2-芳基硫杂脯氨酸的合成及其研究(Ⅰ)——芳醛与半胱氨酸缩合反应动力学

硫杂脯氨酸是一种能使癌细胞逆转为正常细胞的新型抗癌药物,它的一系列衍生物具有多种抗癌疗效,而2-取代衍生物具有令人感兴趣的抗癌作用。本文在合成一系列(10种)2-芳基硫杂脯氨酸衍生物基础上,测定了合成反应动力学的有关参数,初步探讨合成反应机理。     

约束子结构法的一种改进

在动态分析中利用有限单元法,常常会导致大规模的矩阵,通常利用子结构的模态综合来减缩矩阵的阶数.本文提出一种新的方法,以减缩约束子结构模态综合中的连接坐标.基于相继缩聚,在Craig方程中的对接结点位移即可逐次消去.因而这种方法克服了经典减缩中所存在的缺点,可连续使用约束子结构法,直至最后一级系统的连接坐标维数被减缩到容许的规模为止.数值计算结果表明,本文改进的减缩方法是有效的.     

Simulation of sub micron particle formation and growth during combustion processes

Recently ,hazardscausedbysuspendedparticu latematter (SPM ) ,especiallybyparticleswithdiam etersmallerthan 1.0 μm (PM 1.0 ) (calledsub mi cronparticles) ,havereceivedmuchattentionintheenvironmentalresearch[1] .Combustion processcaninherentlyresultintheformationofsub micronparti clesanditisamajorsourceofatmosphericloadingofsuch particles .Thesecombustiondevicesincludesmelters,coalcombustion ,waste to energyincinera tors ,andcementkilns .Althoughenvironmentalreg ulationsaredesignedandusedunde…     

Numerical investigation on the self-excited oscillation of wet steam flow in a supersonic turbine cascade

The self-excited flow oscillation due to supercritical heat addition during the condensation process in wet steam turbine is an important issue. With an Eulerian/Eulerian model, the self-excited oscillation of wet steam flow in a supersonic turbine cascade is investigated. A proper inlet supercooling results in the transition from steady flow to self-excited oscillating flow in the cascade of steam turbine. The frequency dependency on the inlet supercooling is not monotonic. The flow oscillation leads to non-synchronous periodical variation of the inlet and outlet mass flow rate. The aerodynamic force on the blade varies periodically due to the self-excited flow oscillation. With the frequency lies between 18.1?80.64 Hz, the oscillating flow is apt to act with the periodical variation of the inlet supercooling due to stator rotor interaction in a syntonic pattern, and results in larger aerodynamic force on the blade. The loss in the oscillating flow increases 20.64% compared with that in the steady flow.     

外势场中理想玻色气体的玻色-爱因斯坦凝聚的热容性质

研究了在任意空间外势场中理想玻色气体的玻色-爱因斯坦凝聚问题,从而计算热容量且讨论了热容量性质.     

Two-phase flow patterns for flow condensation in small-diameter tubes

Two-phase flow patterns have been observed visually to investigate the effects of tube diameter, mass flux and tube inclination on flow condensation in small-diameter tubes. For horizontal or inclined small-diameter tubes, gravity-domination is decreased by shear stress and surface tension on phase change interface, which weakens the stratification of condensate and vapor flow due to the action of gravity perpendicular to flow direction. As decreasing the tube diameter from 5. 79 mm to 2.18 mm. the annular or sub-annular flows become prevailing in flow regime map. The existing flow regime maps for macro scale cannot predict the experimental data in the present study.     

Heat Transfer in Flue Gas with Vapor Condensation

IntroductionDetermination ofthe total heattransfer coefficientsfor the convection of gases containing acondensable vapor is an increasingly important andinteresting topic,since this kind of heat transferprocess is frequently encountered in the utilizationof waste or low temperature energy.The recoveryof low temperature energy is an importantenvironment issue.With condensable vapor,theconvective heat transfer is greatly increased by thecondensation of the condensable gas (water vapor)in flue ga…     

假性紫罗兰酮合成新工艺(Ⅱ)

本文研究柠檬醛与丙酮以碱性物质为催化剂在均相条件下缩合制备假紫罗兰酮的工艺 条件．缩合反应温度为35℃，反应时间1h，假性紫罗兰酮摩尔得率提高到85％以上．     

沥青乳化剂乳化效果的研究

用从造纸废液中提取的木质素与亚硫酸钠反应,合成磺化木素(EL-2-1)。以虹外、元素分析方法给予鉴定。二亚乙基三胺与油酸经缩合、环化反应,生成氨基乙基氢化咪唑啉。用EL-2-1、咪唑啉作乳化剂对胜利100~*乙道路沥青进行乳化效果的考察。试验结果表明,两种乳化剂均能较好地乳化胜利100~*乙道路沥青。沥青乳液的拌和稳定度试验结果表明,EL-2-1为慢裂型乳化剂;咪唑啉为快裂型乳化剂。     

翅片管与空气—水蒸汽混合气间传热规律研究

本文研究水蒸汽重量百分含量为10－35％的空气－水蒸汽混气纵向流过翅片管时，翅片管与空气－水蒸汽混合气间的对流传热。研究表明，由于水蒸汽在翅片面上的冷凝，翅片管与空气－水蒸汽混合气间的对流传热系数高于翅片管与干气体间的对流传热系数，并且翅片间距越大，水蒸汽冷凝使对流传热系数增加的程度越大。从理论上对实验现象做出了较好的解释，并给出子有冷凝发生时，翅片管与空气－水蒸汽混合气间对流传热系数的关联式。