Graphene-based hybrid materials and their applications in energy storage and conversion

Graphene attracts more and more scientists and researchers owing to its superior electronic,thermal,and mechanical properties.For material scientists,graphene is a kind of versatile building blocks,and considerable progress has been made in recent years.Graphene-based hybrid materials have been prepared by incorporating inorganic species and/or cross-linking of organic species through covalent and/or noncovalent interactions.The graphene-based hybrid materials show improved or excellent performance in various fields.In this review,we summarize the synthesis of graphene and graphene-based hybrid materials,and their applications in energy storage and conversion.     

地下洞库防水施工方案

军事用途的地下洞库,防水施工是施工控制的关键。防水施工是系统的施工过程,贯穿于洞库施工的各个阶段,任何一个阶段没有处理好,都会给整个工程留下隐患,从而影响到洞库的使用效果,加大后期使用成本。通过阐述6205洞室各施工阶段防水施工的控制要点,并结合现场施工实际,提出防水施工的具体施工方案。     

Effect of Mg substitution for La on microstructure, hydrogen storage and electrochemical properties of La1−xMgxNi3.5 (x=0.20, 0.23, 0.25 at%) alloys

The effect of Mg substitution for La on microstructure, hydrogen storage and electrochemical properties of the annealed La_(1-x) Mg_x Ni_3.5(x=0.20, 0.23, 0.25 at%) alloys have been studied. All the samples were mainly composed of(LaMg)_2Ni_7,(LaMg)Ni_3, and LaNi_5 phases. Mg substitution for La changed the phase abundance, but did not change the constitution of all phases, which is con fi rmed by the results of backscattered SEM images and EDS analysis. The P–C isotherms indicated that the La_(1-x) Mg_x Ni_3.5alloys reversibly absorbed and desorbed hydrogen smoothly at 298 K. The hydrogen absorption cyclic stabilities of La_(1-x) Mg_x Ni_3.5alloy after 5 hydrogen absorption/desorption cycles reached the maximum values of91.9% and 96.0% at 298 K and 323 K, respectively. The hydrogen desorption capacity and plateau pressure for the La_(1-x) Mg_x Ni_3.5alloy reached the maximum values of 1.055 H/M and 0.074 MPa, respectively. The desorption capacities of La_(1-x) Mg_x Ni_3.5reached 0.193 H/M and 0.565 H/M in the fi rst minute at 298 K and 323 K, respectively. Electrochemical property measurement indicated that La_(1-x) Mg_x Ni_3.5(x=0.20,0.23, 0.25 at%) alloys possessed excellent activation capability and were completely activated within3 cycles. Discharge capacities of La_(1-x) Mg_x Ni_3.5alloys reached 378.2 m A h/g(x = 0.20 at%), 342.7 m A h/g(x = 0.23 at%), and 369.6 m A h/g(x = 0.25 at%), respectively. Moreover, energy density of La_(1-x) Mg_x Ni_3.5alloy was much larger than that of La_0.80Mg_0.20Ni_3.5 alloy and nearly approaches the maximum value of La0.75Mg0.25Ni3.5. Thus, the La_(1-x) Mg_x Ni_3.5alloy exhibits optimum comprehensive properties of hydrogen storage and electrochemistry.     

中国书画颜料颜色仿真与存储方法研究

在虚拟绘制中,基于Kubelka-Munk颜色光学理论,提出了一种中国书画颜料颜色仿真新方法,其主要思想是:根据颜料R/G/B三颜色通道的遮盖力(c)和单位厚度颜料在黑背景下的反射率(Rb)计算得到颜料各颜色通道吸收系数(K)和散射系数(S),通过K、S和宣纸反射率计算得到宣纸上有效厚度为d时颜料的反射率(Rd),根据该反射率与下一层颜料的K、S和d计算得到两层颜料合成时的反射率,依此类推得到多层颜料合成时的反射率,将该反射率转换成颜色亮度值(R,G,B),从而得到宣纸上多层颜料合成时的颜色(RGB).在此基础上提出一种颜色存储方法,通过存储宣纸上颜色(RGB)实现对绘制结果的实时存取和显示.所提方法已成功应用于基于力反馈技术的虚拟绘制系统中,较好地仿真了植物色与矿物色在颜色合成中的不同特征.     

一种新颖的可重构数据存储压力仪

为更好获取导弹动态毁伤效应数据,利用嵌入式数据采集技术,使用CPU和FPGA作为主控芯片,设计了一种可重构的数据存储压力仪. 该仪器通过内置压电压力传感器,采用双路模拟放大电路和数字控制与存储电路,实现系统两种压力量程的测量,可提高测量精度;应用差动输入、输出方式实现内/外触发,提高触发电路的抗干扰能力,确保全系统触发的可靠性. 在战斗部打靶实验中,由该数据存储压力仪组成的测量系统成功测量了动态爆炸冲击波压力场,证明了该仪器具有良好的实用性、可靠性和可扩展性.     

网格存储中的自适应负载平衡策略

为了优化网格存储的系统性能,针对网格环境中不同存储单元的性能差异,基于文件的访问特点提出一种自适应的负载平衡策略. 通过建立能量模型体现文件访问对存储单元的负载压力;通过与用户访问复合减少负载调整开销;通过创建和回收副本实现数据访问优化. 实验证明,提出的负载平衡策略与传统的磁盘冷却算法相比,请求处理时间和系统吞吐量均有20%左右的提高.     

基于单片机的课堂签到系统设计与实现

目的为方便教师统计学生的出勤情况,设计和实现课堂签到系统。方法通过分析课堂签到系统的功能,采用发光二极管和光敏二极管构成了光电传感器电路,完成学生学号的识别,以AT89C51单片机、存储器芯片和显示器为核心来实现该系统。结果给出了课堂签到系统的硬件电路设计图和软件设计流程图。结论该系统可以完成到课学生信息的统计,同时,也能统计出未到学生的信息,极大的提高了教师的工作效率。     

WNXD数据库存储策略的研究和实现

针对NativeXML数据存储性能不高、支持查询和更新效率低等不足,提出一种新的半结构化信息存储模型WNXD。引入动态倒排技术和数据映像机制,将记录和分页的存储模式相结合,建立3种结构化索引,用不同方法解决了结构化和动态增长的矛盾。创建了实用的存储模型,提供了从整体到局部,从元素、属性到具体值的全面覆盖访问策略,底层的数据存取,尤其是内容混杂的各类形式异构数据的有效性和完整性存取,得到了最大程度保证,查询次数减小了I/O,提高了系统处理性能。     

金属有机骨架材料上气体吸附存储与分离的研究进展

对金属有机骨架(MOFs)材料的结构及合成方法做了简要概述;结合国内外研究现状详细介绍了MOFs材料在吸附存储与分离领域的研究进展,并对MOFs材料在该领域的应用进行了展望.     

无线传感网络中空间失效模式下的数据存储恢复算法

针对空间失效模式下的数据存储和恢复问题,设计了一种基于数据复制的存储和恢复算法.该算法为每个数据节点分配一个冗余节点,在数据节点失效时可以利用冗余节点中的数据来成功恢复数据,并且使整个过程消耗的代价最小.理论分析和仿真实验表明,同Greedy算法相比,在保证成功恢复的同时,该方法显著降低了网络的整体能耗,从而有效延长了网络的生存周期.