SnP2S6半导体层数依赖的压电效应

二维压电材料在能源、电子和光电子学方面的应用引起了越来越多的关注.从实验合成的压电晶体SnP₂S₆出发，我们系统研究了单层、双层、三层和块体SnP₂S₆的压电效应.第一性原理计算表明：层状SnP₂S₆具有良好的热力学和动力稳定性，其带隙和载流子有效质量与层数无关，而压电性质具有明显的层数依赖性；单层SnP₂S₆的压电系数(d₁₁)高达14.18 pm/V,远大于MoS₂、h-BN和InSe的压电系数，双层SnP₂S₆的面外压电系数(d₃₃)大于12 pm/V.优异的压电性能使SnP₂S₆在二维压电传感器和纳米发电机等器件中的应用成为可能.     

A hint from phosphine complex: The π back-bonding in cobalt-phosphorene composite enables enhanced electrocatalytic performance

Regulating the electronic structure of the metal electrocatalyst is fundamental for its performance optimizing. The electronic states of the active metal centers are highly dependent on their coordination environment, especially when bonding is formed. The π back-bonding can induce great electron density redistribution around metals, yet it is barely applied in electrocatalyst design. Herein we electrodeposited metallic cobalt on black phosphorus(BP)nanosheets, forming BP-Co with a unique π back...