New crystal structure of molecular complex 1-piperidine carboxylate-piperidinium-H<Subscript>2</Subscript>O studied by X-ray single crystal diffraction

Piperidine absorbs CO2 and H2O in air to form a molecular complex： piperidium-l-piperidinecarboxylate-H2O. The structure of the complex was characterized by X-ray single crystal diffraction. The crystal structure was determined to be triclinic, space group P1^-with a=0.648 6（8） nm, b=0.809 200） nm, c= 1.357 1（16） nm, a=96.96706）°, β =102.506（15）°,γ=104.202 05）°, Z=2. The complex is stabilized via five hydrogen bonds between the three components, N-O electrostatic interaction and O-O interaction （electron transfer） betweenl-piperidinecarboxylate and H2O. Due to electron transference of carbamate ion, the oxygen atom in water molecule is strongly negatively charged and the O-H bond is considerably shorter than that of the free molecule of water. The formation of the molecular complex is a reversible process and will decompose upon heating. The mechanism of formation and stabilization is further investigated herein.     

分解GaP源固态分子束外延生长InGaP/GaAs的结构和性能

采用分解GaP这一新型固态P源分子束外延在GaAs衬底成功制备了InGaP外延薄膜.3μm厚的InGaP外延层低温荧光峰位是1.998 eV,半峰宽为5.26 meV.双晶摇摆曲线的线宽同GaAs衬底相近.霍尔测量非故意掺杂InGaP外延层的室温迁移率同其他源或其他方法生长的外延层结果类似.     

过站航班地面保障流程效能评估

为了感知过站航班地面保障流程运行状况和优化机场协同决策信息系统,研究了单航班条件下的保障流程效能评估问题。通过系统分析地面保障流程,得到各场景的效能评估指标。结合评估指标的大小、重要性及聚散状态3个维度,构建了流程效能评估指标体系。设计了一种基于雷达图周长-面积的过站航班地面保障流程动态效能评估方法,并结合实际运行数据开展仿真验证。研究表明,流程效能评估结果整体上直观描述了保障流程效能的动态变化。通过客观性对比和敏感性分析可知,结果一定程度反映了过站航班离港属性,为航班推出控制提供依据。     

极端嗜热微生物分子伴侣蛋白研究与嗜热功能蛋白质的规模化制备技术研究

极端微生物是丰富的资源宝库,有着巨大的生物技术开发前景。本文从特殊功能蛋白质的发现与表征、结构与功能及潜在性应用．以及特殊功能蛋白质的规模化制备技术两个方面,对极端微生物的资源开发与利用进行了探讨。重点介绍了极端嗜热古菌Pyrococcus furiosus分子伴侣蛋白系统的一些研究,并以P．furiosus胞外α-淀粉酶PFA为例,对工业生物技术领域重组蛋白质的规模化制备技术进行了讨论。     

On the genus Racekiela in Mexico: molecular and morphological description of Racekiela cresciscrystae n. sp.

ABSTRACT

In Mexico, there are currently two known species of Racekiela: R. ryderii and R. montemflumina. Here we describe a new species from high-altitude streams in central and southern Mexico. Racekiela cresciscrystae sp. nov. presents two morphotypes: thick encrusting with raised ridges or lobose outgrowths at the surface and dark green in colour, or lime-green encrustations. The new species as megascleres presents microspined oxeas from 200 to 300 µm long, some centrotylote, or with malformations. Gemmules are spherical with a tri-layered theca, constituted by radially embedded birotules and pseudobirotules. The birotules have longer shaft than the rotule diameter, which is flat, and some slightly umbonate. Pseudobirotules of typical morphology have strongly or somewhat spined shaft. Spines can be straight or hooked. The species also presents other type of pseudobirotules, which are umbonate and with only small warts, instead of spines. DNA sequences from the nuclear ITS1-5.8-ITS2 region were sequenced from the holotype and a paratype of the new species to determine their phylogenetic relationships with other members of the family Spongillidae. Tree topologies (Bayesian Inference and Maximum Likelihood) were consistent in showing Racekiela creciscrystae sp. nov. as a sister clade of R. montemflumina confirming its allocation in a monophyletic genus Racekiela. A comparison with all the Racekiela species described so far is also included. This paper increases the number of species of freshwater sponges in Mexico, and confirmed that Racekiela is a monophyletic genus with morphological characters very well defined.

http://www.zoobank.org/urn:lsid:zoobank.org:pub:3769C54F-23C4-409A-AF02-81F3AA084F7A

http://www.zoobank.org/urn:lsid:zoobank.org:act:A512359D-E428-4D04-B08A-E189E3F6F962     

苯基表面改性MSU-x型介孔分子筛的合成与表征

在中性条件下以脂肪醇聚氧乙烯醚非离子表面活性剂C15H31O(CH2CH2O)9H(A(EO)9)为模板剂,用苯基三甲氧基硅烷(PTMS)与正硅酸乙酯(TEOS)共水解缩聚合成了苯基官能化的MSU-x介孔分子筛(Ph-MSU-x).用红外光谱(FT-IR)、小角X射线衍射(SAXRD)、扫描电镜(SEM)、热重分析(TGA)和氮气吸附-脱附等分析手段对样品进行了表征.结果表明,苯基已成功键合至介孔孔道表面,并保持了MSU-x介孔分子筛三维立体交叉排列的蠕虫状孔道结构,且改性后的Ph-MSU-x具有较强的疏水性、较高的热稳定性以及较大的比表面积、孔容和较窄的孔径分布.     

地方高校研究机构绩效评估指标权重的AHP算法

根据地方高校研究机构的科研特点，探讨了运用AHP理论确定高校研究机构绩效评估指标权重的方法。     

C_(60)的热力学函数与分子结构

在已获得的C6 0 分子取向几率与温度关系的基础上 ,考虑C6 0 晶体两种最优取向构成的双能级系统 ,探讨了C6 0 晶体的各种热力学函数在 2 6 0K温度下的表现形式 .着重分析了 87K附近二阶相变两侧热力学函数的变化规律 .根据已报道的C6 0 晶体在有序相两端点温度 87K和 2 6 0K的取向分布实验结果 ,将较高能级分子取向 (38°)的几率转化成分数值 1 6和 3 8.由热力学基本原理 ,得到了两端点温度的 38°取向分子的三维排列结构 ,并对其随温度的转变作了初步的探讨 .