CO2泡沫剂的气溶性与封堵性研究

为有效封堵CO_2气窜通道和提高驱油效率,研制了气溶性的CO_2泡沫剂N-NP-15c-H。应用高压可视化搅拌式泡沫仪在不同温度、压力下进行了泡沫剂气溶性测试并评价了助溶剂的增溶效果。研究表明,加入助溶剂后泡沫剂在CO_2中的溶解量可提高到1.31%。填砂模型封堵性能实验表明,在125℃的低渗透率(27 mD)孔隙介质中形成了有效的CO_2泡沫封堵,阻力因子最高达14。该泡沫剂具有较好的应用前景,可以为CO_2驱油封堵气窜提供技术参考。     

超长煤巷监测数据背景CO筛查及自燃预判研究

为了解决超长双煤巷自燃发热的早期预报问题,在自燃标志气体分析法失效的情况下,运用井下监测系统大数据的CO趋势分析法。为了筛除井下柴油机动车尾气产生CO的波动干扰,创新提出能够仅反映煤相对缓慢氧化的背景CO体积分数的概念;对矿井某一独立通风的考察区域,在某一足够长的时间段内,总能找到所有柴油车都不工作的极端时刻（或不受尾气干扰的情况）,且CO体积分数值被监测系统记录到,从而建立了背景CO体积分数的筛查方法;经时间单元周期为0.125 d和0.5 d时的筛查结果对比,随着考察时间单元的取大,CO体积分数曲线越来越低,波动减小,背景CO体积分数曲线越来越清晰,证明其客观存在性。以最短自然发火期的一部分为考查期,依据背景CO体积分数的趋势走势来预判煤柱自然发火,结合红庆梁煤矿经验,得到CO趋势递增率k^*₁=0.607×10^-6 d^-1,以此作为自燃危险预判的临界指标,将自燃危险预警分三级,即当k₁ ≥k^*₁,一级预警,启动重点巡查,将超长距离...     

Theoretical advances of the structures and catalytic activities of small-sized gold nanoclusters

Gold nanoclusters exhibit extraordinary catalytic activities,but the dominating factor is still unclear due to the complexity of the structures.In this review,we briefly summarized the recent theoretical progress on their structures and catalytic activities.Combining the experimental and theoretical efforts,the structures of small-sized gold clusters have been explored systematically.Based on the determined structures,factors that influence the catalytic capabilities of small-sized gold clusters(Au_(16)-Au_(35))are studied using CO oxidation asa probe.The preadsorption energies of CO and O_2are found strongly correlated with catalytic activities,which could be affected by the clusters'geometries,sizes,and charge distributions.In addition,the presence of water could significantly lower the activation energy barrier of O_2 dissociation to enhance the clusters'catalytic activities.     

含CO体系在载铜吸附剂上吸附动态性能(2)--数学模型化研究

建立了合适的吸附动态模型,用于描述含CO体系在载铜吸附剂上的吸附特性,利用单组分实验数据的模型参数能够对多组分动态透过曲线进行很好的预测,不仅可减少实验工作量,而且对本体系吸附过程的工业放大设计具有指导意义,也为其它吸附过程数模的开发提供借鉴作用.     

煤矿生产中电动机事故原因分析及预防措施

电动机在煤矿生产中发生故障是难免的,但它严重地影响煤矿的安全生产。文章针对电动机事故的原因进行分析,提出了相应的预防措施。     

微小型高功率CO_2气体激光器的新进展

简要介绍了 CO2 气体激光器、波导 CO2 激光器件微小型化的现状 ,着重介绍了自己研制的全金属环状波导管 CO2 激光器件 .该器件按增益体积整体缩放 ,扩散冷却型新技术、新概念 .并指出 ,该新技术、新概念将是今后气体 CO2 激光器微小型高功率化的最有效途径之一 .     

Preparation and kinetic analysis of Li4SiO4 sorbents with different silicon sources for high temperature CO2 capture

Using diatomite and analytical pure SiO2 as silicon sources,Li4SiO4 sorbents for high temperature CO2 capture were prepared through solid-state reaction method.Phase composition was analyzed by X-ray diffraction,and the CO2 absorption capacity and absorptoin-desorption performance were studied by the simultaneous thermal thermogravimetric analyzer(TG-DSC).The results showed that silicon source had an important influence on CO2 absorption properties.The kinetic parameters for the chemisorption and diffusion processes were obtained by the isothermal study for different silicon sources.The results showed that the activation energies for these two processes were estimated to be 105.427 and 35.928 kJ/mol for the sample with analytical pure SiO2(AS).While for the sample with diatomite(DS),the activation energies for these two processes were estimated to be 78.500 and 20.439 kJ/mol,respectively.     

La_(1-x)Cu_xNiO_3复合氧化物的制备及其催化性能研究

采用溶胶-凝胶法研制La1-xCuxNiO3复合氧化物系列催化剂,考察该系列催化剂对NO和CO的催化转化性能,并借助X-射线衍射(XRD)、扫描电子显微镜(SEM)等方法研究催化剂的活性与结构的关系.结果表明,所制得的La1-xCuxNiO3复合氧化物催化剂都具有钙钛矿型结构,其中La0.8Cu0.2NiO3复合氧化物的颗粒较小,粒径较为均一,从而催化性能更好,对于NO的还原和CO的氧化都具有良好的催化活性,能使NO和CO的转化率分别高达96.3%和90.5%.     

交通事故责任认定在刑事审判中的运用－兼评最高人民法院[2000]33号司法解释

交通事故责任是由违章行为与交通事故的因果关系及其在因果关系中的作用决定的，所以在审理交通肇事刑事案件时，应注意这几个问题：交通事故责任不能直接等同于当事人的主观方面的过错；交通事故责任不一定周全了事故的所有原因力；交通事故推定责任不能作为定罪的依据。     

吸取矿井水害事故教训 强化矿井水害的防治

阐述并分析了矿井水害事故发生的原因,提出了防治矿井水害事故的措施。