水环境中石油烃类的TiO2光催化降解量子产率的测定

把反应速率常数和量子产率作为动力学常数,研究了石油烃类化合物的TiO2光催化氧化降解.并采用高光密度法,以K3Fe(C2O4)3做光露计,300 W中压汞灯为光源,在365 nm波长处测定石油烃类的反应速率常数和量子产率.结果表明:正十六烷、正癸烯和萘等石油烃类在365 nm波长下的TiO2光催化氧化降解反应均服从一级反应动力学,其反应速率常数分别为4.3×10-3、6.7×10-3和5.1×10-3m in-1.K3Fe(C2O4)3光解服从零级反应,其速率常数为5×10-5(mol/L)-1.m in-1;正十六烷、正癸烯和萘的量子产率分别为1.20、1.87和1.42,其值均大于1,进而表明了TiO2光催化氧化法对石油烃类化合物的降解反应可能有活性氧参与.     

Bi2Ti2O7薄膜的制备及在栅场效应管中的应用

采用化学溶液沉积法，用价格低廉的原料成功地制备了Bi₂Ti₂O₇介质膜.制膜过程简单，成本低廉，得到的薄膜具有良好的绝缘性和较高的介电常数.用其制备的绝缘栅场效应管与相同尺寸的SiO₂绝缘栅场效应管相比，前者具有较高的跨导和较低的开启电压.     

Mining the Change of the Quality of Stored Grain

The quality of grain changes continually during its storage, including the change of its physical characteristics and physiological characteristics. This paper presents an approach to predict the change of the quality of stored grain with data mining technology. Logistic Regression, Decision Tree and Muitilayer Perceptron are applied to predict the change of the grains＇ quality control index and to obtain the grains＇ quality change probability. The grain sampling with higher probability can be processed earlier.     

Preparation and Characterization of Organic/Inorganic Hybrid Nanofibers

A new class of nanocomposites based on organic and inorganic species integrated at a nanoscale has obtained more attention these years. Organic-inorganic hybrids have both the advantages of organic materials, such as light weight, flexibility and good moldability, and inorganic materials, such as high strength, heat stability and chemical resistance. In this work, PVAc/TiO2 organicinorganic hybrid was prepared by sol-gel process. Eiectrospinning technique was used to fabricate PVAc/TiO2 hybrid nanofibers. The structures and properties of the hybrid nanofibers were characterized by Scanning Electron Microscopy （SEM）, Atomic Force Microscope （AFM）, Differential Scanning Calorimeter （DSC） and Fouriertransform infrared （FTIR） spectra. SEM and AFM were employed to study the topography of the hybrid nanofibers. The chemical structure of the hybrid nanofibers were examined by FTIR. The DSC scans revealed the second order transition temperature of the hybrid materials were higher than PVAc.     

Synthesis and Characterization of Titania and Rare Earth Doped Titania Nanoparticles by Sol-gel Process

Titania sol has been prepared by the sol-gel process with Ti（OC4H9）4, as precursor. TiO2 gel was obtained through hydrolysis and condensation process. Rare earth such as La2O3, CeO2 and Gd2O3 were introduced into the nanostructure TiO2. After TiO2 and rare earth doped TiO2 powders were calcined at 400℃, 500℃, 600℃, 700℃ and 800℃ respectively, the characteristic analyses of the TiO2 samples were studied by UV-VIS, XRD and TEM etc. It was found that there are some stringer absorption peaks at 200 - 325 nm. The rare earth doping can increase the phase transition temperature convertin8 anatase phase into rutile phase, can decrease the grain size of TiO2particles and can improve the ann-UV capacity of the coating fabrics.     

Mg-(6～8)A1-0.7Si合金的组织和力学性能分析

通过金相观察、扫描电镜、X衍射分析和拉伸实验等方法,研究了Mg-(6~8)A1-0.7Si合金的铸态组织和力学性能.研究结果表明:添加了少量Sb和RE的Mg-(6~8)%A1-0.7%Si的铸态组织主要由α-Mg基体、Mg17A l12相、Mg2Si相、Mg3Sb2相和少量针状A l4Si2Mn2Y相组成,并且随着A l含量的增加,试验合金组织中的Mg17A l12相增多,共晶析出物变得更加连续.同时,力学性能的测试结果表明:A l含量变化对于试验合金抗拉强度、屈服强度和延伸率的影响呈现出不同的变化规律.     

基于ANSYS的结构设计优化

优化设计是工程界较为关注的领域,阐述了ANSYS软件设计优化程序的原理及具体设计步骤,针对两个实例分别采用GUI交互式和命令流式介绍ANSYS在具体结构优化设计中的实现方法。结果表明:基于ANSYS的合理结构设计能够在满足安全性的前提下节省材料。获得很大的经济效率。相对于交互式来说。采用ANSYS程序的命令输入整个优化文件并进行优化的方法是采用计算机解决工程实际问题的简单易行、快速可靠的方法。     

硬质聚氨酯泡沫塑料的开发

以废聚酯(瓶)为原料,研究了废聚酯瓶料醇解成芳香族聚酯多元醇的工艺。探讨了聚酯多元醇、泡沫稳定剂、发泡剂及催化剂等原料对硬质聚氨酯泡沫塑料制备的影响。     

所有制结构与吉林省经济增长的关系分析

通过C-D生产函数衍生得到的计量模型,分析公有制和非公有制经济生产中投入要素劳动和资本的变化对吉林省经济增长的效应。结果表明,非公有制经济中劳动投入的增长,是通过提高总劳动的效率而提高经济总产出;非公有制中资本投入的增长,是通过提高总资本的效率而拉动经济增长。因此,加快所有制结构调整,增加非公有制投资比例,对推动我省经济发展具有重要意义。     

新型固体酸催化剂SO42-/Al2O3-Al的制备

采用铝阳极氧化法和浸渍法制备出新型SO42-/Al2O3-Al固体酸催化剂,通过BET,XRD,XPS等物性表征,考察了阳极氧化时间、焙烧温度等对催化剂制备的影响。BET结果表明,催化剂的比表面积要小于载体Al2O3的比表面积;XRD结果表明,载体Al2O3为无定形结构,且负载SO42-后,催化剂的物相结构没有发生改变;XPS结果表明,催化剂表面主要由SO42-和Al2O3组成。活性评价表明,该催化剂对酯化反应具有较好的催化活性。