3%NaCl溶液中55%Al—Zn—1.6%Si合金镀层电化学参数测定及…

提出一种弱极化曲线测量数据计算机处理方法，并计算了５５％Ａｌ－Ｚｎ－１．６％Ｓｉ合金镀层在３％ＮａＣｌ溶液中腐蚀过程的电化学参数，研究了镀件在３％Ｎａ－Ｃｌ溶液中发生整体腐蚀加速的机理。     

电镀条件对镍相合金镀层结构组织和催化活性的影响

本较系统地研究了镍钼合金的电镀条件对镀层的化学组成，表面结构和析氢催化活性的影响。镀层中的钼含量和催化活性随镀液中钼含量的增加而增加。在较低ｐＨ值下电镀得到的镍钼合金具有较佳的析氢电催化活性。在ｌｍｏｌ／Ｌ ＮａＯＨ溶液，４０℃和１００ｍＡ／ｃｍ＾２电解条件下，析氢过电位约为１２２ｍＶ．用Ｘ光电子能谱和扫描电镜分别分析了镀层的表面元素价态和表面结构组织。     

Ni-P-PTFE化学复合镀工艺的磁场机理探讨

利用化学复合镀的方法,通过外加磁场这一新工艺的引入来制备Ni-P-PTFE复合镀层。研究过程中,在其它工艺条件不变的情况下,通过入镀时间、磁场强度、磁场方向等因素的改变,探究磁场对复合镀工艺及镀层性能的影响。研究结果表明：当有外加磁场作用时,复合镀层中的粒子沉积速度和粒子含量显著提升,同时,外加磁场强度的改变对所得复合镀层的厚度、耐蚀性能、成分都有较大影响。     

Structure and 57Fe conversion electron Mössbauer spectroscopy study of Mn-Zn ferrite nanocrystal thin films by electroless plating in aqueous solution

Mn1-xZnxFe2O4thin films with various Zn contents and of different thickness were synthesized on glass substrates directly by electroless plating in aqueous solution at 90℃ without heat treatment. The Mn-Zn ferrite films have a single spinel phase structure and well-crystallized columnar grains growing per- pendicularly to the substrates. The results of conversion electron ^57Fe Mossbauer spectroscopy （CEMS） Indicate that the cation distribution of Mn1-xZnxFe204 ferrite nanocrystal thin films fabricated by electroless plating is different from the bulk materials＇ and a great quantity of Fe^3＋ ions are still present on A sites for x〉0.5. When the Zn content of the films increases, Fe^3＋ ions in the films transfer from A sites to B sites and the hyperfine magnetic field reduces, suggesting that Zn2. has strong chemical affinity towards the A sites. On the other side, with the increase of the thickness of the films, Fe3＋ ions, at B sites in the spinel structure, increase and the array of magnetic moments no longer lies in the thin film plane completely. At x = 0.5, Hc and Ms of Mn1-xZnxFe204thin films show a minimum of 3.7 kA/m and a maximum of 419.6 kA/m, respectively.     

电沉积条件对Ni-S电极电化学性能影响的分析研究

介绍Ni-S电极的制备,以及电镀时间、电镀电流密度、镀层中硫含量、镀液pH值、镀液温度等对Ni-S合金电极的活性的影响。     

稀土对热镀锌层耐蚀性的影响

实验研究了稀土元素对GI镀锌液的流动性、镀层厚度、镀层微观结构以及耐蚀性能的影响,初步探讨了稀土提高GI镀层耐蚀性的作用机理.结果表明:添加稀土具有细化镀层表面树枝晶、提高镀液流动性、降低镀层厚度和改善镀层耐蚀性的作用;镀层的耐腐蚀性随着稀土含量的增加先增后减,即稀土对镀层耐蚀性的影响存在一个最佳范围;实验条件下,稀土含量ω=0.045%～0.069%时,镀层的耐盐雾腐蚀性能约为纯锌层的2.8倍.     

Fatigue behavior of press hardened Al-Si coated high strength steel

The fatigue behavior of press hardened Al-Si coated high strength steel has been investigated, and the fatigue strength turns out to be about 1 000 MPa. Surface morphology of fractured and non-fractured specimen has been observed, and the coating shows significant influence on the fatigue behavior. The difference of elastic modulus between coating and substrate led to the main cracks perpendicular to the loading direction. The coating close to fracture exfoliated thinly, while the coating far away from the fracture kept integrated. Though the specimen was polished to obtain high surface quality, 3 types of cracks occurred during the fatigue test. What＇ s more, inclusion particles were proved to play a crucial role in causing these cracks.     

模糊控制在钢材镀层厚度方面的研究

本文对带钢连续热镀锌生产线进行了研究,带钢镀层厚度控制系统采用传统PID控制器进行控制带钢的镀层厚度。现场的强干扰会导致镀层厚度模型参数的改变,导致传统PID控制的效果受到影响。然而,模糊控制是综合专家的操作经验,具有不依赖被控对象的精确数学模型的特点。为此,在大量现场数据的基础上设计了基于模糊控制的带钢镀层纵向平均控制系统。     

碳纳米管的制备及其在纳米复合镀层中的应用研究

利用化学气相沉积法制备碳纳米管(carbonnanotubes,CNTs),分析了气源、催化剂及温度等因素对CNTs形貌和纯度的影响.利用化学复合镀技术制备了Ni P CNTs纳米复合镀层,并研究了镀层的摩擦性质及电化学性质.研究结果表明:与Ni P镀层相比,Ni P CNTs纳米复合镀层的耐磨性及耐腐蚀性均有较大程度的提高.