基于粘结强度特征数的烧结矿强度评价方法

烧结矿的强度主要取决于含铁矿物的强度、粘结相自身的强度以及粘结相与含铁矿物间的粘结强度。研究表明粘结相与含铁矿物间的粘结强度是烧结矿强度的主要制约因素。将粘结强度与能满足工厂生产要求标准的烧结矿粘结强度(12.58 MPa)的比值定义为粘结强度特征数,并用其评价烧结矿的整体强度。同时,结合烧结矿的微观结构对烧结矿强度进行研究。结果表明,与粘结相自身微观结构相比,粘结相与含铁矿物界面的微观结构较为疏松;固液两相之间的冷收缩系数不同,粘结相与含铁矿物之间易形成内应力,不利于粘结强度的提高。因此,粘结强度满足一定要求时,烧结矿的强度就能满足生产要求。     

Experimental investigation and thermodynamic assessment of the yttriumhydrogen binary system

A coupled experimental investigation and thermodynamic study of the yttrium-hydrogen(Y-H) binary system were carried out to provide more comprehensive and quantitative insights into the key thermodynamic properties of this system. Y-H system in the full range of H/Y = 0–3.0 was investigated by accurate pressure composition isotherm(PCI) measurement to provide credible phase equilibria information and thermodynamic data.The phase boundaries obtained were in agreement with previous experimental data but with improved accuracy.With the guide of the crystal structures, all the solid phases were modelled using the three sublattice model. The Y-H phase diagram and thermodynamic parameters were calculated and assessed with the CALPHAD technique.The obtained results are in very good agreement with our experimental data and the published data reported in literature. The obtained thermodynamic database of Y-H system can be used to predict the hydrogenation behavior and decomposition temperatures of hydrides.     

Study on the hydrogen storage property of (TiZr0.1)xCr1.7-yFeyMn0.3 (1.05

Jigang Li  Li Xu  Xiaojing Jiang  Xingguo Li 《自然科学进展(英文版)》2018,28(4):470-477

城市污水处理厂硫化氢恶臭气体的发生及源控制

城市污水处理厂散发的硫化氢,臭阅低,可与不饱和酮反应生成其它恶臭物质,不仅严重影响周围居民的生活质量,还会腐蚀污水厂的混凝土和金属构筑物,降低处理效率,并且对污水处理厂的工作人员具有毒害作用。随着公众环保意识的提高,控制与消除城市污水处理厂硫化氢的恶臭污染已成为各国环保科研人员的研究热点之一。控制污水处理厂恶臭污染的传统方法是末端治理,即在硫化氢生成之后进行消除,与末端治理相比,预防性控制法最突出的优点在于防患于未然,抑制硫化氢生成,从源头上解决了污水处理厂硫化氢的污染问题。本文重点介绍了预防生化硫化氢生成的措施,最后提出了一些尚待解决的问题,展望了未来技术的发展方向。     

利用含硫化氢尾气一步法合成脒基硫脲的研究

采用硫化氢尾气和双氰胺直接反应,一步合成脒基硫脲。考察了温度,时间等对反应的影响。反应温度80℃-82℃,反应时间1．5h,产率可达90％。     

Current Research Progress in Magnesium Borohydride for Hydrogen Storage (A review)

Hydrogen storage in solid-state materials is believed to be a most promising hydrogen-storage technology for high efficiency, low risk and low cost. Mg(BH₄)₂ is regarded as one of most potential materials in hydrogen storage areas in view of its high hydrogen capacities(14.9 wt% and 145–147 kg cm^-3). However, the drawbacks of Mg(BH₄)₂ including high desorption temperatures(about 250°C–580°C), sluggish kinetics, and poor reversibility make it...     

Synergetic effect of multiple phases on hydrogen desorption kinetics and cycle durability in ball milled MgH2–PrF3–Al–Ni composite

A new Mg MgH₂–PrF₃–Al–Ni composite was prepared by ball milling under hydrogen atmosphere. After initial dehydrogenation and rehydrogenation, Pr₃Al₁₁, MgF₂, PrH₃ and Mg₂NiH₄ nanoparticles formed accompanying the main phase MgH₂. The hydrogen absorption-desorption properties were measured by using a Sieverts-type apparatus. The results showed that the Mg MgH₂–PrF₃–Al–Ni composi...     

SUS441不锈钢/Al金属间化合物微叠层复合板的界面结构与力学性能

采用“表面预处理—交替层叠—热轧复合—热处理”的工艺流程制备了SUS441不锈钢/Al金属间化合物微叠层复合板。利用光学显微镜、X射线衍射仪、扫描电子显微镜等检测与表征方法研究了热处理温度对复合板界面形貌、微观组织、物相组成、维氏硬度、拉伸性能的影响。结果表明：复合板界面结合良好;热处理后,固–液反应界面氧化严重,易导致界面分层而开裂;固–固、固–半固、固–液热处理后,金属间化合物层由均匀层和两相层组成,均匀层的物相组成为Fe₂A1₅,两相层的物相组成为Fe₄Al₁₃和Al₁₃Cr₂,且两相层具有韧性特征,固–半固反应所得到的复合板的综合力学性能最佳。     

提高纤维编织网与砂浆粘结性能的实用方法

纤维编织网增强混凝土结构(简称TRC)的力学性能与纤维编织网和基体之间的粘结状况密切相关.采用环氧树脂浸渍纤维编织网并在其表面粘砂的方法来提高粘结强度,控制砂浆基体的开裂.通过四点弯曲试验和拉拔试验考察了不同粘砂粒径对TRC粘结性能的影响.试验结果表明,采用环氧树脂浸渍纤维编织网并在其表面粘砂的方法能够提高纤维编织网与基体之间的摩擦力,甚至产生咬合效应.因此可明显提高TRC的弯曲开裂荷载,增加裂缝数量,改善纤维编织网与砂浆之间的粘结性能.其中粘砂粒径为0.15～0.30 mm改善效果最为显著.     

氢等离子体特性及其对钨的辐照行为研究

本文依托四川大学直线等离子体装置(SCU-PSI)产生高通量氢等离子体,采用朗缪尔探针对氢等离子体特性进行诊断,研究了氢等离子体特性随放电电流、气体流量等输入条件的演变规律;并利用调控产生的氢等离子体对纯钨进行了相应的辐照研究. 实验结果显示, 在磁场0.1~0.2 T、气流量1 000~2 200 sccm和电流180~228 A范围内,氢等离子体通量密度、热负荷密度及电子密度、温度等参数与磁场和电流呈正相关关系,而与气体流量呈负相关关系. 在该范围内,最高等离子体密度达到2.6×1019 m-3,等离子体通量达到8.8×1022 m-2?s-1,热负荷达到6.5×104 W/m2. 利用调控产生的等离子体对纯钨样品进行初步辐照实验,结果显示随着入射等离子体特性的不同,样品表面出现不同程度的尺寸和密度不均匀颗粒状辐照损伤结构,并且颗粒尺寸随氢等离子体离子通量的增加而增大. 本文结果显示SCU-PSI可以产生理想的氢等离子体环境,因此可以作为未来聚变领域,研究氢等离子体和托卡马克装置面向等离子体材料钨以及相应结构材料相互作用的有效实验装置.