Comparison of the carbon isotope composition of total organic carbon and long-chain n-alkanes from surface soils in eastern China and their significance

Surface soil samples collected over a high spatial resolution in eastern China were analyzed for carbon isotope composition(δ 13C) of total organic carbon(TOC) and higher plant-derived long-chain n-alkanes,with the latter reported as weighted mean values.The two sets of δ 13C values are significantly correlated and show similar trends in spatial variation.The spatial distribution of δ 13C shows less negative values in the mid-latitudes between 31°N and 40°N and more negative ones at higher and lower latitudes.This is consistent with previously reported carbon isotope data from surface soil phytoliths in the same region and suggests that the mid-latitude area provides relatively favorable growing conditions for C4 plants.Furthermore,δ 13C values of both TOC and long-chain n-alkanes from 12 surface soil samples collected from a small grassland in north China displayed similar carbon isotope values and the difference between paired δ 13C of a soil samples remains relatively constant.Our data demonstrate that in eastern China,soil δ 13C composition of both TOC and long-chain n-alkanes is effective indicators of C3/C4 ratios of the prevailing vegetation.This work suggests that -22‰ and -32‰ are good estimated end members for the weighted mean δ 13C values of long-chain n-alkanes(C27,C29 and C31 n-alkanes) from soils under dominant C4 or C3 vegetation,allowing us to reconstruct paleovegetation trends.     

Micro-Raman investigations on the structures of the surface and the inner of MgSO_4 droplets

Spherical MgSO4 droplets were deposited by a syringe on the hydrophobic Teflon substrate. Using micro-Raman technique, the laser beam was highly focused twice on the surface and in the center of spherical droplets. The Raman spectra for the surface and the inner of MgSO4 droplets were accord-ingly obtained, suggesting formation of a thin layer of gels on MgSO4 droplets at low relative humidity. The gel layer covered the surface and exhibited a significant delay in response to the change of ambi-ent relative humidity, resulting in the structural difference between the surface and the inner of MgSO4 droplets.     

具有杀虫活性1-(3-甲氧基-4-羟基苯基)-7-(4-羟基苯基)-1，6-庚二烯-3，5-二酮天然化合物的首次全合成

以香草醛和4-羟基苯甲醛为原料,通过汇聚合成的策略,经7步反应首次完成了由姜科植物Etlingera elatior的根茎中分离得到具有杀虫活性天然产物1-(3-甲氧基-4-羟基苯基)-7(4-羟基苯基)-1,6-庚二烯-3, 5-二酮的全合成, 总收率20.8%,合成的关健步骤是α,β-不饱和甲基酮区域选择性酰基化反应.     

Preparation and magnetic properties of CoFe2O4/TiO2 composite films

Using （Ti（OC4H9）4） and metal chlorates as starting materials, CoFe2O4/TiO2 composite films were prepared by sol-gel method. The effects of heat treatment temperature and pH of the precursor on microstructure and magnetic properties were studied. The phase structure of the samples was examined by X-ray diffraction. The microstructure was examined by scanning electron microscope, atomic force microscope and polarized microscope. The magnetic property was measured by vibrating sample magnetometer. The results show that the crystals of different phases grow up independently. CoFe2O4 is uniformly embedded into the TiO2 matrix in the prepared composite films, and the growth of composite films is dependent on the heat treatment temperatures and PH of the precursor. The average size of CoFe2O4 crystal is 19 nm in Nanocomposite film prepared when the heat treatment temperature is 800℃ and the pH of the precursor is between 2 and 3. The magnetism of the composite films is enhanced as the heat treatment temperature increases.     

用共振光散射光谱法测定痕量阳离子表面活性剂的研究

在pH值2.0的B-R缓冲液中,痕量的溴化十六烷基三甲基胺(CTMAB)的加入导致K2HgI4共振光散射强度增加,在λex=λem=422 nm处,得到一个共振散射峰,其强度与CTMAB的浓度成线性关系,据此建立了一种测定水中阳离子表面活性剂的共振光散射光谱法.方法的线性范围为0.02-6.50 mg/L,检出限为0.15 μg/L.该方法简便快速,灵敏度高,对实际样品进行了测定,得到了满意的结果.     

人类HDAC4和MIF4GD蛋白相互作用的初步研究

以HDAC4为“诱饵”,利用酵母双杂交系统筛选人肝cDNA文库得到“猎物”蛋白,通过GST Pull-down,Co-IP,荧光共定位等技术验证HDACA和“猎物”的特异性结合,并通过成人多组织cDNAPanel确定“猎物”的组织表达谱．通过体内、外蛋白结合实验证实了HDACA与MIF4GD（MIF4G domaincontaining）蛋白特异性互作,且两者亚细胞共定位于细胞质内,并确定了MIF4GD在胎盘、肝脏和胰腺中有特异性表达．本实验发现并验证了HDACA与MIF4GD的特异性互作,并确定了MIF4GD的特异性表达谱,为深入研究两种蛋白的功能及其所参与的生理过程提供了新的线索．     

2,3,4,5,6-五氟苯乙烯聚合物刷的制备和表征

用原子转移自由基聚合方法在硅片表面制备了2,3,4,5,6-五氟苯乙烯聚合物刷．利用椭圆偏正光测厚仪、接触角测定仪和X射线光电子能谱仪对薄膜结构进行了表征．     

基于Geant4的多相流CT系统优化设计

针对多相流CT系统,利用基于蒙特卡洛方法的高能粒子输运仿真软件工具包Geant4分析,构建了多相流CT系统5源、7源和9源仿真模型.分析多相流CT系统的数学模型,并利用LBP、FBP以及ART算法进行了图像重建.基于散射光子比和重建图像质量等优化指标分析,进行了多相流CT成像系统的优化设计.实验表明,优化设计后的CT系统使层流、环流和泡状流的散射光子比分别降低到5.32%、5.33%和5.29%,有效抑制了光子散射,明显改善了再构图像质量.     

2,4,6-TNT晶体电子结构的密度泛函理论研究

采用密度泛函理论(DFr)对2,4,6-三硝基甲苯(TNT)晶体的分子结构及电子结构进行了理论研究,探讨了TNT晶体的分子结构以及费米能附近的能带结构和原子的投影态密度(PDOS),并分析了TNT分子间的相互作用以及分子内和分子问的氢键作用.同时还利用Gaussian98程序包对单个TNT分子结构进行了B3P86/6-31g**水平的优化计算,分析了单个TNT分子和晶体中TNT分子的差异.     

Intranet IPV6过渡策略综述

通过对IPv6过渡技术的分析,提出了Intranet IPv6过渡策略,并针对Intranet IPv6过渡原则以及可能出现的各种问题进行了探讨。