西松烯内酯的合成研究——Ⅱ.中间体苏式-7-羟基-3,9,13-三甲基-6-异丙烯基-(2E,8E,12)-十四碳三烯苯硫醚的合成

以香叶醇为原料经过4步反应得到8-溴-3,7-二甲基-(2E,6E)-辛二烯基苯硫醚(7),(7)与(?)牛儿醛在Cr(Ⅱ)作用下立体选择地得到苏式-7-羟基-3,9,13-三甲基-6-异丙烯基-(2E,8E,12)-十四碳三烯苯硫醚.     

1-[5-(3-吡啶)-四唑-2-乙酰基]-4-芳基氨基硫脲及3-[5-(3-吡啶)-四唑-2-亚甲基]-4-芳基-1,2,4-三唑-5-硫酮等化合物的~(13)C-NMR 的研究

本文测定1-[5-(3-吡啶)-四唑-2-乙酰基]-4-芳基氨基硫脲及3-[5-(3-吡啶)-四唑-2-亚甲基]-4-芳基-1,2,4-三唑-5-硫酮等六种化合物的~(13)C-NMR 谱.各种~(13)C-NMR 化学位移,根据取代基效应,讯号强度以及同模型化合物化学位移对照而确认其归属.     

Climate as the dominant control on C<Subscript>3</Subscript> and C<Subscript>4</Subscript> plant abundance in the Loess Plateau: Organic carbon isotope evidence from the last glacial-interglacial loess-soil sequences

Two modes of photosynthesis predominate in terres-REPORTS trial plants: the C3 and C4 modes[1]. The C3 mode is used by all of trees, bushes, and cold season grasses. The C4 mode is used by the most of tropical and warm season grasses. They are disadvantaged relative to C3 plants at high CO2/O2 ratios because of the additional energy ex-pense needed to concentrate CO2 in the bundle-sheath cells. At low CO2/O2, however, C4 plants can achieve a relatively high quantum yield by suppressin…     

Change in the sedimentary environment of Wanquan River Estuary,Hainan Island,China

Pb geochronology and sediment core profiles of organic carbon, total sulfur and organic carbon isotope (d 13C) values were used to reconstruct the local environ-mental history of the Shamei Lagoon, located in the Wan-quan River Estuary, eastern Hainan Island, China. Totalsulfur and d 13C values decreased upwards in the top 30 cm of a sediment core that spanned the last 200 years of deposi-tion. Total sulfur concentration and d 13C values respectively decreased upward from 1.92% to 0.36%, and -20.63?to -23.64? The C/S ratio in the 19th century and earlier was relatively stable in the range of 0.47—0.80, and there was a positive correlation between organic carbon and total sulfur. Since around 1900 AD, the C/S ratio increased rapidly to a maximum of 3.94, but no simple correlation was found be-tween organic carbon and total sulfur during this more re-cent period. These results indicated that before 1800 AD, the lagoon had a fully marine character, and the location of to-day抯 Wanquan River Estuary was an open embayment.From 1800 to 1900, the salinity of Shamei Lagoon decreased noticeably. The amount of seawater which could enter thelagoon decreased gradually as the Yudai spit grew. Today,seawater scarcely affects the lagoon; it is essentially a fresh-water basin.     

IL-1β regulates the mouse Fas ligand expression in corneal endothelial cells

Constitutively expressed Fas ligand (FasL) in several distinct epithelial cell types appears to protect tissues by inducing apoptosis of Fas immune cells during inflammatory reactions. To study the rela-tionship of FasL and inflammation process in cornea,we examined the effects of inflammatory cytokine IL-1β on the FasL production,expression and cytotoxic function in corneal endothelial cells. In this paper,we demonstrate that IL-1β inhibits the FasL production and expression in corneal endothelial cells. The promoter activities of FasL in these cells are reduced by IL-1β in a dose-dependent manner. Finally,we also find that IL-1β block the cytotoxic effects of FasL derived from corneal endothelial cells to the Fas target cells. These data support the view that FasL derived from corneal endothelial cells modulate inflammation within cornea.     

分子内1,3-偶极环加成反应研究(Ⅴ)——N-4-戊烯基硝酮体系环加成区域选择性产物的色谱分析及结构鉴定

利用色谱法、气-质联用技术及碳-13核磁共振,定量地研究了N-4-戊烯基硝酮体系区域选择性产物的结构和含量.实验结果表明气相色谱法是对N-4-戊烯基硝酮环加成产物分析的有效方法.所得结果与1,3-偶极环加成反应的动力学控制、硝酮偶极体系的LUMO轨道控制及过渡态理论相符,它为分子轨道理论在有机合成中的应用研究提供了重要的实验依据.     

基于图像分析的摄像头识别条形码的算法

随着科技的发展和进步,信息采集无处不在,人们对信息采集的成本也要求越来越低,摄像头采集条码是目前采集条码的一种趋势,它由于低成本和携带方便的特点开始受到人们关注,本文介绍了摄像头和PC机相连采集条码的算法,为摄像头识别条码提供了雏形。     

LEP—120工业粘合剂结构的核磁共振研究

通过对ＬＥＰ－１２０型工业粘合剂核磁氢谱和碳谱的综合解析，确定了样品中各种组分的结构和相对含量。并对样品的核磁氢谱和碳谱数据进行了全归属。显示了核磁共振技术在有机和高聚物结构鉴定中重要作用。     

2Cr13钢调质后奥氏体粗晶遗传及其对性能的影响

本文对汽轮机末级叶片钢2Cr13粗晶马氏体在重新加热淬火后的粗晶遗传现象进行了研究,观察了在奥氏体化时恒温形成的动力学和组织结构。讨论了在相变区的加热速度、奥氏体化温度及保温时间对奥氏体晶粒的影响。研究表明,调质后粗晶奥氏体的遗传现象,是由于沿原奥氏体晶界碳化物偏聚析出的结果。还讨论了奥氏体晶粒度对调质后力学性能的影响,扫描及透射电镜观察结果表明,调质后的力学性能,主要取决于钢中碳化物的分布及尺寸。