岭澳核电站二期给水管道流动加速腐蚀的控制与改进

在1986年瑟利（SURRY）电站发生了严重的管道泄漏导致人员伤亡的事故引起了广泛的关注之后,关于对汽机管道中流动加速腐蚀的研究得到了长足地进展。本文以参考了国内外对该现象进行研究的各方资料,介绍了核电站二回路给水管道系统中发生流动加速腐蚀的机理,以及在岭澳核电站二期工程建设过程中,为了控制管道的流动加速腐蚀,如何从就尽量减轻该现象所采取的相关措施。     

海洋结构用钢的临界腐蚀疲劳试验研究

本文对两种新的高强度低合金钢在不同介质,阴极保护点位和载荷频率下的亚临界腐蚀疲劳特性进行了实验研究。实验得出了上述各因素对腐蚀疲劳裂纹扩展速率的影响结果,并对各因素影响裂纹扩展速率的原因进行了分析。     

肇州油田油井结垢及其机理研究

结垢是油田注水生产过程中普遍存在的问题,可以发生在地层和井筒的各个部位.结垢不仅对产层造成伤害、降低原油采收率,还导致原油成本上升.针对油井结垢严重这一问题,实验选择大庆肇州油田州40-38垢样及水样,对垢样进行成分分析,对水样进行离子组成分析,并根据分析结果,提出结垢机理.结果表明:该油井采油设备被严重腐蚀,所结垢的成分主要是由Si、Al化合物组成的矿物质垢和铁垢.     

阴极保护在中原油田的应用

对罐内采用牺牲阳极进行阴极保护,对站内罐底板采用强制电流进行阴极保护,对站内埋地钢质管线采用防腐涂层和牺牲阳极的联合保护。     

Two distinct roles of Al2Sm and Al11Sm3 phases on the corrosion behavior of the magnesium alloy Mg-5Sm-xAl

The roles of Al₁₁Sm₃ and Al₂Sm phases on microstructure evolution, mechanical properties and corrosion behavior of the Mg-5Sm-xAl system was investigated. The results showed that adding Al to Mg–5Sm binary alloy brought two Al–Sm phases, Al₁₁Sm₃ and Al₂Sm, which had two distinct roles regarding the microstructure evolution, mechanical properties and corrosion behavior of the Mg-Sm-Al alloy. Al₁₁Sm₃ produced a strong galvanic couple with the Mg matrix, and significantly accelerated the corrosion. The Al₂Sm particles promoted heterogeneous nucleation and refined the grains, which increased the tensile strength and ductility. Both types of Al–Sm particles provided strengthening effect for the alloy. With higher Al contents, Al₂Sm formed an Al oxide protective surface layer and increased corrosion resistance.     

Anti-corrosion performance of waterborne Zn-rich coating with modified silicon-based vehicle and lamellar Zn (Al) pigments

In order to develop the eco-friendly Zn-rich coatings with higher corrosion resistance and lower pigment contents, several series of coatings were designed and manufactured employing lamellar Zn (Al) pigments mixed with silicone-acrylate emulsion modified inorganic silicate vehicle, and then were evaluated by conventional methods and the electrochemical method. The results indicated that the pigment contents reduced to approximate 25 mass% with lamellar Zn or (Zn and Al) pigments as substitute for spherical Zn pigments, and pigment mixtures were homogeneously dispersed due to silicone-acrylate emulsion moistening modification. Furthermore, the optimal coating had good coating properties (adhesion grade: one), acid resistance (lower mass losses) and anti-corrosive performance (improved corrosion potential and anodic passivation). The experimental results indicated that the modified lamellar Zn (Al) coating was suitable for large-scale spread and application on protecting steel structures in the hostile environment.     

双咪唑啉季铵盐缓蚀剂的合成及性能研究

将月桂酸、二乙烯三胺、碳酸二甲酯等作为原料合成一种双子咪唑啉季铵盐类化合物,并在3.5%Na Cl溶液中通过静态失重法测定该缓蚀剂对马口铁片的缓蚀能力,考察了缓蚀剂浓度、温度等因素对其缓蚀性能的影响。通过Tafel曲线和交流阻抗的测定,对其缓蚀性能进行进一步考察。结果表明双子咪唑啉缓蚀剂在3.5%NaCl溶液的腐蚀环境中对马口铁片具有好的缓蚀效果。当温度T为30℃,缓蚀剂浓度为50 mg/L时,其缓蚀率最大可到91.25%。Tafel曲线表明缓蚀剂浓度增加,其腐蚀电位会向正电位方向移动,且自腐蚀电流密度也在很大程度上随之降低,缓蚀率在增加。从交流阻抗谱的阻值半径可知当缓蚀剂浓度为50 mg/L时得到的阻抗谱半径最大,说明在这一浓度下,腐蚀速率最小,缓蚀效果最优。     

地沟油制备咪唑啉缓蚀剂及缓蚀性能研究

以地沟油,二乙烯三胺为原料,经过酰胺化,环化反应合成油溶性烷基咪唑啉缓蚀剂,利用傅里叶红外光谱对其结构进行表征,测定反应过程中的胺值,通过失重法考察其缓蚀性能。结果表明,缓蚀剂合成过程中反应温度140℃,时间2h,物料配比1:1.2时,反应产物的收率达到71.57%。缓蚀剂在添加量为70mg/L,测试温度为40℃,转速为30r/min及时间为8h的情况下,可以达到最佳的缓蚀效果,其缓蚀率最高可以达到98.47%。远超过市场一般类型的缓蚀剂。     

Corrosion behavior of Mg-Y alloy in NaCl aqueous solution

The corrosion behavior of Mg-(0.25,2.5,5.8 and 15)Y alloys in 3.5wt.％ NaCl aqueous solution was investigated.It was found that the degree of corrosion deterioration increased with increasing immersion ...     

激光熔覆在海洋工程上的应用现状

介绍了激光熔覆技术的原理与特点，重点综述了激光熔覆技术在海洋工程上的研究与应用现状，指出了激光熔覆技术在海洋工程上实际应用存在的问题。