水合鸢尾异黄酮磺化物[K（H2O）]（C17H13O6SO3）的合成及晶体结构

目的 合成一种新的水溶性水合鸢尾异黄酮磺化衍生物[K(H2O)](C17H13O6SO3),并确定其分子结构.方法 在60 ℃条件下用浓H2SO4磺化30 min,得到尼泊尔鸢尾异黄酮磺化物,并用体积比为 1/1 的乙醇-水溶液培养单晶,采用X-射线四圆衍射、IR和元素分析等方法表征其结构.结果 和结论将尼泊尔鸢尾异黄酮在60 ℃用浓硫酸磺化,高选择性地在底物B环的3′位引入一个磺酸基,合成了水溶性尼泊尔鸢尾异黄酮衍生物,产率为82%.该合成方法简单,反应条件温和,选择性高,产物容易分离,且产率较高,是合成标题化合物一种理想的方法.X-射线晶体结构表明该化合物属于单斜晶系,空间群P21m,晶胞参数a=0.835(4) nm,b=0.728(3) nm,c=3.000(14) nm,β = 96.09(7)°,V=1.814(15) nm3,Dc=1.650 g·cm-3,Z=4.在化合物的晶体结构中, 相邻的钾离子之间被O6,O7和O8桥链形成聚八面钾离子链.此外,化合物中还存在多个氢键,这使化合物自组装成一个三维网格结构的超分子.     

溶胶-凝胶法制备(Bi, Nd)4Ti3O12铁电薄膜

采用溶胶凝胶法在Pt/Ti/SiO2/Si基片上制备了(Bi, Nd)4Ti3O12铁电薄膜.将薄膜分别进行每一层、每二层、每三层500 ℃空气中预退火10 min，分别称为样品a、b、c，最后都于氮气氛中680℃总退火半小时. 结果表明预退火工艺对薄膜的铁电性能影响很大.样品a、b的铁电性能(2Pr分别为47.8 μC/cm2和51.9 μC/cm2)远远高于样品c(2Pr = 28.7 μC/cm2).三组薄膜都呈现良好的抗疲劳特性.     

一类时滞中立型系统的无记忆反馈H_∞控制

本文采用Lyapunov函数和LMI不等式方法,研究了一类输出方程亦带有不确定性的中立型时滞系统在控制律的作用下鲁棒H∞控制问题.     

盐酸介质中黄铜缓蚀剂H612缓蚀性能研究

采用失重法研究了不同温度下不同质量浓度的H612在10%的盐酸介质中对黄铜的缓蚀作用.结果表明,H612在10%的盐酸介质中对黄铜的腐蚀有良好的抑制作用.采用失重法和SEM分析法评价H612的缓蚀性能,H612是一种性能优良的盐酸黄铜缓蚀剂.     

水热法制备Co3O4及其超电容性能的研究

以硝酸钴为原料、尿素为沉淀剂、柠檬酸三纳为模板,用水热法制备了Co3O4,并采用循环伏安、恒流充放电等方法研究了样品的电化学性能.结果表明,Co3O4电极在6mol·L-1KOH溶液中、在0～0.4V电位范围内、电流密度为5mA·cm2时,单电级比电容可达900F·g-1.     

Receding horizon H∞ control for discrete-time Markovian jump linear systems

Receding horizon H∞ control scheme which can deal with both the H∞ disturbance attenuation and mean square stability is proposed for a class of discrete-time Markovian jump linear systems when minimizing a given quadratic performance criteria. First, a control law is established for jump systems based on pontryagin’s minimum principle and it can be constructed through numerical solution of iterative equations. The aim of this control strategy is to obtain an optimal control which can minimize the cost function under the worst disturbance at every sampling time. Due to the difficulty of the assurance of stability, then the above mentioned approach is improved by determining terminal weighting matrix which satisfies cost monotonicity condition. The control move which is calculated by using this type of terminal weighting matrix as boundary condition naturally guarantees the mean square stability of the closed-loop system. A sufficient condition for the existence of the terminal weighting matrix is presented in linear matrix inequality (LMI) form which can be solved efficiently by available software toolbox. Finally, a numerical example is given to illustrate the feasibility and effectiveness of the proposed method.     

利用蛋白质组学技术筛选与BIV基质蛋白MA相互作用蛋白

牛免疫缺陷病毒BIV的基质蛋白MA是由gag基因编码病毒结构蛋白之一,参与病毒运输包装等多种过程.通过蛋白质组学方法,寻找与MA有相互作用的宿主蛋白.通过原核表达MA-CBP融合蛋白,将其结合在几丁质上,并与细胞裂解物混合,纯化特异结合的细胞蛋白.利用双向电泳以及MALDI-TOF质谱分析,筛选到8个与MA具有相互作用的候选蛋白,功能涉及运输、氧化还原、热激反应等.进而克隆所鉴定蛋白之一的PRDX4,利用体外结合实验进一步证实其与BIV MA蛋白存在相互作用.初步建立利用蛋白质组学技术研究病毒与宿主相互作用实验方法,所得结果为了解慢病毒结构蛋白在病毒生活周期中功能提供了线索,有助于探索过氧化物酶家族蛋白在病毒感染过程中的作用及其分子机制.     

三氮唑羧酸酯类席夫碱的合成及生物活性

从５－氨基－１Ｈ－１，２，４－三氮唑－３－羧酸出发，合成了７种５－氨基－１Ｈ－１，２，４－三氮唑－３－羧酸甲酯类席夫碱，对其产率，物理性持作了首次报道，采用ＵＶ，ＩＲ，＾１ＨＮＭＲ和元素分析等对化合物结构进行了初步表征，实验室生物活性测试表明此类化合物具有较好的生物活性。     

H_∞ Control of a 5th- order Model of Synchronous Generators

1　IntroductionThe control of synchronous generators is one of the most important and widely studiedproblem in the area of power systems control.Such a problem is a non-trivial one,mainlybecause of the highly nonlinear behaviour of synchronous machines.As a matter of fact,their dynamic dramatically changes when passing from a working condition to another.Asa consequence,standard PID-based controllers can not guarantee high performances overthe entire working range.Among the various control a…