浅谈地下水中铁、锰质的迁移与富集规律

介绍了地下水中铁锰质的来源,铁锰的主要存在形态及铁锰质的迁移与富集规律,指出地下水中的铁锰质的迁移与富集除受含水介质成份、迳流条件、上覆土层性质、酸碱条件等影响外,主要受氧化还原环境控制。     

毛细管电泳化学发光法用于铁形态的分析

以邻菲咯啉为配位剂,将毛细管电泳与鲁米诺-过氧化氢化学发光体系结合,成功的分离并检测了Fe(II)和Fe(III).在该体系中引入邻菲罗啉有以下优点:(1)有效的防止了Fe(II)被空气氧化的可能性.(2)提高了Fe(II)检测灵敏度.(3)提高了Fe(II)和Fe(III)的分离效率.在pH4.3的醋酸-醋酸钠缓冲溶液中,不到8min的时间即可实现Fe(II)和Fe(III)的分离.此法对Fe(II)检测的线性范围是1nmol/L～200nmol/L,对Fe(III)的线性范围是10nmol/L～330nmol/L,它们的检出限分别是Fe(II)68amol(3.4×10-9mol/L)和Fe(III)460amol(2.3×10-8mol/L).     

Analysis of the matrilineal genetic structure of population in the early Iron Age from Tarim Basin, Xinjiang, China

Ancient mtDNA data of human remains were analyzed from four early Iron Age Tarim Basin sites （Yuansha, Zaghunluq, Sampula and Niya） in the southern Silk Road region. Haplogroup distributions show that ancient Tarim Basin population was comprised of well-differentiated Western and Eastern matrilineal lineages. Some West lineage of Tarim Basin population originated from Near East and Iran region. Of the East lineages, North and Northeast Asia originated lineages were the main components, and a few Southeast Asian lineages also existed, which indicated a more extensive origin and a more complex admixture. The genetic structure of ancient Tarim Basin population is relatively close to the modern populations of Xinjiang, which implied that the early Iron Age is an important period during the formation of the modern Xinjiang population.     

温度对二硫苏糖醇释放马脾铁蛋白铁的影响

用光谱法检测了二硫苏糖醇(DTT)在不同温度下对马脾铁蛋白(HSF)铁核铁的释放过程。在空气(21%O2)、DTT浓度为1.67mmol/L和反应时间为2h条件下,37°C时铁释放量是5°C时的19.43倍,25°C时铁释放量是5°C时的16.91倍,37°C时铁释放量仅是25°C时的1.15倍。这说明HSF分子在不同的温度下其蛋白壳结构发生了柔性改变。这种改变使HSF亲水通道在5°C时变得更为狭窄,从而使DTT进入HSF变得困难。     

助溶酸浸硫铁矿烧渣的研究

采用常压下助溶酸浸的方法对提取硫铁矿烧渣中的铁进行了研究,得到硫铁矿烧渣中铁浸出率的影响因素及规律。结果表明,影响铁浸出率的主要因素为硫酸浓度、反应时间和温度、硫酸用量系数、助溶剂用量及热水用量;当硫酸用量系数为1.05、硫酸浓度为65%-70%、反应温度为125℃、反应时间为3-4 h、助溶剂用量为烧渣量的16%-20%、热水用量为烧渣量的1倍或1.8倍时,铁的浸出率可达95%以上。     

Effects of doping FeCl3 on hydrogen storage properties of Li-N-H system

The effects of doping FeCl_3 on the LiNH_2-2LiH system were investigated systematically. FeCl_3 was prior to react with LiH during ball milling their mixtures. The metallic Fe, which is generated from metathesis reaction between FeCl_3 and LiH, plays an important role on improving the dehydrogenation kinetics of LiNH_2-2LiH system. The results indicated that the dehydrogenation peak and ending temperatures of the doped 1 mol%FeCl_3 sample shifted to low temperatures, and the dehydrogenation active energy changed from 102.45 k J/mol to 87.52 k J/mol. While increasing the amount of FeCl_3, an excess of LiCl, the by-product of metathesis reaction between FeCl_3 and Li H, can stabilize LiNH_2 and thus hinder hydrogen desorption. The dehydrogenation product is a new solid cubic phase solution of lithium imide-chloride. The high limit of the solid solution of LiCl and Li_2NH is near the molar ratio of 1:1.     

燕山地带部分辽代冶铁遗址的初步调查

对燕山地带的河北兴隆蓝旗营冶铁遗址、河北滦平东沟冶铁遗址、河北赤城上仓冶铁遗址进行了田野调查,对采集的炉渣、炉壁、矿石等进行了实验室分析.通过初步研究发现三处冶铁遗址的性质比较接近,主要技术为生铁冶炼和炒铁,证明燕山地带的辽代居民掌握一定的生铁冶炼技术,并掌握了添加石灰石和白云石等作为助熔剂的技术,但综合冶炼技术不成熟.通过对比发现燕山地带辽代冶铁遗址的冶炼技术比较接近,随着遗址所处矿区的不同有一定的差异,初步印证了辽代的统治者对当时冶铁业进行了集中的管理,并且采取就近进行冶炼的作业方法.     

低铬白口铸铁的冲蚀磨损与断裂韧性

通过稀土硅铁合金炉前孕育和热处理工艺改善碳化物形态分布及基体组织的强韧性,从而获得性能较为优越的低铬白口铸铁,对其进行断裂韧性测定和较系统的冲蚀磨损试验.结果表明:孕育处理使碳化物由连续网状分布转变为断续网状分布,同时细化了晶粒,导致断裂韧性K_(IC)的提高;并改善其冲蚀抗力;且表现为磨料越硬效果越显著,说明磨料硬度对低铬白口铸铁冲蚀抗力有显著影响:当磨料为较软的玻璃砂时,冲蚀抗力随材料基体硬度的提高而提高;当磨料为硬的碳化硅时,冲蚀抗力随断裂韧性K_(IC)的提高而提高;当材料硬度相近时,则断裂韧性越高,越耐冲蚀.文中结合冲蚀断口的扫描电镜观察及残留奥氏体转变量的X射线测定对试验结果及冲蚀机理进行了分析讨论.     

STM study on micromorphology of pyrite and dynamic significance of ore-formation

A careful scanning tunneling microscope (STM) observation has been made on the micromorphology structure of the crystal faces for a group of pyrites which include two types of pyrite specimens: natural pyrites, from the different stage of hydrothermal ore deposits and artificial crystal of pyrite. It has been discovered that there is a set of micromorphological structures on the surfaces of pyrite crystals, including pisolitic hillocks, lotus root-like hillocks and spiral steps. This study reveals that the micromorphology of pyrite crystals, which are closely related to thermodynamic conditions and dynamic environment of the ore-forming systems, carries a lot of genetic information.     

对云南雪山铁矿开发地质灾害危险性评估

根据实地调查和已有资料,对云南省禄劝县雪山铁矿开发进行了地质灾害危险性评估,并提出了地质环境、地质灾害防治措施。