团簇Co3FeP光谱的预测分析

为了对团簇Co₃FeP的光谱进行预测分析,采用密度泛函理论在B3LYP/def2-tzvp的量化水平下,对团簇Co₃FeP进行理论研究,获得4种优化构型.从红外光谱图、拉曼光谱图、偶极矩和极化率4个方面对其结构及相关规律进行了深入研究和预测,得出如下研究结论:所有构型均为C₁对称,构型1⁽³⁾的能量最低; 构型的拉曼活性和红外活性均受其自旋多重度和几何形态的影响; 构型1⁽¹⁾和2⁽¹⁾在红外光谱图和拉曼光谱图中的分布趋势相似; 相比于单重态构型而言,构型1⁽³⁾在红外光谱图和拉曼光谱图中的最高峰和次高峰分别发生了蓝移和红移.     

废锂电池中钴锂浸出率影响因素的全因子实验

为了最大化浸出废锂电池中钴锂金属元素,固定浸出时间,采用全因子实验方法,以氨基磺酸浓度、过氧化氢质量分数、固液比、浸出温度为自变量,Co2+和Li+浸出率为因变量进行模型拟合,应用Minitab 17软件对工艺参数模型进行预测,并对最佳工艺参数进行验证。结果表明,主效应上,氨基磺酸浓度、过氧化氢质量分数、固液比、浸出温度对Co2+和Li+浸出率有显著的影响;交互效应上,氨基磺酸浓度+固液比、过氧化氢质量分数+浸出温度对Co2+浸出率有明显的影响,氨基磺酸浓度+浸出温度、过氧化氢质量分数+浸出温度、固液比+浸出温度对Li+浸出率有一定影响,其余效应影响不显著。所得最佳工艺参数为:c(NH2SO3H)=144 mol·L-1,w(H2O2)=10%,S/L=25 g·L-1,θ=55 ℃,t=70 min,在此浸出条件下,Co2+和Li+浸出率分别为9531%和9236%。     

熔融盐法合成球形锂离子电池正极材料LiNi_(0.8)Co_(0.2)O_2

采用热分析法对不同组成的LiOH-LiNO3二元体系进行研究,绘制了具有最低共熔点的该二元体系T-x相图,该体系的最低共熔点为175.7℃.利用低共熔混合物LiNO3-LiOH为锂盐,与前驱体球形Ni0.8Co0.2(OH)2混合烧结制备出了球形锂离子电池正极材料LiNi0.8Co0.2O2.探讨了Li/(Ni+Co)摩尔比、合成温度、合成时间等因素对产品的影响.X射线衍射分析表明合成的材料具有规整的层状NaFeO2结构,SEM表明所得材料为球形.充放电测试表明在3.0~4.3的电压范围内,首次放电比容量可达170 mAh.g-1,充放电效率为95.5%.结果表明采用该工艺可以制备出电化学性能良好的LiNi0.8Co0.2O2正极材料.     

柠檬酸钠络合剂对有机溶胶法制备钴纳米粒子的影响

首次采用甲酸钠为还原剂、乙二醇为溶剂、柠檬酸钠为络合剂的有机溶胶法制得了粒径为2nm的单分散钴纳米粒子.考查了柠檬酸钠的添加对钴纳米粒子的粒径大小、尺寸分布、收率以及晶型的影响.当柠檬酸钠和氯化钴的摩尔比从0增至6时,钴纳米粒子的平均粒径从200nm降至2nm.同时,柠檬酸钠对钴纳米粒子的尺寸分布也有很好的控制作用,没有使用柠檬酸钠时所得钴纳米粒子尺寸分布很广,从数10nm到300-400nm, 而使用一定量柠檬酸钠后,所得钴纳米粒子粒径在2±0.25nm范围内. 实验也发现使用柠檬酸钠作络合剂会降低纳米粒子的收率.     

富硒鸡腿菇菌丝体深层发酵培养基的优化

研究营养因子对鸡腿菇菌丝体生长和富硒的影响,筛选到适合鸡腿菇富硒深层发酵的优化培养基配方为:葡萄糖2%,玉米粉4%,花生粕0.4%,KH2PO4 0.2%,MgSO4·7H2O0.1%,VB1 10×10-3 g/L,Na2SeO3 4.4×10-3 g/L.在此优化培养基的基础上进行5 d的摇瓶发酵培养,得到菌丝体生物量为18.14 g/L,富硒率为56.35%.     

板模型中带周期边界条件的迁移算子的谱分布

在Lp(1≤p∞)空间中,首先利用线性算子理论讨论了一类带周期边界条件下非均匀介质的迁移方程,其次采用半群等方法证明了迁移算子AH产生C0半群,证明了该半群产生的二阶余项的紧和弱紧性,最后得到了该迁移算子在区域Γ中仅由有限个具有限代数重数的离散本征值所组成。     

Strain-induced modulation of magnetic anisotropy in Co/BaTiO_3 composite

A uniaxial magnetic anisotropy Co film was grown on a single-crystal Ba Ti O3（BTO） substrate. The strain yielded by the voltage-induced ferroelastic domain switching in the BTO substrate was recorded by atomic force microscope and modulated the magnetism of the Co film. The manipulation of the magnetism of the Co film is experimentally demonstrated by voltage dependence of magnetic hysteresis loops measured via magneto-optic Kerr effect.     

Pollen-inferred Holocene vegetation and climate histories in Taro Co,southwestern Tibetan Plateau

A 310-cm-long sediment core, covering the last 10,200 years, was collected from Taro Co on the south- western Tibetan Plateau and analyzed for pollen, grain size and total inorganic carbon content. The pollen data showed that vegetation changed from alpine steppe to alpine meadow during 10,200-8,900 cal a BP, to alpine steppe dominated by Artemisia during 8,900-7,400 cal a BP, to alpine meadow during 7,400-3,300 cal a BP and to alpine steppe after 3,300 cal a BP. Correspondingly, the pollen, grain size and total inorganic carbon content results revealed climatic change in this area over four stages. The initial stage was from 10,200 to 8,900 cal a BP, during which the climate changed from cold-dry to warm-humid. The second stage （8,900-7,400 cal a BP） was characterized by a warm and dry climate. However, at approximately 7,400 cal a BP, the climate began to become cold andhumid, which continued until 3,300 cal a BP. The last stage, from 3,300 cal a BP to present, was characterized as cold and increasingly arid. Climatic events of the early and mid-late Holocene showed that the area was significantly affected by the westerlies. However, the mid-Holocene climate in Taro Co was controlled by the Indian monsoon. The mid-late Holocene depositional environment record of Taro Co was very important to further elaborate the degree of influence by the westerlies or Indian monsoon.     

孢薪菇漆酶的提取及其理化性质

从孢薪菇（Coprinus coimtav）、金针菇（Flammulina velutipes）、平菇（Pleurotus sapidus）、茶薪菇（Agrocybe cylindracea）、黑木耳（Hirneola auricular-judae）和香菇（Lentinula edodes）子实体中提取漆酶，用分光光度法测定酶活，筛选出漆酶酶活最高的孢薪菇。实验结果表明，孢薪菇漆酶是一种对热较稳定的高温酶，其最适pH3.0，最适温度60℃；Pb^2 、K^ 对酶活有较大的激活作用，而Fe^3 、Fe^2 则对酶活有较强的抑制作用。     

用气相色谱研究[Co(NH_3)_4CO_3]Cl与NH_4SCN取代反应中配合物的结构变化

根据热分解的气相色谱分析结果推证反应过程的物质结构变化还未见报导.本文采用气查色谱与自制的热分解署联用,对[Co(NH_3)_4CO_3]Cl与NH_4SCN的固相热分解反应过程的产物进行检测。得出该取代反应是按S_N2机理进行的,推证了[CO(NH_3)_4CO_3]Cl和[CO(NH_3)_4CO_3]Cl+NH_4SCN在热分解过程中空间结构的变化。