禾黑芽枝霉诱变体果胶酶的化学修饰

用乙基碳化亚二胺（ＥＤＣ）、二乙基焦碳酸（ＤＥＰＣ）、磷酸吡哆醛（ＰＬＰ）、过氧化氢（Ｈ２Ｏ２）、三硝基苯磺酸（ＴＮＢＳ）、对氯汞苯甲酸（ＰＣＭＢ）、Ｎ－经琥珀酰亚胺（ＮＢＳ）、碘乙酸（ＩＡＣ）和二硫基二硝基苯甲酸（ＤＴＮＢ）分别对禾黑 霉本的三种果胶裂解酶（ＰⅠ，ＰⅡ，ＰⅢ）进行了化学修饰，紫外可见光谱的实验结果证明，各种试剂都与果胶酶氨基酸特定残基共价结合，大多数氨基酸残基的化学修饰对果胶酶的     

戊二醛修饰上转换发光材料Na[Y0.57Yb0.39Er0.04]F4的制备与表征

利用表面接枝改性法,用戊二醛作修饰剂,对上转换发光材料Na[Y0.57Yb0.39Er0.04]F4进行了表面醛基修饰.傅里叶红外吸收光谱证明了醛基的存在,紫外分光光度法定量检测修饰醛基的含量为1.38×10-3mol.g-1,热分析定性地证明了材料表面有机官能团的存在,扫描电镜显示了修饰后上转换无机发光材料颗粒的直径有所增加.沉降实验表明,修饰醛基后的上转换发光材料在水溶液中的分散稳定性得到了提高.     

Chemical reductionism revisited: Lewis, Pauling and the physico-chemical nature of the chemical bond

The wave-mechanical treatment of the valence bond, by Walter Heitler and Fritz London, and its ensuing foundational importance in quantum chemistry has been traditionally regarded as the basis for the argument that chemistry may be theoretically reduced to physics. Modern analyses of the reductionist claim focuses on the limitations to achieving full reduction in practice because of the approximations used in modern quantum chemical methods, but neglect the historical importance of the chemical bond as a chemical entity. This paper re-examines these arguments with a study of the development of the valence bond by chemist Gilbert Lewis within a chemically autonomous framework, and its extension by Linus Pauling using Heitler and London’s methods. Here, we see that the chemical bond is best described as a theoretical synthesis or physico-chemical entity, to represent its full interdisciplinary importance from the philosophical and historical perspectives.     

异相光催化技术及其影响因素和改进方法

介绍半导体异相光催化反应机理、影响异相光催化的因素．综述贵金属沉积、金属离子掺杂、复合半导体、半导体的表面光敏化等改性手段对光催化活性的影响，并对其原理进行解释和说明．     

无机缓蚀剂在化学清洗中的作用机理

从电化学腐蚀角度分析，阐明了无机缓蚀剂在化学清洗中的作用机理。     

集成化工过程仿真培训系统

设计了一种集成应知／应会培训与化工流程培训的化工过程仿真培训系统。它既巩固了操作工的理论知识，又提高了操作实际装置的能力，因而能显著增强培训效果     

稀土变质、多元微合金化处理的高锰钢淬火新工艺

经稀土变质、多元微合金化处理的高锰钢，其铸态组织形态、大小、间距及分布状态均发生了很大的变化。与普通高锰钢相比，强韧性有了显著提高，热裂现象在很大程度上得以消除，抗磨性能大大增强。据此提出：应根据该材质铸件结构的特点及复杂程度，参考使用条件及对其性能的特殊要求，分别采用简单实用、经济合理的淬火新工艺。     

硝酸剥蚀对纳米铜粉在润滑油中分散特性的影响

对纳米铜粉进行硝酸剥蚀和表面改性,研究剥蚀程度和表面改性剂的用量对纳米铜粉分散性能的影响.应用X射线衍射(XRD)、透射电镜(TEM)和傅里叶红外光谱(FI-IR)对剥蚀和改性后纳米铜粉的组成、颗粒大小、表面状况进行表征.结果表明:硝酸剥蚀可以起到细化纳米铜粉颗粒的作用,聚乙烯吡咯烷酮(PVP)在对纳米铜粉表面改性的同时抑制Cu2O的产生.剥蚀改性后的纳米铜粉的分散稳定性明显优于未剥蚀改性的纳米铜粉.     

《大清刑事民事诉讼法草案》搁置时间考析

关于《大清刑事民事诉讼法草案》搁置的时间，考证认为光绪三十三年十月法部奏准的《各级审判厅试办章程》实际取代了草案的立法空缺，而光绪三十四年九月法部继续覆议的奏折是以清朝官场传统的方式宣布草案退出覆议程序。因此，草案搁置的确切时间点应该是在光绪三十四年九月，因为此时法部进呈的继续覆议奏折标志着草案以体面的方式宣告退出法案覆议程序。     

Structural Performance and Characterization of Polyimide Doped Activated Carbon Fibers for Mercury Adsorption

Structure characteristics about activated carbon fibers (ACF) and polyimide (P84) doped ACF modified by HNO3 solution were studied to apply in mercury removal in coal-fired flue gases.The P84,which was always used in the non-woven fabric for bag filter,was intermingled with polyacrylonitrile-based ACF (PAN-ACF) in the weight ratio of 1:1 in order to make the doped ACF with P84 (doped-ACF-P84).Then the doped-ACF-P84 fibers were modified by HNO3 solution.The structure and morphology of doped-ACF-P84 were characterized and compared with those of ACF and doped-ACF-P84 modified by HNO3 solution.The results show that the modified doped-ACF-P84 fibers have almost the same pore structure and specific surface area comparing with the original one.However,contrasted with the original PAN-ACF,the doped-ACFP84 fibers modified by HNO3 solution have more oxygen-containing groups used for mercury removal.In particular,they have more lactone and carboxyl groups.