Accumulation process and model for the Ordovician buried hill reservoir in the western Lunnan area, the Tarim Basin

The Ordovician buried hill reservoir in the western Lunnan area, a type of dissolved fracture and cavernous reservoir, is mainly composed of heavy oil. The oil is the mixture sourcing from the Middle-Lower Cambrian and Middle-Lower Ordovician, with three stages of pool forming process： （1） the destruction and parallel migration/accumulation during the late Caledonian to early Hercynian; （2） the oil and gas accumulation during the late Hercynian characterized by adjustment upward along faults and parallel migration/accumulation; （3） the formation of heavy oil during the latest Hercynian. The Ordovician buried hill reservoir is affected by the diffusion of light oil and gas but had no hydrocarbon charging during the late Yanshan period to Himalayan period, but in this period, formed the association of heavy oil and dissolved gas cracked from crude oil with dry coefficient of 0.91-0.96. The study on accumulation process of the Ordovician buried hill reservoir has important implications for the exploration potential of early oil and gas accumulation in the cratonic area of the Tarim Basin.     

胜利油田王家岗地区沙四段裂缝储层测井识别方法研究

由于断裂带作用，胜利油田王家岗地区沙四段泥质灰岩段裂缝较发育，形成裂缝储层。研究应用常规测井资料识剐王家岗油田裂缝储层的方法。利用测井资料识别裂缝储层往往存在多解性，为提高裂缝储层识别能力，对王家岗地区裂缝储层发育程度应用综合概率方法进行识别研究，并应用该方法对王家岗油田王120井的裂缝储屡进行了有效识别。     

Division and formation mechanism of coalbed methane reservoir in Huainan Coalfield,Anhui Province,China

The coalbed methane (CBM) reservoir is the basic geological unit of CBM storing and CBM resource developing. The forming conditions of the CBM reservoir include coal thickness, coal rank, seam buried depth, caprock, and geological structure. The division of a CBM reservoir in the Huainan coalfield is mainly based on the geological structure form and seam buried depth. According to the Fufeng nappe and the secondary structures of Huainan syn-clinorium, seven CBM reservoirs are divided in the Huainan Coalfield, such as Caijiagang, and the dynamic mechanism of CBM forming is analyzed. The structural position where the CBM reservoir is located has the important controlling role on the features of CBM reservoir.     

西松烯内酯的合成研究Ⅲ．苏式－7，14－二羟基－3，9，13－三甲基－6－异丙烯基－（2E，8E，12E）－十四碳三烯苯硫醚的合成

本文报道苏式－７，１４－二羟基－３，９，１３－三甲基－６－异丙烯基－（２Ｅ，８Ｅ，１２Ｅ）－十四碳三烯苯硫醚（８）的２条合成路线，路线１以溴化物（３）和牛儿醛为原料，经缩合，基团保护、氧化和去保护基四步反应合成（８），总产率２４％，路线２则经氧化和缩合两步反应得到（８），总产率４８％。     

Simulated experiment evidences of the corrosion and reform actions of H2S to carbonate reservoirs： an example of Feixianguan Formation, east Sichuan

The reservoir of Feixianguan Formation of the Lower Triassic in the Sichuan Basin is the deepest buried carbonate reservoir in China, with developed secondary corrosion holes, high quantities carbonate reservoir, maximum effective carbonate reservoir thickness. Also Feixianguan gas reservoir has the highest quantities of H2S. Research discovers that there are close relationships between the formation of reservoir and H2S. The mutual actions between acidity fluid and carbonate promoted the forming of secondary carbonate holes. Through the experiment of corrosion of the samples of Feixianguan carbonate reservoir in saturated aqueous solution of hydrogen sulfide, the porosity and permeability increased greatly, porosity increased 2% and permeability increased nearly two quantity degrees, also the density became light, which confirm the corrosion and reform actions of H2S to carbonate.     

碳酸盐岩油藏基质酸化水平井表皮因子模型研究(Ⅰ)理论模型建立

水平井开采技术是近年来广泛用于页岩薄层、低渗透等复杂油藏开采的一种主要方法.然而,如何全面考察来自油藏、酸液及酸化过程中的一些主要因素特别是难于用一般方法描述的酸蚀孔洞形成和生长的随机因素对酸化处理效果的影响,则是碳酸盐岩油藏水平井基质酸化技术设计和效果评价时所遇到的难题之一.通过首次综合考虑当代分形理论研究的新成果——酸蚀孔洞形成和生长过程中的分形与分维特征、水平井地层伤害沿水平井筒的椭圆柱体分布形态以及水平井油藏渗透率各向异性特性,提出了一种碳酸盐岩油藏水平井表皮因子综合模型,从而为上述问题的探讨在一定程度上提供了理论基础和可能途径.     

煤矸石在水库坝体填筑中的实际应用

在水库土石坝填筑施工中,针对填筑料的储备极大地影响工程的进度和成本,论述了如何有效利用地方资源,寻找可利用的代替材料已经作为新兴的课题。     

Main controlling factors of distribution and genetics of marine reservoirs in China

Marine reservoirs are mainly made up of clastics and carbonate reservoirs, which are distributed widely in central Tarim, Sichuan, Ordos basins from the Pre-Cambrian to Cenozoic, mainly in Palaeozoic. Marine clastic reservoirs are developed in foreshore and nearshore, tidal flat and delta environment. The sedimentary facies are important controlling factors for reservoir quality. Compaction, pressolution and cementation are factors of decreasing porosity, and low palaeo-temperature gradient, early emplacement of oil and gas and dissolution are favorable for preservation of pore. Carbonate reservoirs are divided into reef and bank, karst, dolomite and fracture reservoirs. Dolomitization, dissolution, TSR and fracture are important factors of controlling carbonate reservoirs＇ quality.     

Chemical analysis of the pheromone blends produced by males and females of the neotropical moth,Mocis megas (Guénée) (Lepidoptera,Noctuidae, Catocalinae)

Summary Pheromonal secretions produced by females and males of the noctuid moth,Mocis megas (Guénée) have been analyzed by gas chromatography and mass spectrometry (EI (electron impact) and CI (chemical ionization)). The female sex pheromone was a blend of (Z,Z,Z) 3,6,9 heneicosatriene (55%) and (Z,Z) 3,6-cis-9S, 10R-epoxyheneicosadiene (45%). Male secretion produced at the level of a prothoracic organ was a blend of two unsaturated major hydrocarbons: (Z,Z) 6,9 heneicosadiene, (64%) and (Z,Z,Z) 3,6,9 heneicosatriene (24%) and C₁₉, C₂₀ and C₂₂ homologues (total ratio 12%), as minor components. The trienic hydrocarbon was present in both sexes. The behavioral role of this male secretion has not yet been elucidated.     

Novel rearrangement of purines

Summary 6-Trichloromethyl-9-methylpurine (1) rearranges to 6-dichloromethyl-9-methyl-8-oxopurine (2) in aqueous mild acidic solution. The rearrangement is rationalized in terms of a reaction involving protonation, covalent hydration, prototropic equilibrium and/or a hydride transfer. An alternative mechanism involving a positive halogen compound and hypochlorous acid as an intermediary is also proposed. Compound1 condenses with 4,5-diaminopyrimidine to give the purine-pyrimidine Schiff base pair4.Acknowledgments. We are deeply indebted to Professor S. Cohen of the Sackler School of Medicine, Tel Aviv University (Ramat Aviv, Isreal) for his advice and encouragement. Support of this research by the Israel Cancer Association, the Ber-Lamsdorf Foundation Switzerland Israel and by the Advancement of Mankind Foundation, is gratefully acknowledged. We thank Proff. D. Arigoni and A. Eschenmoser, ETH Zürich, for their valuable proposals and comments on the mechanism of the rearrangement.