Experimental investigation and thermodynamic assessment of the yttriumhydrogen binary system

A coupled experimental investigation and thermodynamic study of the yttrium-hydrogen(Y-H) binary system were carried out to provide more comprehensive and quantitative insights into the key thermodynamic properties of this system. Y-H system in the full range of H/Y = 0–3.0 was investigated by accurate pressure composition isotherm(PCI) measurement to provide credible phase equilibria information and thermodynamic data.The phase boundaries obtained were in agreement with previous experimental data but with improved accuracy.With the guide of the crystal structures, all the solid phases were modelled using the three sublattice model. The Y-H phase diagram and thermodynamic parameters were calculated and assessed with the CALPHAD technique.The obtained results are in very good agreement with our experimental data and the published data reported in literature. The obtained thermodynamic database of Y-H system can be used to predict the hydrogenation behavior and decomposition temperatures of hydrides.     

微型货车后桥壳的应力校核

主要介绍微型货车后桥板簧断面处的应力计算。     

FAM激光测粒仪

本文讨论了各种衍射式激光测粒仪在理论上的局限性,并设法加以改进和提高,从而发展了综合利用夫琅和弗衍射和米氏散射理论的激光测粒仪(FAM激光测粒仪),经对比性实测表明,其性能较国外的衍射式测粒仪有了明显的提高。     

INVESTIGATION ON A FLOWRATE MEASURING SYSTEM USING LIGHT FIBRE FLUOROMETERS

In this paper a flowrate measurement method in pipe directly using light fibres with some fluorescent tracer is proposed. This method will work better than traditional tracers measurement such as using radioactive or salt tracers. It is shown that the flowrate signals are sensitive and intensive also if the injected tracer volume is very small and if the tracer concentration is very lew (<10ppm) ico. It is also show that the calibration factor K is constant within a certain flowrate range. An estimation of uncertainty of flowrate measurement is given, which shows that the measuring accuracy can be within ±2%.     

茚基轻稀土醋酸衍物生的合成与结构表征

本文合成了八个新的茚基轻稀土醋酸衍生物,它们的通式为Ind_nLn(OOCR)_(3-n)·THF(n=1,2;Ind=C_9H_7;Ln=Nd,Sm;R=-CCl_3,-CMe_3)。元素分析、红外光谱和质谱鉴定,表明这些化合物都是通过羧酸阴离子为桥联基团的二聚或多聚体结构。此外,对它们的空气及热的稳定性进行了比较和讨论。     

激光散射法测定聚合物的分子量

O 原理简介分子量是聚合物的一种重要物理量,它与聚合物的许多重要物理、化学性质有直接关系。由光在聚合物溶液中的丁铎尔(Tyndall)效应,根据光散射原理,德拜(Debye)提出了光散射强度与聚合物分子量有如下关系:     

我国重点保护野生动物等级划分标准的探讨

本文介绍当前国际麦斯——兰地（Mace—Land）对濒危种类的等级划分标准.提出执行国际标准为划分濒危物种等级意见.     

混合配体稀土三元配合物的研究V．吲哚3－丙酸邻菲罗啉稀土三元配合物的合成及性质

本文报道首次合成了１５种稀土三元配合物，经过元素与化学分析，确定配合物组成为：ＬｎＰ３Ｐｈｅｎ（Ｌｎ为稀土离子，Ｐ为吲哚－３－丙酸根，Ｐｈｅｎ为邻菲啉），通过化学分析、红外光谱、热谱、紫外光谱．ＨＮＭＲ谱、荧光光谱．Ｘ射线粉末衍射和Ｘ光光电子能谱等方法对新合成三元配合物的结构及性质进行了研究．     

稀土离子在薄层色谱过程中的行为及展开剂的研究

本文从马丁方程出发对薄层吸附色谱过程中稀土离子的行为机理作了探索,在实验基础上研究五个展开体系对稀土元素 R_M 的影响,论证了展开剂各组分之间的竞争效应,协萃效应及反协萃效应对稀土元素 R_M 世和相邻稀土元素ΔR_M 的影响趋势,同时对如何选择展开剂最佳条件进行了讨论,对目前所用的一些方法作了比较和研究。     

激光角散射式微粒测量装置及其测量结果的单值性讨论

本文讨论了以激光为光源的角散射式微粒测量装置的工作原理及其优点,并在大量分析国内外研制生产的该种测量装置的基础上,指出了在单散射角下对颗粒进行检测时,存在着测量结果出现多值性的可能,文中讨论了解决这一关键技术问题所采取的可能方案和措施。