Effect of thermo-mechanical treatment on Ti–Ta-Hf high temperature shape memory alloy

The microstructure, martensitic transformation and mechanical/functional properties of Ti–Ta-Hf alloys with various thermo-mechanical treatments were investigated. The results reveal that the hot-rolling could refine the grain size and introduce a certain number of defects, resulting in the disappearance of martensitic transformation. The as-casted and solution treated Ti–Ta-Hf alloys were composed of α'' martensite phase and smaller volume of β phase. In contrast, the grain size of solution treated Ti–Ta-Hf alloy was slightly less than that of as-casted Ti–Ta-Hf alloy. This should be responsible to the higher yield stress and superior strain recovery characteristics for solution treated Ti–Ta-Hf alloy. The yield stress for the dislocation slip and the maximum recoverable strain of solution treated Ti–Ta-Hf alloy were 723 ​MPa and 5.06%, respectively.     

Improving the photocatalytic activity of graphitic carbon nitride by thermal treatment in a high-pressure hydrogen atmosphere

Extending visible light absorption range and suppressing the recombination of photogenerated charge carriers are always important topics in developing efficient solar-driven photocatalysts. In this study, the thermal treatment process at 400 °C in a high-pressure hydrogen atmosphere was applied to modify graphitic carbon nitride. Compared to the normal atmospheric hydrogen treatment process, this process has the merit of producing nitrogen deficient graphitic carbon nitride in high-yield. The optimal photocatalytic activity of modified graphitic carbon nitride was demonstrated by controlling the treatment duration in the hydrogen atmosphere.The changes in the crystal structure, microstructure and optical properties of carbon nitrides were investigated by several characterizations. The relationship between the photocatalytic activity and structures of graphitic carbon nitride was preliminarily established. The results obtained in this study could provide some new ways of improving the activity of graphitic carbon nitride based photocatalyst.     

平台水平移动对高空平台通信系统性能的影响

基于飞艇或飞行器的高空平台(HAP)通信系统面临的一个主要的挑战是平台位置保持。平台保持准静止位置的代价较大。因而,通常建议平台保持在一个位置圆柱内。本文推导终端采用固定指向天线时平台水平最大偏移距离计算公式,并分析有限和无限呼叫持续时间条件下覆盖区蜂窝内呼叫的切换概率。研究表明,平台最大水平偏移距离随着终端波束带宽的增大而增加;相同的波束带宽条件下,平台高度越低,要求的最大偏移距离越小。此外,当最大偏移距离较小时,平台的水平移动只在蜂窝边界附近区域产生切换,且越靠近边界呼叫切换概率越大。蜂窝内平均呼叫切换概率随着平台最大偏移距离的增加而增大;呼叫持续时间内平台移动距离越大,蜂窝内平均呼叫切换概率越大。当呼叫持续时间或平台速度趋于无穷大时,切换概率达到最大值。     

HDSL技术分析及应用

在分析ＨＤＳＬ原理和性能的基础上,对其ＣＡＰ（无载波调幅／调相）与２Ｂ１Ｑ编码进行了分析比较,并结合实例给出了ＨＤＳＬ技术的实际应用。     

完善高职院校社会服务功能促进实践教学水平提升的策略研究

开展有高职院校特色的社会服务是社会发展的客观要求,也是高职高专院校的社会责任,构建多功能社会服务平台是促进校企合作,促进学校实践教学水平提升的有效途径。高职教育要注重社会服务功能的实现,并应发挥高职高专院校的特点和优势,分清主次,摸清高职教育社会服务功能实现发展途径、手段与趋势,把握高职教育社会服务功能实现的机遇,全面提高教育教学水平,使高职教育在区域经济发展中起到示范与促进作用。     

Synthesis of Ta C and Ta_2C from tantalum and graphite in the laser-heated diamond anvil cell

The pressure dependence of the onset of the formation of Ta C and Ta2 C from the elements has been investigated by in situ X-ray diffraction and pyrometry.Ta C has been synthesized by the reaction of Ta and graphite at pressures between 8.6 and 14.3 GPa and at temperatures up to 2,300 K using a laser-heated diamond anvil cell. The products were characterized by X-ray diffraction. Ta and graphite begin to react around 1,100 K at ambient pressure conditions, and the reaction temperature increases with increasing pressure. A linear extrapolation of these data is consistent with recent observations of the formation of Ta C at 90 GPa and 3,600 K. We show that diffusion of carbon into tantalum significantly changes the lattice parameter of up to 2 % in the pressure range of up to19 GPa. In some experiments, Ta2 C was formed concomitantly. The experimentally determined bulk modulus of Ta2 C is B0;exp：= 286（5） GPa. Other tantalum carbide phases were not observed.     

Structural phase transition and metallization in compressed SrC_2

The structural, dynamical, and electronic properties of compressed Sr C2 were systematically investigated up to 200 GPa by using ab initio method. Three new phases are obtained by means of evolutionary algorithm. The confirmed most stable structure has C2/c symmetry at zero pressure, which transforms into an orthorhombic Cmcm phase at 4.5 GPa, followed by another orthorhombic Immm phase, which is stabilized at wide pressure range of 21.5–123.5 GPa, and then transformed into Mg B2-type phase（space group, P6/mmm）. Although Sr C2 has similar structural transformation to that of compressed Ca C2, Sr C2 holds small electron–phonon coupling,which leads to its low superconducting critical temperature（only 1.8 K）.     

Compression behavior of Sm）2Ti2O7-pyrochlore up to 50 GPa：single-crystal X-ray diffraction and density functional theory calculations

Single-crystal X-ray diffraction at pressures up to 50 GPa has been employed to study the compression behavior of Sm2Ti2O7-pyrochlore. In contrast to earlier reports, we observed no pressure-induced amorphization or pressure-induced anion disorder up to 50 GPa. The experimental study has been complemented by density functional theory-based calculations. A combination of the theoretical and experimental data yields a bulk modulus of 185 GPa, significantly higher than a value which had been reported earlier. In comparison to earlier work, the current study provides more reliable data due to the use of neon as a pressure medium, which provides a more hydrostatic pressure than the aluminum, which had been employed as a pressure medium in the earlier studies. An analysis of the compressibility of Al2B2O7 pyrochlores shows an approximately linear dependence of the bulk modulus on the unit cell volume.     

Retrieval of column-averaged volume mixing ratio of CO2 with ground-based high spectral resolution solar absorption

The total column-averaged volume mixing ratio of atmospheric carbon dioxide （Xco2） has been retrieved with high spectral resolution solar absorption data obtained from ground-based Fourier transform spectrometer （FTS） measurements at Xichong, a coastal site in the district of Shenzhen in southern China. Based on differential optical absorption spectroscopy （DOAS） theory, the Xco2 was retrieved by finding the best match of observed high spectral resolution solar absorption data and monochromatic radia- tion transfer model calculations. The averaged Xco2 in the whole observation period was about 394.9 ppm. The uncertainty of the retrieval was estimated to be 2.0 ppm （0.51%） by comparing retrievals at two bands. The preliminary results show that Xc% retrieved by this method can be used to validate satellite remote sensing of Xco2.     

高效液相色谱同时测定何首乌中大黄酸、大黄素和大黄酚的含量

采用高效液相色谱法建立了同时测定何首乌中大黄酸、大黄素、大黄酚三种蒽醌类化合物的方法,样品采用超声波法提取,色谱柱为Phenomenex C18(250mm×4.6mm,5μm);流动相为甲醇-0.4%醋酸水溶液(80∶20);流速0.80mL/min;紫外检测波长254nm;柱温为35℃.结果:该方法对大黄酸、大黄素和大黄酚分别在0.0001~12.50μg/mL、0.0002~25.00μg/mL、0.00018~22.50μg/mL范围内线性关系良好,相关系数(r)均大于0.9999,定性检测限(S/N=3)依次是:0.0703ng/mL、0.0282ng/mL、0.0871ng/mL;样品回收率为88.39%~107.2%.结论:本法操作简单快速、定量准确、灵敏度高、成本低,为何首乌中蒽醌类化合物的检测分离及含量测定提供了一个有效的科学方法.