中国西南部第四纪碳酸钙年代与古环境的地球化学特征

喀斯特地区的泉水和溪流水中沉淀下来的一种次生沉积物，是由碳酸钙过饱和沉淀产生的．碳酸钙沉积或沉积多寡受到多种因素的控制和影响，其中古环境，特别是古气候，影响尤甚．我们通过同位素测年工作，探讨了云贵高原第四纪以来的古环境的演递及其发育历史．     

The annexins: spatial and temporal coordination of signaling events during cellular stress

Annexins are a family of structurally related, Ca²⁺-sensitive proteins that bind to negatively charged phospholipids and establish specific interactions with other lipids and lipid microdomains. They are present in all eukaryotic cells and share a common folding motif, the “annexin core”, which incorporates Ca²⁺- and membrane-binding sites. Annexins participate in a variety of intracellular processes, ranging from the regulation of membrane dynamics to cell migration, proliferation, and apoptosis. Here we focus on the role of annexins in cellular signaling during stress. A chronic stress response triggers the activation of different intracellular pathways, resulting in profound changes in Ca²⁺ and pH homeostasis and the production of lipid second messengers. We review the latest data on how these changes are sensed by the annexins, which have the ability to simultaneously interact with specific lipid and protein moieties at the plasma membrane, contributing to stress adaptation via regulation of various signaling pathways.     

淡水养殖的珍珠贝壳热分解行为研究

采用FTIR实时红外检测方法研究室温～600 ℃范围内贝壳珍珠层的红外光谱特征,结合热重分析考察淡水养殖珍珠贝壳中的有机和无机组分变化情况.采用扫描电子显微镜观察珍珠层的微结构,并利用X-射线衍射方法测量不同温度下贝壳中无机成分的晶相变化.结果表明,贝壳中氨基酸类有机物热分解后部分以胺的形式挥发,另一部分则转化为不可挥...     

Synthesis of CaCO3 crystals using hydroxypropylmethyl cellulose hydrogel as template

Calcium carbonate crystallization was performed in hydrogel of hydroxypropylmethyl cellulose (HPMC). Results showed that the polyhydroxy functionalities in HPMC gel network facilitated the nucleation of aragonite which was not found in experiment without HPMC hydrogel and in experiment using methylcellulose (MC) hydrogel as template. On the other hand, due to the unique assembly of the macromolecules in HPMC hydrogel network, which was different from other hydrogels used in some previous reports, particular crystal morphology, corncob-like CaCO_3, was obtained for the first time.     

从碳酸轻稀土提取二氧化铈

本实验，首先根据铈易被氧化成四价铈的性质，使Ce(OH)3lfnywx o C(OH)4.须稀酸（PH≈2．5）中，Ce(OH)4不溶解，而E（OH）3能溶解，使铈与其他轻稀土元素得到初级分离，再根据四价铈容易被磷酸三丁酯（TBP）萃取的性质，使铈得到进一步纯化，后经草酸沉淀、过滤、灼烧得到纯的二氧化铈。     

间歇搅拌釜中甲醇与二氧化碳合成碳酸二甲酯

二氧化碳与甲醇直接合成碳酸二甲酯是一条对化学工业和环境保护都具有吸收力的工艺路线。本文在间歇式反应器中筛选出镁粉作催化剂,测试了各种反应条件的影响,得出了适合的反应条件。     

聚乙二醇对碳酸钙结晶的影响

在聚乙二醇（ＰＥＯ）存在下,ＣａＣｌ２和Ｎａ２ＣＯ３反应得多晶形碳酸钙沉淀,Ｘ－衍射显示主要为文石型结构,并随着ＰＥＯ／Ｃａ摩尔比的增大,晶体颗粒变小。结果表明,聚合物对碳酸钙晶核的形成和晶体的生长有很大影响。本文还对其形成机理进行了初步探讨。     

基于微米CT和扫描电镜的碳酸盐岩微观结构特征分析

为了研究羌塘盆地二叠系龙格组碳酸盐岩储层的微观结构特征,通过微米CT扫描技术和大面积背散射高分辨率扫描电镜成像技术对龙格组典型岩心的三维孔隙结构、空间分布、连通性及孔隙类型等参数进行精细的表征和定量分析,结果表明龙格组地层整体属于低孔-特低孔、微-细喉道、特低渗-超低渗储层,裂缝以构造缝、压溶缝以及溶蚀缝为主,且多被各类高密度矿物及有机质充填,有效裂缝较少。储集空间以微米、纳米级孔隙为主,主要为粒间孔和溶蚀孔,孔隙半径小于20μm,喉道半径在0.08μm左右,孔隙度在0.01%～1.02%,渗透率在0.000 041～0.001 5 mD。该地层受沉积环境影响及后期多期次构造运动和成岩作用控制,矿物成分复杂,储层物性在空间上变化快,非均质性强,具有多孔介质特征,储集空间结构多样、类型复杂。结合矿物成分和微观结构特征分析,在以方解石为主的泥晶灰岩地层,微米级的粒间溶孔较为发育,其孔隙度和渗透率相对较高,且局部发育微裂缝,综合储层物性较好,可作为未来油气资源勘探重点关注的目标层。