热固性酚醛树脂和高铝水泥为原材料,采用双辊剪切混炼和二阶段热压养护等加工手段,制作了一类新型高强无宏观缺陷（ＭＤＦ）水泥基材料,采用傅立叶转换红外光谱（ＦＴ－ＩＲ）,Ｘ射线衍射谱（ＸＲＤ）等检测手段对其微结构的形成作了初步探讨。     

激光熔覆FeNiCrAl合金涂层的组织与腐蚀性能

在304不锈钢表面激光熔覆FeNiCrAl合金粉末,获得无裂纹耐腐性能优良的熔覆层,其厚度1.5～2.0 mm.利用SEM 分析熔覆层的显微组织结构,并测试熔覆层的腐蚀性并绘制极化曲线.结果表明,激光熔覆处理后涂层迅速熔化和冷却,组织由均匀的不规则多边形晶粒组成;熔覆层的自腐蚀电位比熔覆基体提高约70 mV、且自腐蚀电流密度比基体低,可知涂层的耐腐蚀性能相对基体要高很多.     

Effects of Ce-rich RE on microstructure and mechanical properties of as-cast Mg-8Li-3Al-2Zn-0.5Nd alloy with duplex structure

The effects of Ce-rich RE on the microstructure and mechanical properties of as-cast Mg-8Li-3Al-2Zn-0.5Nd-x RE(x = 0, 1, 2, 3 wt%) alloys were investigated. The results indicated that the as-cast Mg-8Li-3Al-2Zn-0.5Nd alloy mainly consisted of α-Mg, β-Li, AlLi, MgLi2 Al and Al2 Nd phases. With the addition of Ce-rich RE in the alloy,Al3 RE and Al2 RE phases generated and gradually grew into net-like or block-like structure. With the addition of RE, Al-RE phases generated by consuming Al element and, thus, less Al element was dissolved in the matrix and less AlLi phase formed. Furthermore, less AlLi phase means that more Li element released to cause the increase ofβ-Li phase and refine the α-Mg phase. Under the influence of these factors, adding more RE led to higher elongation and lower tensile strength and hardness. With the addition of Ce-rich RE, the yield strength and ultimate tensile strength of the as-cast Mg-8Li-3Al-2Zn-0.5Nd alloy gradually decreased from 180 to 152 MPa and from 215 to 193 MPa, respectively, while the elongation was remarkably improved from 21.1% to 40.2%.