Atomic-scale computer simulation for early precipitation process of Ni75Al10V15 alloy

The kinetic model for a ternary system is introduced based on the microscopic diffusion form of the phase-field equations for a binary alloy. The equation is solved in the reciprocal space. This model is used to investigate the early precipitation process of Ni75-Al10V15 by simulating the atomic pictures of the two ordered phases and calculating the order parameters of γ′(Ni3Al) phase. Simulation results show that the γ′ ordered phases precipitate from the disordered matrix by a non-classical nucleation mechanism, and the nonstoichiometric γ′ ordered phase appears first and then transforms into the stoichiometric one. Clusters of V atoms appear at the γ′ phase boundaries followed by the formation of the nonstoichiometric θ ordered phase. The farther the location from γ′ phase boundary is, the lower the order degree of θ phase is. There exist two kinds of DO22 ordered domains: a horizontal one and a vertical one, related to their adjacent γ′ phase boundaries. The model could describe the atomic ordering and composition clustering simultaneously, and any a priori assumption about the new phase structure and precipitation mechanism etc. is unnecessary.     

Computer simulation for the precipitation process of Ni75Al7.5V17.5 alloy

The precipitation mechanism of Ni75Al7.5V17.5 alloy above the L12 instability line, between the L12 and D022 instability lines and below the D022 instability line are studied using microscopic phase-field kinetic equation. This paper is aimed at investigating the effect of temperature on precipitation mechanism and morphological evolution of the alloy. Our simulations demonstrate that the precipitation is a mixed mechanism of non-classical nucleation growth and spinodal decomposition above the L12 instability line. It needs certain thermal fluctuations for nucleation and the number of θ phases is small at this temperature. The precipitation mechanism of γ'phase is congruent ordering followed by spinodal decomposition, and θ phase is a mixed mechanism of non-classical nucleation growth and spinodal decomposition between the L12 and D022 instability lines. The mechanism below the D022 instability line is similar to that between the L12 and D022 instability lines. With the decrease of the temperature, ordering and phase separation becomes fast, the dimension of γ'phase becomes small, the shape transforms from equiaxed to block, the dimension of θ phase becomes large and the shape transforms from strip to circle.     

露天矿生产的车辆安排

运用运筹学中的目标规划决策,建立露天矿生产车辆安排问题的一个多目标和一个单目标的数学模型,并运用目标规划模型的思想,将复杂的多目标问题转化为单目标线性规划问题,得出了露天矿生产的车辆安排计划。     

多约束投资组合优化问题的实证研究

为克服经典MV模型假设条件过于苛刻,而已有相关文献在对其进行修正时仅考虑部分投资约束等不足,文章通过考虑现实经济活动中存在的各类投资限制条件,建立了带有多种投资约束的广义MV模型.在说明了如何有效求解所得投资组合问题之后,基于中国证券市场的交易数据对新模型进行了实证研究.结果表明所给模型不仅是合理、有效的,而且可较好地指导投资者选择最优而稳健的投资方案.     

烯烃捕获不饱和卡宾及其反应机理的研究

介绍了一种制备不饱和卡宾的新的方法，即用1，1-二氯代烯烃与金属钠反应，产生的不饱和中间体用烯烃进行捕获．对捕获的产物经IR，GC—MS及^1HNMR等分析鉴定后证实，各产物主要是通过卡宾中间体或类卡宾中间体与烯烃加成反应或重排反应而得到．     

约束非线性l1问题的调节熵函数法

针对约束非线性l1问题不可微的特点,提出了一种光滑函数的近似逼近方法。该方法利用调节熵函数和罚函数技术将约束非线性l1问题转化为无约束可微优化问题,因而可利用光滑优化的经典算法求出原问题的近似最优解。给出了基于光滑优化问题的BFGS迭代,并介绍了约束非线性l1问题的调节熵函数的有关性质、算法的迭代步骤及其收敛性分析。最后通过数值实例表明了该算法的有效性。     

离心叶轮回转S1流面流动数值计算方法探讨

采用贴体坐标下的有限差分法计算了离心泵叶轮回转S1流面流动,并用试验结果进行了验证,发现了流层厚度对流动数值计算有重要影响.     

CDMA 1X数据业务的优化探讨

叙述了CDMA 1X数据业务优化前应解决的问题及数据优化过程，重点探讨了SCH管理与分配的流程，指出通过网络优化可以综合评估网络的潜力，从而能够更合理、更经济地配置和利用资源，为数据用户提供高质量的服务。     

大学英语分级教学之改革与探索

本文结合大学英语教学现状及分级教学的理论依据,提出了大学英语教学改革--分级教学的必要性和科学性,并进一步就分级教学的模式构想进行了探讨,旨在倡导实行分级教学,以提高大学英语教学水平和质量,为大学英语教学跃上一个新台阶提供一种新思路。     

Cpf1 和 Cas9核酸酶靶向EGFR-L858R突变的研究

表皮生长因子受体(EGFR)单核苷酸突变(2573TG,L858R)占所有EGFR突变的90%.使突变的EGFR失活对有此突变的病人非常有利.这里,应用双荧光报告分析的方法分析规律成簇间隔短回文重复(CRISPR)系统中Cpf1和Cas9在靶向EGFR-L858R突变的编辑效率.在EGFR-L858R突变位点的附近,有两个Cpf1前间区序列邻近基序(PAMs)——TTTN.并且,2573TG突变形成了一个Cas9的PAM——NGG.因此本文通过构建两条AsCpf1的gRNAs(gRNA1和gRNA2)和一条SpCas9的gRNA(gRNA3)在体外通过双荧光蛋白分析系统去评估SpCas9和AsCpf1特异性靶向等位基因的能力.结果证实了AsCpf1和SpCas9都能够特异性的编辑突变的EGFR(2573TG).